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  • Wiley-Blackwell  (2)
  • 1985-1989  (2)
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  • 1
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Salts of Halogenophosphoric Acids. XIV. Preparation and Crystal Structure of Dicopper-potassium-hydroxide-bis(monofluorophosphate) Monohydrate Cu2K(OH)(PO3F)2 · H2OBy the reaction of potassium monofluorophosphate and copper(II) salts in aqueous medium a crystalline, insoluble basic copper potassium monofluorophosphate Cu2K(OH)(PO3F)2 · H2O 1 is formed. The thermal decomposition of 1 has been studied. 1 crystallizes in the monoclinic space group B2/m with a = 9.094 Å, b = 7.755 Å, c = 6.333 Å, α = β = 90°; γ = 117.55°, and Z = 2.
    Notes: Bei der Reaktion von Kaliummonofluorophosphat mit Kupfer(II)-Salzen in wäßriger Lösung bildet sich das basische Kupfer-Kalium-Monofluorophosphat Cu2K(OH)(PO3F)2 · H2O 1 als kristalliner schwerlöslicher Niederschlag. Die thermische Zersetzung von 1 wurde untersucht. 1 kristallisiert in der monoklinen Raumgruppe B2/m mit a = 9,094 Å, b = 7,755 Å, c = 6,333 Å, α = β = 90°, γ = 117,55° und Z = 2.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 543 (1986), S. 199-206 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: On the Reaction of Thiophosphoryl Chloride with Hexamethyl DisilazaneOn the basis of a 31P n.m.r. spectroscopic study of the reaction of PSCl3 with hexamethyl disilazane a method for the preparation of Me3SiNHP(S)Cl2(1) and the diazadiphosphetidine 2, [Me3SiNHP(S)=NSiMe3]2 has been developed. These new crystalline compounds have been characterized by i.r., Raman, 31P n.m.r. and mass spectroscopy, and their thermal behaviour has been studied. The formation and constitution of 2 are discussed, and its 1H and 29Si n.m.r. spectra are reported.
    Notes: Aufgrund orientierender 31P-NMR-Untersuchungen der Reaktion von PSCl3 mit Hexamethyldisilazan (HMDS) wurden Darstellungsmethoden für das Trimethylsilylamid der Dichlorothiophosphorsäure 1, Me3SiNHP(S)Cl2 und das Diazadiphosphetidin 2, [Me3SiNHP(S)=NSiMe3]2 ausgearbeitet. Beide Verbindungen wurden durch ihre IR-, Raman-, 31P-NMR- und Massenspektren charakterisiert und ihr thermisches Verhalten untersucht. Bildung und Konstitution von 2 werden diskutiert und seine 1H- und 29Si-Spektren mitgeteilt.
    Additional Material: 5 Tab.
    Type of Medium: Electronic Resource
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