ISSN:
0030-4921
Keywords:
Chemistry
;
Analytical Chemistry and Spectroscopy
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
The initial assignments by Mahler and Pettit of relative configurations of the two racemic diastereomeric tricarbonyl-(trans,trans-3,5-heptadien-2-ol)iron complexes and to the two racemic diastereomeric tricarbonyl-(trans-3,5-hexadien-2-ol)iron complexes are consistent with NMR coupling constants, conformational analysis, previously reported Eu(fod)3 lanthanide-induced shift data and new Yb(dpm)3 lanthanide-induced shift data. A detailed discussion shows that, contrary to the claim by Foreman, the lanthanide-induced shift data alone provide no new information regarding the relative configurations of these alcohols.
Additional Material:
4 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/mrc.1270071108
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