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  • Wiley-Blackwell  (1)
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    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Die Stabilitätskonstanten der Komplexe von Mn++, Fe++, Co++, Ni++, Cu++, Zn++, Cd++ und UO++2 mit 5, 7-Dichlor-, 5, 7-Dibrom- und 5, 7-Dinitro-8-hydroxychinolin und der entsprechenden N-Oxide sind in Dioxan/Wasser-Gemischen (75/25) bei 35°C in Gegenwart von 0,20 m Natriumperchlorat durch Titration nach Irving und Rossotti bestimmt worden. Eine mögliche Erklärung für die beobachtete Abhängigkeit der Stabilitätskonstanten der Komplexe bei Variation des Liganden und andererseits bei Variation des Metalls wird vorgeschlagen.
    Notes: The stability constants of complexes of Mn++, Fe++, Co++, Ni++, Cu++, Zn++, Cd++ and UO++2 with 5,7-dichloro-, 5,7-dibromo- and 5,7-dinitro-8-hydroxyquinoline and their corresponding N-oxides have been determined in 75 + 25 v/v dioxan + water medium at 35°C in presence of 0.20 M sodium perchlorate by pH-titration technique as given by IRVING and Rossotti. A possible explanation for the observed orders of the stability constants of the metal complex with the different ligands, and of the complexes of a particular ligand with different metal ions is also proposed.
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
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