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  • Wiley-Blackwell  (40)
  • PANGAEA
  • Copernicus
  • 1995-1999  (52)
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Year
  • 1
    Publication Date: 2023-06-27
    Keywords: 16 km ENE Cape Roberts; Cape Roberts Project; Comment; Core wireline system; CRP; CRP-1; CWS; DEPTH, sediment/rock; off Cape Roberts, Ross Sea, Antarctica; Sampling/drilling ice; δ13C, carbonate; δ18O, carbonate; δ18O, water
    Type: Dataset
    Format: text/tab-separated-values, 28 data points
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  • 2
    Publication Date: 2023-06-27
    Keywords: 16 km ENE Cape Roberts; Calcareous fossils; Calcium carbonate; Cape Roberts Project; Chert; Clay minerals; Core wireline system; CRP; CRP-1; CWS; DEPTH, sediment/rock; Heavy minerals; Intrusive, igneous rock; Iron carbonate, siderite; Kalifeldspar; Metamorphite; Mica; off Cape Roberts, Ross Sea, Antarctica; Opaque minerals; Plagioclase; Point counting with SEM/EDAX; Porosity; Pyroxene; Quartz; Sampling/drilling ice; Sedimentary rock; Sulfate; Volcanic glass; Volcanite
    Type: Dataset
    Format: text/tab-separated-values, 171 data points
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  • 3
    Publication Date: 2023-06-27
    Keywords: 16 km ENE Cape Roberts; Calcium carbonate; Cape Roberts Project; Comment; Core wireline system; CRP; CRP-1; CWS; DEPTH, sediment/rock; Energy dispersive X-ray analysis, EDAX; Iron carbonate, siderite; Magnesium carbonate, magnesite; Manganese carbonate, rhodochrosite; off Cape Roberts, Ross Sea, Antarctica; Sampling/drilling ice; Strontium carbonate, strontianite
    Type: Dataset
    Format: text/tab-separated-values, 120 data points
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  • 4
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    Unknown
    PANGAEA
    In:  Supplement to: Fielding, Christopher R; Baker, Julian C; Woolfe, Ken; Howe, John; Lavelle, Mark (1998): Reassessment of the Miocene-Quaternary boundary in CRP-1, Cape Roberts Project, Antarctica. Terra Antartica, 5(3), 425-426, hdl:10013/epic.28334.d001
    Publication Date: 2023-07-10
    Description: During the course of the 1997 drilling campaign, lithostratigraphic boundaries were assigned to the CRP-l core on the basis of perceived changes in lithology. The geologically most important boundary in the core, between the Miocene and overlying Quaternary sections, was placed at 43.55 mbsf. This horizon was described in the core logs (Cape Roberts Science Team, 1998) as a contact between muddy, finegrained sandstone (which were assigned a Lower Miocene age based on diatom biostratigsaphy) and overlying diamictons containing Quaternary diatoms. This boundary is a major unconformity, recognisable on seismic reflection records. As such, it has considerable significance in the ongoing scientific analysis of the drillcore. During a re-examination of the core, focusing on the archive half held at the Antarctic Geology Research Facility of the Florida State University at Tallahassee; the authors noted that the core across the published boundary (43.55 mbsf) did not show any lithological change, but logged a sharp contact between dark olive grey, muddy sandstone and overlying diamicton at 43.15 mbsf (Fig. l). We suggest, therefore, that the core log in appendix l of Cape Roberts Science Team (1998) is misleading over this interval. In order to test the veracity of the suggested boundary revision, a series of thin-sections was examined and point-counted for framework grain abundances.
