ALBERT

All Library Books, journals and Electronic Records Telegrafenberg

X
feed icon rss

Your email was sent successfully. Check your inbox.

An error occurred while sending the email. Please try again.

Proceed reservation?

Export
  • 1
    Electronic Resource
    Electronic Resource
    A new thermodynamic representation of binary electrolyte solutions nonideality in the whole range of concentrations (1978)
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 24 (1978), S. 817-830 
    Details
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A system of equations based on the ionic atmosphere theory of Debye and Huckel, Born model contribution, and local compositions of the nonrandom two-liquid (NRTL) model is developed to represent isothermal activity coefficients, in the whole range of concentrations, for solutions in an undissociated solvent of a partially or completely dissociated electrolyte.The physical constants and the four adjustable parameters necessary to represent the osmotic coefficient, for fifteen strong aqueous electrolytic solutions, are given at 298.15°K and atmospheric pressure. Vapor-liquid equilibrium, for the hydrochloric acid-water system at 298.15°K, is represented for acid compositions ranging from infinite dilution to 18 M using a known dissociation constant and six parameters.
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/aic.690240508
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 2
    Electronic Resource
    Electronic Resource
    Application of DPASV to the study of heavy metal complexation in colloidal latex dispersions (1995)
    Weinheim : Wiley-Blackwell
    Electroanalysis 7 (1995), S. 1143-1150 
    Details
    ISSN: 1040-0397
    Keywords: Stripping voltammetry ; Metal complexation ; Latex ; Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Differential pulse anodic stripping voltammetry (DPASV) was applied to the study of the binding of ZnII, CdII and PbII by two kinds of polystyrene latex particles at different pH values and at different electrolyte concentrations. For the calculation of stability constants, the criterion of consistency between current and potential data was applied. For CdII and PbII, the application of DPASV yields qualitatively good results (in agreement with those previously found by DPP). However, from a quantitative point of view, the consistency criterion often reduces the applicability of the technique to quite narrow pH ranges, which increases the error in some calculations. In the case of ZnII, certain anomalies were found, rendering quantitative considerations impossible.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/elan.1140071209
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 3
    Electronic Resource
    Electronic Resource
    Polarography and stripping voltammetry of metal-polycarboxylate complexes: Complexes of cadmium and zinc with polyacrylic and polymethacrylic acids (1991)
    Weinheim : Wiley-Blackwell
    Electroanalysis 3 (1991), S. 299-307 
    Details
    ISSN: 1040-0397
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Complex formation of Zn(II) and Cd(II) with polymethacrylic acid (PMA) and polyacrylic acid (PAA) is studied by sampled direct current, normal pulse, reverse pulse, and differential pulse polarography and by differential pulse anodic stripping voltammetry (DPASV). Titrations of Zn(II) or Cd(II) with partially neutralized PMA or PAA by DPASV allow the precise determination of the apparent formation constant K of the four systems. The two Zn(II) systems appear to be labile on the different time scales of the several techniques, without remarkable complications due to secondary phenomena. Their K values, determined by all techniques, agree satisfactorily. The two Cd(II) systems, and especially the Cd/PAA system, show rather involved behavior, which tends to normality when the degree of neutralization αn of the polycarboxylates increases. Both slow kinetics and ligand adsorption coupled with induced Cd(II) adsorption (evidenced by maxima on the normal pulse polarograms) seem to be present. For all αn values, DPASV yields higher estimates of K than do polarographic techniques.
    Additional Material: 10 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/elan.1140030410
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
Close ⊗
This website uses cookies and the analysis tool Matomo. More information can be found here...