ISSN:
0001-1541
Keywords:
Chemistry
;
Chemical Engineering
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
,
Process Engineering, Biotechnology, Nutrition Technology
Notes:
The experimental apparatus and procedures which were developed for the determination of the heterogeneous phase behavior of the methane-hydrogen sulfide system have been described in a previous paper (2). The apparatus and procedures were tested and employed at temperatures in the range of - 300 to 300°F. and at pressures up to 2000 1b./sq. in. abs. The vapor-liquid, vapor-solid, liquid-vapor-solid, liquid-liquid-vapor and liquid-liquid-solid phase border curves were determined for six mixtures of methane and hydrogen sulfide. The phase compositions were determined at selected points along the three-phase univariant equilibrium lines. An invariant point (quadruple point) was found which involves the equilibrium of two liquid phases, a vapor phase, and a solid phase. These data are presented on P-T and T-X diagrams.The data contribute to the understanding of phase behavior of light hydrocarbons containing hydrogen sulfide.
Additional Material:
14 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/aic.690040217
Permalink
