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  • 1
    ISSN: 1476-4687
    Source: Nature Archives 1869 - 2009
    Topics: Biology , Chemistry and Pharmacology , Medicine , Natural Sciences in General , Physics
    Notes: [Auszug] The radio sky is relatively unexplored for transient signals, although the potential of radio-transient searches is high. This was demonstrated recently by the discovery of a previously unknown type of source, varying on timescales of minutes to hours. Here we report a search for radio sources ...
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 33 (1987), S. 130-140 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: An approach to chemical plant fault diagnosis is presented that utilizes patterns of violation and satisfaction of the quantitative constraints governing the process. Process knowledge consists of a list of the operational constraints on the plant together with sufficient conditions for violation of each constraint. Interpretation of the pattern of constraint violations is treated by Boolean and non-Boolean techniques. It is shown that non-Boolean reasoning techniques increase the stability and sensitivity of the diagnosis in the presence of noise. The techniques introduced in this paper are easily implemented in rule-based expert systems using certainty factors.
    Additional Material: 7 Ill.
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  • 3
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 33 (1987), S. 1067-1078 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Fault diagnosis is the problem of determining the root causes of process upsets. This paper presents a very efficient method of identifying the possible causes of process disturbances using the signed directed graph (digraph) representation of process interactions. The analysis is based on forming logical statements (rules) derived from the process digraph; these are evaluated using on-line data to yield the diagnosis. Evaluation of rule antecedents is more efficient than the previous algorithmic approach of Shiozaki et al. In the rule-based approach, the diagnostic criteria are represented explicitly, not hidden by a complex algorithmic procedure. This allows the diagnostic rules to be tailored to reflect the best available knowledge of plant behavior. The rules generated by this technique can be integrated with other rules on plant operations using an expert systems framework.
    Additional Material: 14 Ill.
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  • 4
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 34 (1988), S. 25-36 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The problem of diagnosing faults in chemical plants can be efficiently addressed by a hierarchical procedure involving successive narrowing of the space in which the fault search is conducted. A technique is presented for narrowing diagnostic focus useful in the first stages of a diagnostic search. Based on a decomposition of the process according to function, the technique assesses the functionality of process systems based on measurements of controlled and manipulated variables. A procedure for identification of possibly faulty systems and units from the system states is outlined. Detailed diagnosis, not treated in this paper, would be applied after candidate systems or units are located. An example is presented using a hypothetical chemical reaction process.
    Additional Material: 6 Ill.
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  • 5
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Chemistry Edition 14 (1976), S. 1609-1616 
    ISSN: 0360-6376
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Because of the allylic nature of propylene, the vinyl chloride-propylene system exhibits polymerization behavior markedly different from that of vinyl chloride, even at relatively low propylene concentrations. Propylene acts as a degradative chain-transfer agent, and as a result, both the polymerization rate and the molecular weight of the resultant copolymers are lower than those of the homopolymer, decreasing with increasing propylene content. Even at propylene concentrations as low as 10% the rate of polymerization is proportional to the initiation rate, indicating kinetic control by the propylene. The reactivity ratios of these monomers given by Cain were verified. The reciprocal intrinsic viscosity of the copolymer was found to be linearly related to the monomer feed composition.
    Additional Material: 6 Ill.
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  • 6
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Chemistry Edition 12 (1974), S. 2821-2843 
    ISSN: 0360-6376
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: An overall mechanistic scheme for the suspension polymerization of vinyl chloride is presented. The process can be resolved into five discrete stages, each of which presents a unique environment for the interaction of the systems parameters. It is shown that the surface area of the polymer formed during the reaction is not a major factor in autoacceleration and that the increase of kinetic chain length with conversion is due to a radical dilution effect. The latter is a direct result of the difference in rates between polymerization and radical formation, the former being greater. The increase of the initial polymerization rate and the reduction of autoacceleration brought about by chain transfer agents can be explained by the lower diffusion rate and greater bulkiness of the chain transfer agent radical relative to that of the monomer radical. The chaintransfer agent CBr4 is preferentially absorbed by PVC from solution in vinyl chloride. With lauryl peroxide as initiator it is shown that the “hot spot” is the result of a build-up of initiator in the monomer caused by its exclusion from the polymer phase. Vinyl chloride was found to dissolve 0.03% PVC at ambient temperature and to have no effect on the decomposition rate of lauryl peroxide.
    Additional Material: 6 Ill.
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  • 7
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Fire and Materials 2 (1978), S. 34-36 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Limiting Oxygen Indexes were determined for a polyester resin fire retarded with a number of different brominated hydrocarbons. It was found that up to a concentration of 28 phr bromine the values obtained were linearly related to the bromine concentration and independent of the carbon-bromine bond.
    Additional Material: 1 Ill.
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  • 8
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 21 (1977), S. 1615-1619 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The chain transfer activity of propylene leads to the formation of vinyl chloride-propylene copolymers with molecular weights lower than those of PVC homopolymers produced under similar conditions. It has been found that the addition of specified quantities of monomers with two or more active double bonds can increase the molecular weight of these copolymers without causing crosslinking.
    Additional Material: 1 Ill.
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  • 9
    ISSN: 0044-8249
    Keywords: Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
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  • 10
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für die chemische Industrie 78 (1966), S. 215-216 
    ISSN: 0044-8249
    Keywords: Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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