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  • 1
    Electronic Resource
    Electronic Resource
    Zur Kenntnis der Organophosphorverbindungen, X. Darstellung und Eigenschaften tert. -butyl-substituierter Thiophosphorylhalogenide (1970)
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 103 (1970), S. 2114-2121 
    Details
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: On the Knowledge of Organophosphorus Compounds, X. Synthesis and Properties of tert-Butyl Substituted Thiophosphoryl HalidesSynthesis and properties of the tert-Butylthiophosphorylhalides (t—C4H9)nP(S)X3-n (X = Cl, Br; n = 1, 2), the asymmetric compounds R(t—C4H9)P(S)Br (R = CH3, C2H5, i—C3H7) and RP(S)Br2 (R = CH3, i—C3H7) are described, i. r. - and n. m. r. -data are reported.
    Notes: Darstellung und Eigenschaften von tert. -Butylthiophosphorylhalogeniden (t—C4H9)nP(S)X3-n (X = Cl, Br; n = 1,2), der asymmetrischen Verbindungen R(t—C4H9)P(S) Br (R = CH3, C2H5, i—C3H7) und RP(S)Br2 (R = CH3, i—C3H7) werden beschrieben, IR- und NMR-spektroskopische Daten angegeben.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/cber.19701030716
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  • 2
    Electronic Resource
    Electronic Resource
    Zur Kenntnis der Organophosphorverbindungen, XI. Darstellung und Eigenschaften von Methyl-tert.-butyl-thiophosphinsäure-Derivaten (1970)
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 103 (1970), S. 2274-2280 
    Details
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: On the Knowledge of Organophosphorus Compounds, XI. Preparation and Properties of Methyl-tert-butylthiophosphinic Acid DerivativesSynthesis and properties of the methyl-tert-butylthiophosphinic acid derivatives CH3(t-C4H9)P(S)X (X = Br, OR, OH, ONa, O-Chinin. H, OZn/2, SNa, Cl and t-C4H9) are described. I. r. and n. m. r. data are reported.
    Notes: Darstellung und Eigenschaften der Methyl-tert.-butyl-thiophosphinsäure-Derivate des Typs CH3(t-C4H9)P(S)X (X = Br, OR, OH, ONa, O-Chinin H. OZn/2, SNa, Cl und t-C4H9) werden beschrieben und ihre IR- und NMR-spektroskopischen Daten mitgeteilt.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/cber.19701030733
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  • 3
    Electronic Resource
    Electronic Resource
    Kernresonanzspektroskopische Untersuchungen an pentafluorphenylsubstituierten Silanen, I. Zusammenhänge zwischen chemischen Verschiebungen, Kopplungskonstanten und (p-d)π-Wechselwirkungen (1973)
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 106 (1973), S. 460-470 
    Details
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Nuclear Magnetic Resonance Investigations of Pentafluorphenyl-substituted Silanes, I. Correlations of Chemical Shifts, Coupling Constants, and (p-d)π-InteractionsThe 19F n.m.r. spectra of silanes (C6F5)n SiX4-n (X = F, Cl, Br, H, Alkyl, C6H5; n = 1-4) and disilanes C6F5(CH3)2 SiSi(CH3)2 X (X = CH3, C6F5) are analysed Using the ΦF* and JFF values π-acceptor properties of silicon are discussed as function of substituents.
    Notes: Es werden Silane des Typs (C6F5)n SiX4-n (X =; F, CI, Br, H, Alkyl, C6H5; n = 1 - 4) sowie die Disilane C6F5 (CH3)2SiSi (CH3)2 X (X = CH3, C6F5) 19F-NMR-spektroskopisch untersucht. Anhand der ΦF*- und JFF-Werte wird die π-Akzeptorwirkung des Siliciums in Abhängigkeit von der Art der Substituenten und vom Substitutionsgrad diskutiert.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/cber.19731060212
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  • 4
    Electronic Resource
    Electronic Resource
    Über die Michaelis-Arbuzov-Reaktion perhalogenierter Pyridine (1983)
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 116 (1983), S. 2418-2425 
    Details
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Michaelis-Arbuzov-Reaction of Perhalogenated PyridinesReactions of pentafluoropyridine (8) and pentachloropyridine (15) with trialkylphosphite 2 led to dialkyl 2,3,5,6-tetrahalo-4-pyridylphosphonate (9 and 16, resp.). Formation and decay of an intermediate phosphorane C5F4NPF(OEt)3 (10) are discussed. 19F and 31P NMR data are reported.
