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  • 1
    Publication Date: 2012-04-15
    Description: The electro-Fenton (EF) process is a promising method combining electrochemical reactions and Fenton's reagent. In this hybrid process, the electrical current induces the in situ generation of H 2 O 2 via reduction of oxygen, and the catalytic reaction is propagated by Fe 2+ regeneration, which can take place by reduction of Fe 3+ with H 2 O 2 , hydroperoxyl radical, organic radical intermediates, or directly at the cathode. Recent advances in the EF process are discussed and several key variables analyzed, including electrode material, initial pH, and Fenton's reagents, in order to extend the applicability of this technology. A brief survey of the electro-Fenton (EF) process for the removal of different pollutants is presented. Special attention is focused on improving the technology by optimization of the fundamental variables governing the process, including pH, electrode material, and identity of Fenton's reagents in order to extend the applicability of this process.
    Print ISSN: 0930-7516
    Electronic ISSN: 1521-4125
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Published by Wiley
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  • 2
    Publication Date: 2012-03-07
    Description: The electro-Fenton (EF) process is a promising method combining electrochemical reactions and Fenton's reagent. In this hybrid process, the electrical current induces the in situ generation of H 2 O 2 via reduction of oxygen, and the catalytic reaction is propagated by Fe 2+ regeneration, which can take place by reduction of Fe 3+ with H 2 O 2 , hydroperoxyl radical, organic radical intermediates, or directly at the cathode. Recent advances in the EF process are discussed and several key variables analyzed, including electrode material, initial pH, and Fenton's reagents, in order to extend the applicability of this technology. A brief survey of the electro-Fenton (EF) process for the removal of different pollutants is presented. Special attention is focused on improving the technology by optimization of the fundamental variables governing the process, including pH, electrode material, and identity of Fenton's reagents in order to extend the applicability of this process.
    Print ISSN: 0930-7516
    Electronic ISSN: 1521-4125
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Published by Wiley
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 3
    Publication Date: 2011-11-04
    Description: Diesel fuel may be released into soil due to anthropogenic activities, such as accidental spills or leaks in underground storage tanks or pipelines. Since diesel fuel is mainly composed of hydrophobic organic compounds, it has low water solubility. Therefore, treating contaminated areas with conventional techniques is difficult. In this study, electrokinetic treatment of soil contaminated with diesel fuel was carried out. Two different hybrid approaches to pollutant removal were tested. A surfactant was used as a processing fluid during electrokinetic treatment to increase desorption and the solubility of diesel fuel. Additionally, a hybrid technology combining a Fenton reaction and electrokinetic remediation (EK-Fenton) was tested in an attempt to generate favorable in situ degradation of pollutants. The efficiency of each treatment was determined based on diesel fuel removal. After 30 days of treatment, the highest removal of diesel fuel was found to be achieved with the EK-Fenton process. Several approaches to the electrokinetic treatment of soil polluted with diesel fuel were evaluated. The use of surfactants as processing fluid was tested with the aim of increasing desorption and the solubility of diesel fuel, leading to improved removal by electroosmosis. Additionally, the EK-Fenton process was investigated as a method of promoting in situ degradation of diesel fuel.
    Print ISSN: 0930-7516
    Electronic ISSN: 1521-4125
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Published by Wiley
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 4
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