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  • 1
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Biotechnology and Bioengineering 18 (1976), S. 1629-1633 
    ISSN: 0006-3592
    Keywords: Chemistry ; Biochemistry and Biotechnology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Biotechnology and Bioengineering 19 (1977), S. 425-433 
    ISSN: 0006-3592
    Keywords: Chemistry ; Biochemistry and Biotechnology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Under certain conditions it is shown that an extended culture is equivalent to an exponentially-fed-batch culture, that an exponentially-fed-batch culture (and an extended culture) can be maintained at a steady state and that an exponentially-fed-batch culture may be mimicked by a continuous-flow culture with a constant dilution rate. Operational conditions required to maintain steady states are specified.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Biotechnology and Bioengineering 23 (1981), S. 1267-1287 
    ISSN: 0006-3592
    Keywords: Chemistry ; Biochemistry and Biotechnology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: This article and develops a process for large-scale production of glycerol by means of a hemophilic algae. The process is shown to be economically and technically feasible. Although the proposed process is extremely capital intensive, the total production cost is competitive with existing glycerol process. In addition, the overall energy requirement is much lower than that of the petrochemical process. This proposed process provides an alternative route for glycerol production that is minimally dependent on fossil fuels and is therefore, less sensitive to crude oil availability and price. The primary raw material carbon dioxide from stack gas, is an inexpensive and renewable resource. Maximal Utilization of solar energy is made not only in the glycerol synthesis steps but also in the product recovery system. Significant improvement in the process economics can be realized through further development of large-scale cultivation technology, and biomass distribution and collection machinery. Due to the labor intensive nature of the proposed algal process, it is particularly suitable for less developed nations with limited fossil fuel resources and lower labor costs.
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Chichester : Wiley-Blackwell
    Biological Mass Spectrometry 11 (1984), S. 182-186 
    ISSN: 0306-042X
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Mass measurements of the protonated molecules [M + H]+ of four insulins are presented. In addition, structurally significant fragment ions are observed in the mass spectrum and metastable scanning has been used to link these ions to the protonated molecule.
    Additional Material: 7 Ill.
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  • 5
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Chemie Ingenieur Technik - CIT 69 (1997), S. 1257-1257 
    ISSN: 0009-286X
    Keywords: Chemistry ; Industrial Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 589 (1990), S. 7-11 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Cs2AgIAgIIICl6 : A Mixed Valence Compound with Silver in the Trivalent StateJet-black CsAgCl3 has been obtained by oxidation of white CsAgCl2 with liquid chlorine. Guinier X-ray powder patterns show that CsAgCl3 is isotypic with tetragonal Cs2Au2Cl6. Therefore, CsAgCl3 has to be considered a mixed valence Ag(I, III) compound, the first ternary chloride with silver in the trivalent state (I4/mmm, a = 722.23(12) pm, c = 1082.4(4) pm). Thermal decomposition of CsAgCl3 leads to CsAgCl2-II.
    Notes: Die Oxidation von weißem CsAgCl2 mit flüssigem Chlor führt zu schwarzem CsAgCl3. Guinier-Simon-Aufnahmen lassen auf Isotypie mit der Struktur des tetragonalen Cs2Au2Cl6. schließen. Somit liegt eine gemischtvalente Silber(I, III)- Verbindung, das erste ternäre Chlorid mit Silber in der Oxidationsstufe +3, vor (I4/mmm, a = 722,23(12) pm, c = 1082,4(4) pm). Bei der thermischen Zersetzung von CsAgCl3 entsteht die Hochtemperaturmodifikation von CsAgCl2.
    Additional Material: 1 Ill.
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  • 7
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 610 (1992), S. 83-90 
    ISSN: 0044-2313
    Keywords: Amine-boranes ; pyrolysis ; boron carbonitrides ; Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Amine-Boranes as Precursors for Boron CarbonitrideAmine-Boranes have been investigated with respect to their thermal decomposition in the temperature range from rom temperature to 1050°C. The phase transformation of the pyrolytic residue derived from BH3 · C5H5N subsequently heat-treated at temperatures up to 2200°C was studied. The progress of the pyrolysis has been detected by thermal analysis (TGA) and mass spectroscopy. Chemical analysis and ESCA measurements show that the pyrolytic products are single-phase boron carbonitride (BxCyNz) which can be described as a boron and nitrogen containing pyrolytic carbon. This is also supported by means of analytical electron microscopy. Hot pressing of the pyridine-borane-derived BxCyNz at 1800°C and a pressure of 190 MPa yields whiskerlike crystals whose d-values are in accordance with that of BN and/or graphite.
    Notes: Die thermische Zersetzung von Amin-Boranen im Temperaturintervall von Raumtemperatur bis 1050°C sowie die Phasenumwandlung des aus BH3 · C5H5N erhaltenen Rückstands bei Temperaturen bis 2200°C wird untersucht. Der Pyrolyseverlauf wird thermogravimetrisch und massenspektroskopisch verfolgt. Nach elementaranalytischen und photoelektronenspektroskopischen (ESCA) Ergebnissen handelt es sich bei den Zersetzungsprodukten um einphasiges Borcarbidnitrid (BxCyNz), einem Bor und Stickstoff enthaltenden pyrolytischen Kohlenstoff. Dies wird auch durch die analytische Elektronenspektroskopie bestätigt. Durch nachfolgende „Auslagerung“ des aus Pyridin-Boran erhaltenen amorphen BxCyNz in einer Heißpresse bei 1800°C und 190 MPa Druck werden whiskerförmige Kristalle, deren d-Werte auf die Bildung von BN und/oder Graphit hinweisen, erhalten.
    Additional Material: 9 Ill.
    Type of Medium: Electronic Resource
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