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Incremental modification of styrene-butadiene rubber with tert-dodecyl mercaptan (1961)

Booth, C. ; Beason, L. R. ; Bailey, J. T.

New York, NY [u.a.] : Wiley-Blackwell

Journal of Applied Polymer Science 5 (1961), S. 116-123

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ISSN: 0021-8995

Keywords: Chemistry ; Polymer and Materials Science

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics

Notes: The molecular weights and molecular weight distribution of a styrene-butadiene rubber produced at 5°C. according to an incrementally modified recipe with tert-dodecyl mercaptan modifier, do not differ significantly from those of similar conventionally modified rubbers. The limiting effect of diffusion upon the mass transfer of mercaptan in the system provides a consistent explanation of this finding.

Additional Material: 4 Ill.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/app.1961.070051318

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