    Notes: Durch Umsetzung von Pentafluorpyridin (8) und Pentachlorpyridin (15) mit Trialkylphosphit 2 werden 2,3,5,6-Tetrahalogen-4-pyridylphosphonsäure-dialkylester (9 und 16) erhalten. Bildung und Zerfallsreaktionen der relativ stabilen Phosphoranzwischenstufe C5F4NPF(OEt)3 (10) werden beschrieben. 19F- und 31P-NMR-Daten werden mitgeteilt.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/cber.19831160704
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  • 5
    Electronic Resource
    Electronic Resource
    Zur Kenntnis der Organophosphorverbindungen, XII. Über die Umsetzung von Thiophosphorylderivaten mit Grignard-Reagentien und die Gemischanalyse durch NMR-Doppelresonanztechniken (1970)
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 103 (1970), S. 2885-2893 
    Details
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: On the knowledge of the Organo Phosphorus Compounds, XII. The Reaction of Thiophosphoryl Derivatives with Grignard Reagents and the Analysis of the Mixtures by n. m. r. Double-Resonance MethodsThe reaction of t-C4H9MgCl with (CH3)nP(S)X3-n (n = 0, 1, 2; X = Cl, Br) and of CH3MgX′ (X′ = Br, J) with (t - C4H9)nP(S)X3 - n ( 1, 2; X = Cl, Br) is investigated. The complex mixtures obtained are favourably analysed double-resonance methods as f. i. in the case of the formation of CH3(t-C4H9)P(S)J.
    Notes: Die Einwirkung von tert.-Butylmagnesiumchlorid auf (CH3)nP(S)X3-n (n = 0, 1, 2; X = Cl, Br) und die Reaktion von CH3MgX′ (X′ = Br, J) mit (t-C4H9)nP(S)X3-n (n = 1, 2; X = Cl, Br) werden untersucht. Komplexe Reaktionsgemische lassen sich vorteilhaft mittels NMR-Doppelresonanztechniken analysieren, wie u. a. am Beispiel der Bildung von (CH3(t-C4H9)-P(S)J gezeigt wird.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/cber.19701030927
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  • 6
    Electronic Resource
    Electronic Resource
    Notizen. Eine reduktive Michaelis-Becker-Reaktion: Darstellung und Eigenschaften des (Pentachlorphenyl)phosphonigsäure-diethylesters (1984)
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 117 (1984), S. 2287-2292 
    Details
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: A Reductive Michaelis-Becker Reaction: Synthesis and Properties of Diethyl (Pentachlorophenyl)phosphoniteHexachlorobenzene (1) reacts with sodium diethyl phosphite (3) to form diethyl (pentachlorophenyl)phosphonite (6) in a novel heterogeneous redox reaction. Subsequent reactions and NMR data are reported.
    Additional Material: 2 Tab.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/cber.19841170620
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  • 7
    Electronic Resource
    Electronic Resource
    Kernresonanzspektroskopische Untersuchungen an Pentafluorphenylsubstituierten Silanen: II-Fernkopplungen und Through Space Effekte (1974)
    Chichester : Wiley-Blackwell
    Organic Magnetic Resonance 6 (1974), S. 66-72 
    Details
    ISSN: 0030-4921
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Long range 5J(FH) and 6J(FH) couplings were observed for silanes of the type (C6F5)nSiR4-n (n = 1, 2, 3; R = alkyl, aryl) and disilanes C6F5[Si(CH3)2]2R (R = CH3, C6F5). A characteristic increase in line width for 19F-NMR spectra of (C6F5)nSiR4-n(n ≧ 2) is thought to be due to spin systems of the type ([AC]2B)n or ([AX]2M)n with intra-annular couplings between ortho-fluorine atoms of neighbouring ring systems.
