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A Circular Dichroism Approach to the Conformation of 1-Arylethylamino-Substituted 1,3,5-Triazine Derivatives (2000)

Iuliano, Anna ; Voir, Ilaria ; Salvadori, Piero

Weinheim : Wiley-Blackwell

Liebigs Annalen 2000 (2000), S. 1767-1772

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ISSN: 1434-193X

Keywords: Circular dichroism ; Conformation analysis ; s-Triazines ; Chiral auxiliaries ; Chemistry ; General Chemistry

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: ---CD data of the optically pure 2-[(R)-1-(9-anthryl)ethylamino]-4-chloro-6-[(R)-1-(1-naphthyl)ethylamino]-1,3,5-triazine, 2[(R)-1-(9-anthryl)ethylamino]-4,6-bis[(R)-1-(1-naphthyl)ethylamino]-1,3,5-triazine, 2,4-bis[(R)-1-(9-anthryl)ethylamino]-6-chloro-1,3,5-triazine are presented. The analysis of the CD spectra by means of the nonempirical DeVoe approach has afforded the complete conformational characterisation of the three s-triazine derivatives, allowing us to establish how the conformation of these derivatives depends on the nature of the substituent 1-arylethylamino groups.

Additional Material: 6 Ill.

Type of Medium: Electronic Resource

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