ISSN:
1042-7163
Keywords:
Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
The preparation of 1,1-difluoro-3,7-di-tert-butyl-2,8-dioxa-1-phosphabicyclo[3.3.0]octa-3,6-diene (Dit-BuADPO·F2)from hexafluoropropylene oxide (HFPO) and 3,7-di-tert-butyl-2,8-dioxa-1-phosphabicyclo[3.3.0]octa-2,4,6-triene (DitBuADPO) is described. The solid state structure of DitBuADPO·F2 shows an unusual square pyramidal geometry. The structural and spectroscopic properties of DitBuADPO·F2 are compared with other oxidized derivatives of DitBuADPO that contain 5-coordinate phosphorus.
Additional Material:
1 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/hc.520040215
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