    Notes: Longrange-Kopplungen des Typs 5J(FH) und 6J(FH) werden bei Silanen des Typs (C6F5)nSiR4-n (n = 1, 2, 3; R = Alkyl, Aryl) sowie den Disilanen C6F5[Si(CH3)2]2R (R = CH3, C6F5) beobachtet. Eine typische Linienverbreiterung der Fluor-resonanzspektren von (C6F5)nSiR4-n (n ≧ 2) wird auf Spinsysteme des Typs ([AC]2B)n bzw. ([AX]2M)n mit interanularen Kopplungen der ortho-Fluor-atome benachbarter Ringe zurückgeführt.
    Additional Material: 15 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/mrc.1270060203
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  • 8
    Electronic Resource
    Electronic Resource
    Kernresonanzspektroskopische Untersuchungen an C6H2F2(SCH3)2-Isomeren: Das [AMX3]2 Spinsystem (1974)
    Chichester : Wiley-Blackwell
    Organic Magnetic Resonance 6 (1974), S. 374-379 
    Details
    ISSN: 0030-4921
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: The isomeric compounds 1,2-difluoro-4,5-dimethylthiobenzene and 1,4-difluoro-2,3-dimethylthiobenzene were synthesised from CH3SNa and 1,2,4,5-tetrafluorobenzene and 1,2,3,4-tetrafluorobenzene, respectively. The structures of both the C6H2F2(SCH3)2 isomers were determined by NMR spectroscopic methods. The subspectral breakdown of an [AMX3]2 spin system is shown for the limiting case of vanishing long range coupling constants.
    Notes: Aus CH3SNa und 1,2,4,5- bzw. 1,2,3,4-Tetrafluorobenzol wurden 1,2-Difluor-4,5-dimethylthiobenzol bzw. 1,4-Difluor-2,3-dimethylthiobenzol dargestellt. Die Struktur der beiden C6H2F2(SCH3)2-Isomeren wurde durch kernresonanz-spektroskopische Methoden bestimmt. Der subspektrale breakdown des [AMX3]2-Spinsystems wird für den Sonderfall verschwindender long-range-Kopplungen abgeleitet.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/mrc.1270060704
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  • 9
    Electronic Resource
    Electronic Resource
    Kernresonanzspektroskopische Untersuchungen an cis-(CH3)2Pt[P(OCH3)3]2 (1977)
    Chichester : Wiley-Blackwell
    Organic Magnetic Resonance 9 (1977), S. 325-327 
    Details
    ISSN: 0030-4921
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: 100 MHz 1 H n.m.r. spectra of cis-(CH3)2Pt[P(OCH3)3]2 are analysed in full detail as superimposing [AR3X9]2 and [AR3X9]2M systems. The cis structure is derived from J(PP) and J(PtP).
    Notes: 100 MHz 1H NMR Spektren von cis- (CH3)2Pt[P(OCH3)3]2 werden als Superposition von [AR3X9]2-und [AR3X9]2M -Systemen analysiert. Die cis-Struktur wird abgeleitet von den Kopplungskonstanten J(PP) und J(PtP).
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/mrc.1270090608
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  • 10
    Electronic Resource
    Electronic Resource
    Aminomethylphosphine Oxides: Synthesis, dissociation and stability constants, 31P{1H}-NMR-controlled titrationsDedicated to Professor Dietrich Mootz on his 60th Birthday (1994)
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 620 (1994), S. 914-920 
    Details
    ISSN: 0044-2313
    Keywords: Aminomethylphosphine oxides ; synthesis ; 31P{1H}-NMR controlled titrations ; stability constants ; Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Aminomethylphosphinoxide: Synthese, Dissoziations- und Stabilitätskonstanten, 31P-{1H}-NMR-kontrollierte TitrationenDie Titelverbindungen werden durch Gabriel-Synthese nach bekannten und verbesserten Verfahren erhalten. Durch neue Methoden der 31P{1H}-NMR-kontrollierten Titration werden Dissoziations- (gegeben als Basizitäts- und Aciditäts-) sowie Stabilitätskonstanten erhalten. Dynamisch gemittelte und ionenspezifische Chemische Verschiebungen δP werden abgeleitet.
    Notes: The title compounds are prepared via Gabriel-synthesis following known or improved procedures. Novel methods using 31P{1H}-NMR controlled titrations of aminomethylphosphine oxides lead to dissociation constants (given as basicity or acidity constants resp.) and to stability constants. Dynamically averaged and ion specific chemical shifts δP were derived.
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/zaac.19946200526
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