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  • 1
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 13 (1973), S. 102-112 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Filling cold mold cavities with hot polymer melts at high pressures is of great practical interest. The transport approach to this process of solving the general equations of change with suitable equations of state to describe the flowing material has been largely ignored. No analytic solution is possible, and the non-steady state flow adds a dimension which makes digital computation discouraging because of the core storage and execution time requirements.The mold filled in this simulation is a disk which hot polymer melt enters through a tubular entrance located at the center of the top plate. The tube is 2.54 cm. long and has a radius of 0.24 cm. The plate separation and outer radius of the disk cavity may be varied. A constant pressure applied at the entrance of the tube causes the flow. The cavity walls are kept at various low temperatures. The reported results are for rigid polyvinyl chloride (PVC).The general transport equations, i.e. continuity, momentum, and energy, for a constant density power law fluid are used to solve the flow problem. Convergence to the differential solutions is guaranteed but since a lower limit was imposed on the time increment by the core storage limit of the computer facilities (27K) and long execution times, all results are semiquantitative for the problem as stated.Using the results obtained it is possible to predict “fill times”. The formation of a frozen polymer skin as the cavity fills may be followed via the velocity profiles. The temperature profiles which reflect cooling and the amount of viscous heat generated provide the basis for studying resin thermal degradation effects.Finally, because so much of the total pressure drop is disispated in the entrance tube, and so much viscous heat is generated there, this study indicates that the design of the gate and runner system is perhaps the most important facet of success in mold filling.
    Additional Material: 14 Ill.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Journal für Praktische Chemie/Chemiker-Zeitung 314 (1972), S. 863-876 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Butadien, Isopren, 2,3-Dimethylbutadien und trans-Piperylen reagieren mit Acrylsäureestern unter Einwirkung von ZIEGLER-analogen Katalysatorsystemen, die aus einer Eisen- oder Kobalt- sowie einer aluminiumorganischen Verbindung, gegebenenfalls unter Zusatz eines Elektronendonators, gebildet werden, zu Heptadien-(2,5)-säurealkylestern. Im Reaktionsgemisch sind außer geringen Mengen von isomeren Heptadiensäureestern höhere Mischoligomere und Polymere vorhanden.Cis-Piperylen und Chloropren geben die Titelreaktion nicht.
    Additional Material: 8 Tab.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Journal für Praktische Chemie/Chemiker-Zeitung 320 (1978), S. 433-451 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Polyfunctionalized N-Tensides. I. Nucleophilic Substitutions with Bischloronitrosocompounds. 1. Reactions with Amines, Mercaptans and Sodium AzideChloronitrosation of alkenes gives bischloronitrosocompounds 1, which react with amines to α-aminooximes (2 and 4), with mercaptans to α-alkylthiooximes 11, and with sodium azide to α-azidooximes 8. Reduction with LiAlH4 gives vicinal substituted diamines (6, 7, 10) from α-amino-or α-azidooximes (2, 4, 8) and β-alkylthioamines 13 from α-alkylthiooximes 11.The determination of E- or Z-configuration in the α-substituted oximes is discussed.
    Additional Material: 8 Tab.
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  • 4
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Journal für Praktische Chemie/Chemiker-Zeitung 325 (1983), S. 350-351 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Journal für Praktische Chemie/Chemiker-Zeitung 326 (1984), S. 519-523 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Synthesis of 2-Aminoalkan-(1)-oles and 2-Dimethylaminoalkan-(1)-oles
    Additional Material: 2 Tab.
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  • 6
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für die chemische Industrie 78 (1966), S. 144-144 
    ISSN: 0044-8249
    Keywords: Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    Chichester [u.a.] : Wiley-Blackwell
    Journal of Raman Spectroscopy 5 (1976), S. 103-114 
    ISSN: 0377-0486
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Description / Table of Contents: L'etude comparative à 290 K et 150 K des spectres de diffusion Raman des monocristaux orientés de sulfate et de séleniate de cuivre permet de proposer des attributions pour de nombreuses raies Raman de ces composés. Le calcul des tenseurs de polarisabilité des modes normaux des ions (SO4)2- et (SeO4)2- et leur comparaison aux résultdts expérimentaux permettent de préciser la structure et le rôle des ligandes (SO4)2- et (SeO4)2- dans ces cristaux. L'existence des ions Cu(H2O)4 et Cu(D2O4 est confirmée et leurs modes de vibrations internes attribués.
    Notes: The Raman spectra of oriented single crystals of Copper (II) sulphate and selenate at 290 K and 150 K are reported and compared. Assignments are proposed for numerous internal modes of the crystals. Raman scattering tensors are calculated for the normal modes of (SO4)2- and (SeO4)2- and compared with experimental results. The structure and the part played by ligands (SO4)2- and (SeO4)2- in these crystals are stated precisely. The molecular complexes Cu(H2O)4 and Cu(D2O)4 are characterized by the assignment of their vibrational frequencies.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Angewandte Chemie International Edition in English 5 (1966), S. 131-131 
    ISSN: 0570-0833
    Keywords: Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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