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  • 1
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Rapid Communications in Mass Spectrometry 9 (1995), S. 261-263 
    ISSN: 0951-4198
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Physics
    Notes: A liquid chromatography/mass spectrometry methodology is described that enables the simultaneous estimation of the individual protein-binding affinities of a mixture of compounds. This approach has proved to be robust and enables a series of molecules to be ranked according to their protein-binding affinities within 20 minutes.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Computational Chemistry 5 (1984), S. 115-121 
    ISSN: 0192-8651
    Keywords: Computational Chemistry and Molecular Modeling ; Biochemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Computer Science
    Notes: Analysis of a Gaussian potential function suitable for modeling degenerate bending vibrations in weakly bound molecular complexes is presented. Approximate eigenvalues and eigenvectors are obtained by application of perturbation theory. Comparison to the “exact” eigenvalues obtained via a numerical solution shows that the first- and higher-order perturbation corrections are consistent with variational principles.
    Additional Material: 1 Ill.
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  • 3
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Letters Edition 18 (1980), S. 321-323 
    ISSN: 0360-6384
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 27 (1982), S. 4263-4272 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The two numerical methods are used to estimate craze surface displacements and stresses for both isolated crazes and crazes at crack tips. The results are compared with the predictions of craze micromechanics models. The investigation includes the computation of the craze surface stress profile required to maintain a given craze opening displacement profile. The boundary element program requires less computer time than the finite element one, and similar results are obtained. The analysis also considers the craze surface displacement profile corresponding to an assumed craze surface stress distribution. The element methods produce results which are approximately the same as those obtained using the model of Verheulpen-Heymans and Bauwens.
    Additional Material: 9 Ill.
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  • 5
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Physics Edition 19 (1981), S. 1759-1768 
    ISSN: 0098-1273
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: The finite-element method is applied to a craze model in order to estimate surface displacements and stresses of an isolated craze in a thin rectangular plate. The limitation of assuming linear-elastic behavior of the craze fibrils is demonstrated by comparing computed profiles with published experimental ones. Accurate finite-element estimates of craze surface stresses are obtained from the experimental displacement profile. The analysis is extended to the three-dimensional case but the difference between the craze displacements at the surface of the plate and those at midthickness is too small to justify the considerable increase in computer time in comparison with that required for two-dimensional analysis.
    Additional Material: 6 Ill.
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  • 6
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für die chemische Industrie 20 (1907), S. 570-571 
    ISSN: 0044-8249
    Keywords: Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 7
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Samples of poly(methyl methacrylate) with a central circular hole are compressed, and crazes form on or after unloading, provided that the strain attains or exceeds a threshold value ∊t. Crazes induced in air are transformed rapidly to cracks, but environmental crazes are more stable. These residual stress crazes form at the diameter of the hole on a plane perpendicular to the applied stress direction. In contrast, during loading, crazes form on the vertical plane containing the hole axis. Unloading crazes are relatively insensitive to changes in strain rate, whereas loading erazes have a pronounced rate dependence. Environmental residual stress crazing exhibits an apparent rate sensitivity at constant time, but the critical applied strain ∊t is essentially constant, irrespective of rate, if the sample is in contact with the environment for a sufficiently long time to ensure that the minimum ∊t is obtained. Residual stress crazes appear to initiate at the equator of the hole, and the maximum tensile residual strain, indicated by a strain gauge, occurs in this position.
    Additional Material: 7 Ill.
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  • 8
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 46 (1992), S. 2131-2137 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Damage development during instrumented falling weight impact (IFWIM) testing of poly(methyl methacrylate) (PMMA) is recorded using short pulse photography. The first visible damage is cracking on application of the peak force. Finite element analysis predicts the deformation and state of stress throughout the specimen until the first point of failure is reached. A variation in the specimen geometry produces a significant change in initial failure energy, while the maximum tensile stress is approximately constant. The proposed failure criterion is the attainment of a critical time-dependent value of tensile stress. © 1992 John Wiley & Sons, Inc.
    Additional Material: 8 Ill.
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  • 9
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 32 (1992), S. 586-592 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Thin microtomed samples from hot-tool butt welds of polypropylene pipes are subjected to uniaxial tensile stress using a specially built instrumented microtesting machine. The deformation of the interface between the weld and the bulk polymer is measured by an optical method. An analysis of these measurements is carried out using the finite element method, and contours of the effective stress are obtained. There is a steep stress gradient at the junction of the weld flash and the bulk polymer, although the stress concentration factor is relatively low. The stress is essentially constant in the bulk polymer apart from the region near the weld zone. Tests on samples without the weld flash show that the maximum stress occurs within the weld zone. This is consistent with long-term tests on larger samples, where the fracture is found to initiate within the weld. The method of analysis enables the stress-strain response of the weld material to be determined.
    Additional Material: 13 Ill.
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  • 10
    Electronic Resource
    Electronic Resource
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part B: Polymer Physics 24 (1986), S. 2433-2444 
    ISSN: 0887-6266
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: The finite element method is applied to contours (measured by interferometry) of craze zones in front of stationary crack tips in polymethylmethacrylate (PMMA) in order to compute the stress distribution. The stress along the craze zone has its maximum at the crack tip, being about twice that predicted by the Dugdale model; and it decreases at first sharply and then more gradually, being almost constant as the craze tip is approached. Stress distributions, in a growing craze at the still stationary crack tip, at various times can be combined in a normalized curve. Craze stresses relax with time as the craze continues to propagate in a stable manner. When the specimen is unloaded, the craze stress is compressive near the crack tip, but is tensile at the craze tip and for most of the craze length. Analysis of measurements made during a loading cycle establishes minimum stress intensity levels at which no fibrils are in compression. The levels are different for increasing and decreasing loads, and it is found the craze stresses are tensile for most of the cycle. Throughout the cycle, there is an excellent correlation between the average craze stress and the theoretical stress predicted by the Dugdale model.
    Additional Material: 11 Ill.
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