ISSN:
0887-624X
Keywords:
styrene
;
ethyl acrylate
;
reactivity ratios
;
kinetics
;
copolymerization
;
Chemistry
;
Polymer and Materials Science
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
An experimental study of the bulk-free radical copolymerization of styrene (STY)/ethyl acrylate (EA) initiated by 2,2′-azobisisobutyronitrile was conducted. Reactivity ratios were evaluated using both nonlinear least-squares (NLLS) and error-in-variables model (EVM) techniques. A thorough study of the kinetics over the full conversion range was subsequently carried out at a variety of feed compositions, initiator concentrations, and temperatures, with and without added chain transfer agent (CTA). © 1996 John Wiley & Sons, Inc.
Additional Material:
22 Ill.
Type of Medium:
Electronic Resource
Permalink