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  • Wiley-Blackwell  (75)
  • American Geophysical Union (AGU)
  • 1970-1974  (75)
Collection
Keywords
Publisher
Years
Year
  • 1
    Electronic Resource
    Electronic Resource
    Feedforward computer control of a class of distributed parameter processes (1970)
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 16 (1970), S. 754-761 
    Details
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A finite difference technique has been developed which is suitable for the derivation of feedforward control algorithms for the control of distributed parameter processes. The method embodies both steady state and transient feedforward compensation.An experimental study, involving closed loop, on line, analogue computer control of a simple distributed parameter process proves the feasibility of the finite difference technique. The process under study is a steam water heat exchanger subject to inlet temperature forcing and controlled by flow rate manipulation. The new technique yielded significantly improved results when compared with the performance of a conventional two-mode feedback controller, or a linearized feedforward control algorithm.
    Additional Material: 9 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/aic.690160513
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  • 2
    Electronic Resource
    Electronic Resource
    Carbon dioxide-ethane phase equilibrium and densities from experimental measurements and the B-W-R equation (1974)
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 20 (1974), S. 357-362 
    Details
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Liquid composition-total pressure and liquid composition-liquid density data for the carbon dioxide-ethane system were measured at -31.7°, -17.8°, -3.9°, and 10.0°C (-25°, 0°, 25°, and 50°F ± 0.02°F), from 0 to 80 mole % CO2 at 10°C and 0 to 100% CO2 for the other isotherms. The Benedict-Webb-Rubin equation of state with a modified A0 mixing rule was used to correlate the composition-pressure data, with deviations in predicted pressures of only 0.8% average and 2% maximum. Vapor-liquid equilibrium compositions and component K values y/x were then predicted for this minimum boiling azeotrope system from 10° down to -56.7°C (50° to -70°F).
    Additional Material: 9 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/aic.690200223
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  • 3
    Electronic Resource
    Electronic Resource
    Calculation method for the response time to step inputs for approximate dynamic models of distillation columns (1972)
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 18 (1972), S. 1243-1252 
    Details
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A calculation method to determine the response time to be used for approximate mathematical models is developed for the dynamic behavior of distillation columns. Previous work has shown that the concept of Inventory time can be successfully used to approximate the response time, that is, the 60% point of the step response, of distillation columns operating at a high degree of separation. A modified version of the inventory time method, based on the minimum change of storage, has been developed to predict the response time for other ranges of separation within reasonable bounds of error, ± 10%. Only steady state and design data were used. A rigorous nonlinear simulation generates the steady state and transient data upon which the approximate models are based.While the modified inventory time method developed cannot handle every possible operating condition with the desired degree of accuracy, it has been shown to apply over a much wider range of operating conditions than the original inventory time method.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/aic.690180623
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  • 4
    Electronic Resource
    Electronic Resource
    Reaction of nitrogen dioxide with linear polyurethane (1973)
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Chemistry Edition 11 (1973), S. 3227-3242 
    Details
    ISSN: 0360-6376
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Linear polyurethane has been exposed to nitrogen dioxide over a temperature range from 15 to 60°C at pressures of 20 and 2 mm Hg, respectively. Normal random-chain scission of urethane links takes place accompanied by a limited amount of random crosslinking. These crosslinks are eventually irreversibly scissioned again. At the same time, carbon dioxide is evolved, and the infrared spectra of the polymer films change during exposure, indicating disappearance of urethane linkages and formation and decay of nitro and nitroso groups along the polymer backbone. The overall reaction is diffusion-controlled at least down to a film thickness of 10 μ. All energies of activation of the various processes are relatively small as expected for a diffusion controlled process. Tentative mechanisms have been proposed agreeing well with experimental results.
