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  • Wiley-Blackwell  (7,974)
  • 1985-1989  (7,974)
Collection
Keywords
Publisher
Years
Year
  • 1
    Electronic Resource
    Electronic Resource
    Development of macromolecular prodrugs of the antitumor antibiotic adriamycin (1985)
    New York : Wiley-Blackwell
    Die Makromolekulare Chemie 9 (1985), S. 175-178 
    Details
    ISSN: 0025-116X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/macp.1985.020091985125
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  • 2
    Electronic Resource
    Electronic Resource
    Letters to the editor (1985)
    Chichester : Wiley-Blackwell
    Biological Mass Spectrometry 20 (1985), S. 422-431 
    Details
    ISSN: 0030-493X
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/oms.1210200608
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  • 3
    Electronic Resource
    Electronic Resource
    Hydrogen-bonding 8.Part 7; M. H. Abraham, P. L. Grellier, D. V. Prior, P. P. Duce, J. J. Morris and P. J. Taylor. J. Chem Soc., Perkin Trans. 2, (in press). Possible equivalence of solute and solvent scales of hydrogen-bond basicity of non-associated compounds (1989)
    Chichester : Wiley-Blackwell
    Journal of Physical Organic Chemistry 2 (1989), S. 540-552 
    Details
    ISSN: 0894-3230
    Keywords: Organic Chemistry ; Physical Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Using the solvatochromic indicator method, a scale of solvent hydrogen-bond basicity, β1 (General), has been set up using a series of double regression equations, \documentclass{article}\pagestyle{empty}\begin{document}$$ \nu = \nu _0 + s\pi _1^* + b\beta _1 $$\end{document} for 11 aniline-type indicators. A similar solvent scale, β1 (Special), has been constructed by the homomorphic comparison method using only results by Laurence et al. on the indicators 4-nitroaniline and 4-nitro-N,N-dimethylaniline. Results are available from our previous work on a general solute scale, β2H, and we have also obtained a special solute scale, β2 (pKHB) from available log K values for hydrogen-bond complexation of bases with 4-fluorophenol in CCl4. However, the two solute β2 scales are virtually identical.It is shown that there is a general connection between β1(General) and β2H, with r = 0·9775 and s.d. = 0·05 for 32 compounds, and between β1(Special) and β2H, with r = 0·9776 and s.d. = 0·06 for the same 32 compounds. The latter correlation over 60 compounds yields r = 0·9684 and s.d. = 0·07. However, there are so many compounds in these regressions for which the differences in the solvent and solute β values are larger than the total expected error of 0·07 units that the use of β1 to predict β2 or vice versa is a very hazardous procedure. About 70 new β1 values obtained by the double regression method are also reported.
    Additional Material: 6 Tab.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/poc.610020706
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  • 4
    Electronic Resource
    Electronic Resource
    Effect of combined pressure and temperature changes on structural recovery of glass-forming materials. I. Extension of the KAHR model (1988)
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part B: Polymer Physics 26 (1988), S. 501-513 
    Details
    ISSN: 0887-6266
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: The KAHR model of structural relaxation has been extended to include the effects of pressure upon the retardation times of glass-forming materials. The previously used methodology is applied with a continuous distribution of retardation times of the fractional exponential form. Several forms of the pressure dependence are examined. The combined temperature and pressure changes on structural recovery of glasses are addressed in this paper.
