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  • 1
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    International Journal of Quantum Chemistry 5 (1971), S. 497-503 
    ISSN: 0020-7608
    Keywords: Computational Chemistry and Molecular Modeling ; Atomic, Molecular and Optical Physics
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: A MO-LCAO-SCF treatment is performed on water, ammonia and methane using a recently proposed approximate method.The procedure is found capable of predicting total and orbital energies in close agreement with the results of accurate computations using double ζ basis sets of Slater type orbitals.A comparison is made with the results of similar approximate ab initio procedures.
    Additional Material: 2 Tab.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Biopolymers 7 (1969), S. 671-680 
    ISSN: 0006-3525
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Preferential adsorption of cations occurs in the solvated shell surrounding polyanions, especially polynucleotides and nucleic acids. The solvation parameter Γ is determined from sedimentation coefficients which are considered as pienometric determinations of the specific volume of the sample. By comparing two identical concentrations (0.1M) of monovalent salts, NaCl and CsCl, and using the model of DNA described in the preceding paper, one can relate the ratio SCs/SNa to solvation parameters ΓCs, and ΓNa.On the other hand, Γ can be related to the difference of energy W, between cation and water, to be extracted from the solution and placed in the vicinity of the polyanion. One finds generally a preferential solvation of the polarizable caesium ion by means of London-van der Waals interactions with bases. With reasonable assumptions, an estimate of W can be made, and the predicted value of Γ can be compared to the experimental one. An average of six sites is found around each base in a single-stranded polymer, but-only one in the double-stranded structure. The amount of secondary structure can thus be estimated from the simple measurement of the ratio of two sediment constants.
    Additional Material: 2 Tab.
    Type of Medium: Electronic Resource
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  • 3
    Publication Date: 2015-06-09
    Description: On 30 October 1930, an M w  5.8 earthquake hit the northern Marche coastal area (central Italy), causing significant damage ( I 0 VIII–IX degree Mercalli–Cancani–Sieberg) along a 40 km stretch of the Adriatic coast between Pesaro and Ancona, centered on the town of Senigallia. This area is characterized by relatively infrequent and moderate-sized earthquakes and by elusive active faults. In spite of the presence of well-known northwest–southeast-trending, northeast-verging fault-propagation folds forming the outer thrusts of the Apennines, the current level of activity, and the kinematics of these coastal structures are still controversial. We present a multidisciplinary analysis of the source of the 30 October 1930 Senigallia earthquake, combining instrumental and macroseismic data and elaborations with available evidence from geological and tectonic investigations. We determine the main seismic parameters of the source, including the earthquake location, its magnitude, and, for the first time, its focal mechanism, providing the first instrumental evidence for thrust faulting along the northern Marche coastal belt. Our findings provide conclusive evidence for the current activity of the northern Marche coastal thrusts. As such they have significant implications for the seismic hazard of the area, a densely populated region that hosts historical heritage, tourism facilities, industrial districts, and key transportation infrastructures. Online Material: Description of method used for moment tensor computation, tables of focal mechanisms and recording stations, and figures of seismic flux and uncertainty maps for macroseismic epicenters.
    Print ISSN: 0037-1106
    Electronic ISSN: 1943-3573
    Topics: Geosciences , Physics
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