    Keywords: 16 km ENE Cape Roberts; Calcite; Cape Roberts Project; Chert; Claystone; Core wireline system; CRP; CRP-1; CWS; DEPTH, sediment/rock; Epoch; Grain size, mean radius; Kalifeldspar; Micrite; off Cape Roberts, Ross Sea, Antarctica; Opaque minerals; Plagioclase; Porosity; Pyroxene; Quartz; Sampling/drilling ice; Sorting description; Thin section analysis/measurements; Volcanic glass; Volcanite
    Type: Dataset
    Format: text/tab-separated-values, 75 data points
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  • 5
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    PANGAEA
    In:  EPIC3Terra Antartica, Bremerhaven, PANGAEA, 5(3), pp. 425-426
    Publication Date: 2019-07-17
    Repository Name: EPIC Alfred Wegener Institut
    Type: PANGAEA Documentation , notRev
    Format: application/pdf
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  • 6
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    PANGAEA
    In:  EPIC3Terra Antartica, Bremerhaven, PANGAEA, 5(3), pp. 647-653
    Publication Date: 2019-07-17
    Repository Name: EPIC Alfred Wegener Institut
    Type: PANGAEA Documentation , notRev
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  • 7
    ISSN: 0899-0042
    Keywords: microbial chiral inversion ; 2-phenylpropionic acid ; kinetic isotope effect ; Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Previous investigations have described the development of nongrowing suspension of Verticillium lecanii as a microbial model of the mammalian chiral inversion of the 2-arylpropionic acids (2-APAs). Mechanistic studies in mammals have shown that inversion involves loss of the α-methine proton but retention of the original atoms at the β-methyl position, and a mechanism has been proposed involving enzymatic epimerisation of acyl-CoA thioester derivatives of the substrate. Inversion of the 2-APAs by V. lecanii exhibits extensive intersubstrate variation in the presence, rate, extent, and direction of inversion, which are different from those observed in mammalian systems, possibly indicating differences in the mechanism of inversion between mammalian and microbial cells. This study involved the investigation of proton/deuterium exchange by 1H-nuclear magnetic resonance following incubation of deuterated derivatives of 2-phenylpropionic acid (2-PPA), a model compound, in cell suspensions of V. lecanii and incubation of undeuterated 2-PPA in cell suspensions containing D2O. The results indicated that the inversion of 2-PPA by V. lecanii also involved exchange of the α-methine proton but complete retention on the original atoms at the β-methyl position. No kinetic deuterium isotope effect was observed, indicating that loss of the α-methine proton is not the rate-limiting step of the inversion process. This suggests that the observed differences between microbial and mammalian systems probably involve the stereoselective acyl-CoA thioester formation step and not the subsequent epimerisation of the resultant diastereomers. Chirality 9:254-260, 1997. © 1997 Wiley-Liss, Inc.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Biotechnology and Bioengineering 46 (1995), S. 510-513 
    ISSN: 0006-3592
    Keywords: cephalosporin C ; production of 7ACA ; immobilized D-amino acid oxidase ; immobilized GL-acylase ; industrial enzyme process ; Chemistry ; Biochemistry and Biotechnology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The first large-scale production of 7-aminocephalosporanic acid (7ACA) from cephalosporin C (CPC) using a wholly enzymatic synthesis method is reported here. We produced 7ACA from CPC in as high a molar yield as 85% using the immobilized enzymes D-amino acid oxidase (D-AOD) and glutaryl-7-ACA acylase (GL-acylase). In the first reactor, CPC is converted to keto-adipyl-7-aminocephalosporanic acid (keto-7ACA) using an immobilized D-AOD isolated from a yeast, Trigonopsis variabilis. The keto-7ACA is then spontaneously converted to glutaryl-7-aminocephalosporanic acid (GL-7ACA) via a chemical reaction with hydrogen peroxide. The hydrogen peroxide is also a product of the D-AOD reaction. Near quantitative conversion of the keto-7ACA to GL-7ACA was observed. The second reactor converts GL-7ACA to 7ACA using an immobilized GL-acylase, which was isolated from a reconbinant Escherichia coli. The final 7ACA crystalline product is a high quality product. The reactions are conducted under very mild aqueous conditions: pH 8.0 and 20° to 25°C. The production of desacetyl side products is minimal. This process is currently being implemented on an industrial scale to produce 7ACA. © 1995 John Wiley & Sons, Inc.
    Additional Material: 4 Tab.
    Type of Medium: Electronic Resource
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  • 9
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Rapid Communications in Mass Spectrometry 9 (1995), S. 1087-1094 
    ISSN: 0951-4198
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Physics
    Notes: A pneumatically assisted electrospray liquid chromatography/mass spectrometry interface has been modified for use with open-tubular supercritical fluid chromatography (SFC). The modified interface houses the SFC flow restrictor within the spray device. A sheath-flow liquid of methanol or methanol/water containing ammonium acetate flows coaxially to the restrictor. The addition of the sheath-flow liquid results in the ionization of analytes known to be in a neutral charge state during the chromatographic separation. The sheath-flow liquid also allows for the independent operation of the chromatograph and the mass spectrometer. Both could be operated under optimum conditions. The operation of the interface was optimized using a solution of poly(dimethylsiloxane) in CO2 introduced by continuous infusion. We also report the application of the modified instrument to samples containing amines and propoxylated alcohols.
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
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  • 10
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Macromolecular Rapid Communications 17 (1996), S. 409-415 
    ISSN: 1022-1336
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: A side-by-side diffusion cell was used to study the permeability of glucose through a temperature- and pH-sensitive poly(N-isopropylacrylamide-co-methacrylic acid) hydrogel membrane. At fixed temperature (37°C), lowering pH in one side of the cell induced hydrogel volume collapse and strongly attenuated glucose permeation across the membrane. Hysteresis was observed in the glucose permeability versus pH characteristic.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
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