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  • Wiley-Blackwell  (110)
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  • 1
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 8 (1962), S. 629-634 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 22 (1976), S. 685-691 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The cost of a reactor-heater system with an auxiliary cooler can have at least two local minima and a local maximum, with respect to the design variables: temperature and extent of reaction. This cost can be bounded below by a unimodal function which, being a posynomial (a sum of power functions), can be minimized efficiently by geometric programming. Construction of this lower bounding function is not obvious, since the cost involves both a definite intergral and economies of scale.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 17 (1971), S. 235-240 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A procedure for optimizing generalized polynomial functions occurring widely in engineering design problems is presented. Equality constraints of the same form can be handled. The technique involves driving to zero the gradient of a Lagrangian function by a Newton-Raphson method. A nonlinear transformation so simplifies the derivatives needed for Newton-Raphson iteration that they are given in closed form. The initial estimate needed to start the algorithm need not be feasible. Successive systematic adjustment of Lagrange multipliers is accomplished, and an unambiguous procedure for starting multipliers is given. All implicit computations are linear. Convergence is not proven, but successful computational results for the design of a reactor exchanger pump system in eight variables and with five constraints are presented.
    Additional Material: 1 Ill.
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  • 4
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 20 (1974), S. 996-1002 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A simple procedure for achieving the minimum cost design of a single reaction fluidized reactor system with feed and recycle heaters is presented and proven. The problem's mathematical interest stems from its multimodality, the handling of the exponential dependence of temperature, and the presence of an integral equation constraint. The proof technique is an extension of Lagrange's method, supplemented by ideas from geometric programming, extended to exponential and the integral functions.
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  • 5
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 4 (1958), S. 436-439 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A fundamental investigation of the departure from equilibrium in steady-state phase transitions has been made in terms of irreversible thermodynamics and absolute rate theory. The present status of the concept of accommodation coefficients was reviewed and hypotheses were advanced for the reconciliation of opposing viewpoints. Formulas for the magnitude of the departure from equilibrium were derived for single- and multicomponent systems. The deviation from equilibrium appeared to be small for ordinary rates of phase change, but interpretation of the available data was hampered by lack of a detailed molecular picture of the phase-change process.
    Additional Material: 1 Ill.
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  • 6
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 9 (1963), S. 186-190 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 10 (1964), S. 913-919 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The calculus of variations, dynamic programing, and Pontryagin's maximum principle all are methods for optimzing serial decision processes, the kind associated with multistage operations having no recycle or bypass. Addition of recycle to a serial process makes it cyclic, and branching structures can be built up by connecting serial ones. The concept of cut state makes possible the decomposition of cyclic and branched systems into serial ones solvable by serial procedures. Under favorable circumstances cut states can be directed to their optimum values by efficient optimum seeking methods, which is not possible for ordinary state variables. These method are worthwhile only for loops having at least three stages, and the treatment of converging branches is more complicated than for diverging ones. Visualization of the various system structures is aided by functional diagrams. Definitions and nomenclature are developed for continued research on optimization of macrosystems by serial techniques.
    Additional Material: 6 Ill.
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  • 8
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 11 (1965), S. 237-245 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Although it is already known how to apply feedforward control to an overdetermined system (2), feedback control is more difficult because overdeterminancy involves more measured variables than controllers. Feedback control is possible for a system of production units separated by storage tanks holding intermediate products and perturbed by random external upsets (1). Two types of feedback control are studied: local control in which each manipulated variable is controlled by the levels in the two tanks immediately adjacent, and central control in which all the levels simultaneously affect each manipulated variable. The behavior of these systems for three-action linear controllers is described. Proportional local control is shown to have a structure similar to those of the unrefluxed countercurrent separation processes of the chemical industry. Such systems are therefore inherently stable. Central control, although requiring a more complicated equipment arrangement, actually has a simpler dynamic behavior because it cancels out interactions between controllers.
    Additional Material: 11 Ill.
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  • 9
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 13 (1967), S. 236-240 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Feedback and feedforward inventory control systems are derived which give improved probability of holding all inventories between predetermined limits, even when there are fewer controllers than controlled variables. The concept of partial controllability is developed to describe systems with uncontrollable states. An example shows that four tank levels can be held within limits with high probability, with only one manipulated flow rate used.
    Additional Material: 1 Ill.
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  • 10
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 16 (1970), S. 943-949 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Most processes have more storage levels to control than there are production rates for changing inventories, a situation known as partial controllability. Necessary and sufficient conditions under which all levels can be held within predetermined limits are presented. A control law maximizing the probability of satisfactory operation is developed, together with the computational steps required for its implementation. A simple numerical example is given.
    Additional Material: 4 Ill.
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