    Additional Material: 12 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pol.1973.170111216
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  • 5
    Electronic Resource
    Electronic Resource
    The numerical solution of non-linear consolidation problems (1971)
    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 3 (1971), S. 5-11 
    Details
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: It has long been recognized that permeability, compressibility and viscosity vary during the consolidation of soil. However, the introduction of these variations into consolidation theory leads to formidable difficulties due to their rendering the equations highly non-linear. Numerical methods are given herein which enable the governing equation to be solved for a variety of different non-linear laws.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/nme.1620030104
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  • 6
    Electronic Resource
    Electronic Resource
    A preliminary study of thermoluminescence in polypropylene (1972)
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Physics Edition 10 (1972), S. 2101-2105 
    Details
    ISSN: 0098-1273
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pol.1972.180101022
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  • 7
    Electronic Resource
    Electronic Resource
    Numerical methods for evaluation of equilibrium composition of ideal gases (1971)
    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 3 (1971), S. 509-517 
    Details
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: This paper considers methods of solution of the relevant equations based on the Newton-Raphson process. Expressions are derived for calculation with both good and very poor initial guesses and for calculation of pressure, volume and temperature during an equilibrium process. A method of programming the calculations is outlined. Variations and modifications to suit specific situations are discussed.
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/nme.1620030406
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  • 8
    Electronic Resource
    Electronic Resource
    A systematic approach to the AA′BB′, AA′BB′MX and derived systems in nuclear magnetic resonance (1971)
    Chichester : Wiley-Blackwell
    Organic Magnetic Resonance 3 (1971), S. 83-99 
    Details
    ISSN: 0030-4921
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The AA′BB′ and AA′BB′MX nuclear magnetic resonance spin systems for I = ½ nuclei have been analysed. Expressions for the transition frequencies and intensities have been obtained which have the maximum accuracy consistent with practicable use. The analyses have been applied respectively to a hypothetical AA′BB′ nuclear spin system and to the two molecules para- fluoro-phenyldichlorophosphine and tris-para-fluorophenylphosphine. Inconsistencies in earlier treatments of the AA′BB′ system have been clarified.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/mrc.1270030109
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  • 9
    Electronic Resource
    Electronic Resource
    Tris(dipivaloylmethanato)europium induced shifts of proton resonances in π-deficient nitrogen heterocycles (1971)
    Chichester : Wiley-Blackwell
    Organic Magnetic Resonance 3 (1971), S. 575-582 
    Details
    ISSN: 0030-4921
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Tris(dipivaloylmethanato)europium [Eu(DPM)3]induced shifts of the proton resonances of pyridine and its 2-methyl, 3-methyl, 2,3-dimethyl and 2,5-dimethyl derivatives, pyridazine, pyrimidine, pyrazine, quinoline, isoquinoline, 1,6-, 1,7- and 1,8-naphthyridine, cinnoline, phthalazine, quinazoline, quinoxaline, 1,4,5- and 1,4,6-triazanaphthalene, pteridine, acridine, phenanthridine and 1, 10-phenanthroline, have been measured for solutions containing 0·1, 0·3 and 0·5 molar equivalents of Eu(DPM)3. Differences in the behaviour of these heterocycles are discussed in terms of the steric relationship between the heterocycle and the complex. The 3 cos2 φ term, present in the expression for calculating pseudo-contact shifts, is shown to be important. The order of basicity of these heterocycles, as measured by their pKa values, cannot be used to predict the order of Eu(DPM)3 induced chemical shifts.
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/mrc.1270030512
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  • 10
    Electronic Resource
    Electronic Resource
    AB-based NMR systems. Choice of bounds for θ in trigonometric forms of co-factors in mixed wave-functions (1972)
    Chichester : Wiley-Blackwell
    Organic Magnetic Resonance 4 (1972), S. 67-72 
    Details
    ISSN: 0030-4921
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Labelling problems associated with the choice of bounds for the angle θ in the trigonometric forms of the co-factor expressions for levels in AB-based NMR spectra have been investigated. It has been shown that any pair of octants within the 0 → 2π range can be specified as bounds, provided that appropriate linear combinations of wave functions are chosen. The range 0 ≤ θ ≤ π/2 is preferred for simplicity in calculation.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/mrc.1270040108
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