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/polb.1988.090260303
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  • 5
    Electronic Resource
    Electronic Resource
    Fatigue of acrylic bone cement-effect of frequency and environment (1989)
    Hoboken, NJ : Wiley-Blackwell
    Journal of Biomedical Materials Research 23 (1989), S. 819-831 
    Details
    ISSN: 0021-9304
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Medicine , Technology
    Notes: This study was conducted to investigate some fundamental fatigue testing variables as they apply to the response characteristics of acrylic bone cement. Cyclic loading under load control was conducted at frequencies of 1, 2, 5, 10, and 20 Hz in air at room temperature. At a tensile stress range of 0.3-20.0 MPa the fatigue life increased linearly with logarithmic frequency. The effect of conditioning and testing in saline at both room temperature and 37°C at similar stress levels and a frequency of 10 Hz were also examined. When compared to dry testing at room temperature, testing in saline at 37°C resulted in a reduction in fatigue life while testing in saline at room temperature produced an increase in fatigue life. Of a number of statistical distributions considered, the Weibull was found to be the most appropriate in documenting the findings of this investigation. A companion fractographic investigation of the failure surfaces demonstrated distinct regions of crack growth and fast fracture.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/jbm.820230802
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  • 6
    Electronic Resource
    Electronic Resource
    Tables of rate constants extracted from chemical kinetics and photochemical data for use in stratospheric modeling. Evaluation number 7 (1985)
    New York, NY : Wiley-Blackwell
    International Journal of Chemical Kinetics 17 (1985), S. 1135-1151 
    Details
    ISSN: 0538-8066
    Keywords: Chemistry ; Physical Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: These tables of evaluated rate constants for use in stratospheric modeling have been taken from the most recent report of the NASA Panel that has been periodically producing such reviews. They are reproduced here to make a broader community aware of their existence. This article should NOT be cited, nor should these rate constants be used without consulting the full report. All citations should be to that original report (JPL Publ. 85-37), which contains extensive documentation and discussion of the rationale of the evaluation. Copies may be obtained by requesting JPL Publ. 85-37 from Documentation Services, 111-116B, Jet Propulsion Laboratory, 4800 Oak Grove Drive, Pasadena, CA 91109.
    Additional Material: 2 Tab.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/kin.550171010
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  • 7
    Electronic Resource
    Electronic Resource
    Fluidized-Bed reactor model verification on a reactor of industrial scale (1987)
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 33 (1987), S. 619-627 
    Details
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Previous published comparisons between fluidized-bed reactor models and experimental data have almost exclusively been in laboratory and pilot-plant scale equipment. This paper compares data obtained in an industrial phthalic anhydride reactor of 2. 13 m dia. using naphthalene as the feedstock with three models, the Kato and Wen bubble-assemblage model, the Kunii and Levenspiel three-phase bubbling-bed model, and Grace's two-phase bubbling-bed model. For the conditions of operation (U = 0.43 m/s, d̄p = 53 μm, H = 7.9 m, T = 636 K), all three models give similar predictions and each gives a good overall prediction of the conversion and selectivity if the reaction kinetics are based on the early study of DeMaria et al. (1961). Hydrodynamic parameters needed for the models are calculated from equations available in the literature. Grid and freeboard effects appear to play relatively minor roles in determining the overall conversion and yields for the reactor in question.
    Additional Material: 12 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/aic.690330410
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  • 8
    Electronic Resource
    Electronic Resource
    Global phase behavior of mixtures of short and long n-alkanes (1988)
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 34 (1988), S. 834-839 
    Details
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The perturbed-hard-chain model of Beret, Donohue, and Prausnitz, in the simplified version of Kim et al., is compared with recent VLE data on mixtures of ethane and n-alkanes with carbon numbers from 16 to 24. By using and extrapolating the linear relations between the three adjustable model parameters and the carbon number, as given by Kim et al., we find that the experimental isothermal bubble curves are well represented up to the critical pressure without the use of any adjustable parameters. Experimental Henry constants for ethane in eicosane are well predicted at all temperatures. We find this global model more accurate than the Soave-Redlich-Kwong equation, even if the latter is fitted isotherm-by-isotherm to individual mixtures with temperature-dependent mixing parameters.
