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  • 1
    Digitale Medien
    Digitale Medien
    New York : Wiley-Blackwell
    Biopolymers 7 (1969), S. 671-680 
    ISSN: 0006-3525
    Schlagwort(e): Chemistry ; Polymer and Materials Science
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: Preferential adsorption of cations occurs in the solvated shell surrounding polyanions, especially polynucleotides and nucleic acids. The solvation parameter Γ is determined from sedimentation coefficients which are considered as pienometric determinations of the specific volume of the sample. By comparing two identical concentrations (0.1M) of monovalent salts, NaCl and CsCl, and using the model of DNA described in the preceding paper, one can relate the ratio SCs/SNa to solvation parameters ΓCs, and ΓNa.On the other hand, Γ can be related to the difference of energy W, between cation and water, to be extracted from the solution and placed in the vicinity of the polyanion. One finds generally a preferential solvation of the polarizable caesium ion by means of London-van der Waals interactions with bases. With reasonable assumptions, an estimate of W can be made, and the predicted value of Γ can be compared to the experimental one. An average of six sites is found around each base in a single-stranded polymer, but-only one in the double-stranded structure. The amount of secondary structure can thus be estimated from the simple measurement of the ratio of two sediment constants.
    Zusätzliches Material: 2 Tab.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 2
    Digitale Medien
    Digitale Medien
    New York, NY : Wiley-Blackwell
    International Journal of Quantum Chemistry 5 (1971), S. 497-503 
    ISSN: 0020-7608
    Schlagwort(e): Computational Chemistry and Molecular Modeling ; Atomic, Molecular and Optical Physics
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: A MO-LCAO-SCF treatment is performed on water, ammonia and methane using a recently proposed approximate method.The procedure is found capable of predicting total and orbital energies in close agreement with the results of accurate computations using double ζ basis sets of Slater type orbitals.A comparison is made with the results of similar approximate ab initio procedures.
    Zusätzliches Material: 2 Tab.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 3
    Publikationsdatum: 2021-03-31
    Beschreibung: On 21 August 1962 an earthquake sequence set off near the city of Benevento, in Italy's southern Apennines. Three earthquakes, the largest having Mw 6.1, struck virtually the same area in less than 40 min (at 18:09, 18:19 and 18:44 UTC, respectively). Several historical earthquakes hit this region, and its seismic hazard is accordingly among the highest countrywide. Although poorly understood in the past, the seismotectonics of this region can be revealed by the 1962 sequence, being the only significant earthquake in the area forwhichmodern seismograms are available. We determine location, magnitude, and nodal planes of the first event (18:09 UTC) of the sequence. The focal mechanismexhibits dominant strike-slip rupture along a north-dipping, E-W striking plane or along a west-dipping, N-S striking plane. Either of these solutions is significantly different fromthe kinematics of the typical large earthquakes occurring along the crest of the Southern Apennines, such as the 23 November 1980 Irpinia earthquake (Mw 6.9), caused by predominant normal faulting along NW-SE-striking planes. The epicentre of the 21 August 1962, 18:09 event is located immediately east of the chain axis, near one of the three north-dipping, E-W striking oblique-slip sources thought to have caused one of the three main events of the December1456 sequence (Io XIMCS), the most destructive events in the southern Apennines known to date. Wemaintain that the 21August 1962, 18:09 earthquake occurred along the E-Wstriking fault systemresponsible for the southernmost event of the 1456 sequence and for two smaller but instrumentally documented events that occurred on 6May 1971 (Mw 5.0) and 27 September 2012(Mw 4.6), further suggesting that normal faulting is not the dominant tectonic style in this portion of the Italian peninsula.
    Beschreibung: Published
    Beschreibung: 375-384
    Beschreibung: 2T. Tettonica attiva
    Beschreibung: JCR Journal
    Beschreibung: open
    Schlagwort(e): 1962 Irpinia earthquake ; Multiple earthquake ; Focal mechanism ; Strike-slip faulting ; Active tectonics ; Seismic hazard ; 04. Solid Earth::04.07. Tectonophysics::04.07.07. Tectonics
    Repository-Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Materialart: article
    Standort Signatur Erwartet Verfügbarkeit
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  • 4
    Publikationsdatum: 2016-11-17
    Print ISSN: 0036-8075
    Digitale ISSN: 1095-9203
    Thema: Biologie , Chemie und Pharmazie , Informatik , Medizin , Allgemeine Naturwissenschaft , Physik
    Standort Signatur Erwartet Verfügbarkeit
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