    Additional Material: 10 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/aic.690340513
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  • 9
    Electronic Resource
    Electronic Resource
    Monoclonal antibodies against plant proteins recognise animal intermediate filaments (1987)
    New York, NY : Wiley-Blackwell
    Cell Motility and the Cytoskeleton 8 (1987), S. 312-323 
    Details
    ISSN: 0886-1544
    Keywords: plant cytoskeleton ; Chlamydomonas ; anti-IFA ; onion root tip cells ; immunoflurescence ; Life and Medical Sciences ; Cell & Developmental Biology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Medicine
    Notes: Four monoclonal antibodies were raised against polypetides present in a highsalt detergent-insoluble fraction from cells of Chlamydomonas reinhardtii. Indirect immunofluorescence microscopy of fibroblasts and epithelial cells grown in culture using these plant antibodies revealed staining arrays identical to those obtained with well characterised antibodies to animal intermediate filaments. Immunoflurescence microscopy of Chlamydomonas with these monoclonal antibodies and a monoclonal antibody that recognises all animal intermediate filaments (anti-IFA) gave a diffuse, patchy cytoplasmic staining pattern. Both the plant antibodies and anti-IFA stained interphase onion root tip cells in a diffuse perinuclear pattern. In metaphase through to telophase, the labelling patterns colocalised with those of microtubules. Labelling of the phragmoplast was also detected but not staining of the preprophase band. On Western blots of various animal cell lines and tissues, all the antibodies labelled known intermediate filament proteins. On Western blots of whole Chlamydomonas proteins, all the antiboides labelled a broad band in the 57,000 Mr range, and three antibodies labelled bands around 66,000 and 140,000 Mr but with varibale intensites. On Western blots of whole onion root tip proteins, all the antibodies labelled 50,0000 Mr (two to three bands) polypetides and a diffuse and around 60,000 Mr and three of the antibodies also labelled several polypeptides in the 90,000-200,000 Mr range. The consistent labelling of these different bands by several different monoclonal antibodies recognising animal intermediate filaments makes these polypetides putative plant intermediate filament proteins.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/cm.970080404
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  • 10
    Electronic Resource
    Electronic Resource
    An investigation of the high temperature oxidation of a 20% Cr/25% Ni/Nb stainless steel in carbon dioxide using thin layer activationDedicated to Professor Dr. Alfred Rahmel on the occasion of his 60th birthday (1987)
    Weinheim [u.a.] : Wiley-Blackwell
    Materials and Corrosion/Werkstoffe und Korrosion 38 (1987), S. 506-516 
    Details
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: Untersuchung der Hochtemperaturoxidation eines nichtrostenden Stahls (25% Ni/20% Cr/Nb) in Kohlendioxid mit Hilfe der DünnschichtaktivierungDas Verhalten eines nichtrostenden Stahls (25% Ni/20% Cr/Nb) bei der Hochtemperaturkorrosion unter isothermen Bedingungen (Versuchsdauer bis 525 h) in Kohlendioxid bei 900 und 950°C und anschließendem Abkühlen im Ofen wurde gravimetrisch und zusätzlich mittels Dünnschichtaktivierung untersucht. Dazu wurde ein definierter Bereich der Stahloberfläche durch einen Deuteronenstrahl aktiviert, um die Radioisotopen 51Cr, 52Mn, 56Mn, 56Co, 57Co und 58Co zu erzeugen; die Tiefenverteilungen reichten unabhängig voneinander bis 70 μm. Die Messungen der Aktivitätsniveaus der Radioisotopen vor, während und nach der Oxidation sowie unter Berücksichtigung von abgeplatztem Zunder ermöglichen eine Differenzierung der durch Rißbildung im Zunder hervorgerufenen Effekte auf die Oxidationskinetik. Dabei wurde die Beteiligung der einzelnen Radioisotopen in den entstandenen Zundern und den abgeplatzten Zunderteilchen bestimmt.
    Notes: The high temperature oxidation behaviour of a 20% Cr/25% Ni/Nb stainless steel, during isothermal exposures of up to 525 h duration, in carbon dioxide, at 900 and 950°C and on subsequent furnace cooling, has been studied by weight change measurements, in combination with thin layer activation. For this purpose a defined region of the steel was activated by a deuteron beam to produce the radioisotopes 51Cr, 52Mn, 54Mn, 56Co, 57Co and 58Co, with independent depth distributions to 70 μm. Measurements of the activity levels of the radioisotopes before, during and after oxidation, monitored scale spallation, thus enabling effects on the oxidation kinetics due to scale cracking to be distinguished. The involvement of each radioisotope was ascertained in the types of scales formed and in the spall produced.
    Additional Material: 16 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/maco.19870380908
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