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  • 1
    Publication Date: 2013-09-11
    Description: [1]  Low planktic and benthic δ 18 O and δ 13 C values in sediments from the Nordic seas of cold stadials of the last glaciation have been attributed to brines, formed similar to modern ones in the Arctic Ocean. To expand on the carbon isotopes of this hypothesis I investigated benthic δ 13 C from the modern Arctic Ocean. I show that mean δ 13 C values of live epibenthic foraminifera from the deep Arctic basins are higher than mean δ 13 C values of upper slope epibenthic foraminifera. This agrees with mean high δ 13 C values of dissolved inorganic carbon (DIC) in Arctic Bottom Water (ABW), which are higher than mean δ 13 C DIC values from shallower water masses of mainly Atlantic origin. However, adjustments for oceanic 13 C-Suess depletion raise subsurface and intermediate water δ 13 C DIC values over ABW δ 13 C DIC ones. Accordingly, during preindustrial Holocene times, the δ 13 C DIC of ABW was as high or higher than today, but lower than the δ 13 C DIC of younger subsurface and intermediate water. If brine-enriched water significantly ventilated ABW, brines should have had high δ 13 C DIC values. Analogously, high-δ 13 C DIC brines may have been formed in the Nordic seas during warm interstadials. During cold stadials, when most of the Arctic Ocean was perennially sea-ice covered, a cessation of high-δ 13 C DIC brine rejection may have lowered δ 13 C DIC values of ABW, and ultimately the δ 13 C DIC in Nordic seas intermediate and deep water. So, in contrast to the idea of enhanced brine formation during cold stadials, the results of this investigation imply that a cessation of brine rejection would be more likely.
    Print ISSN: 0883-8305
    Electronic ISSN: 1944-9186
    Topics: Geosciences
    Published by Wiley on behalf of American Geophysical Union (AGU).
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  • 2
    Publication Date: 2016-03-05
    Description: Planktic foraminiferal Mg/Ca ratios have become a fundamental seawater temperature proxy in past climate reconstructions, due to the temperature dependence of Mg uptake into foraminiferal calcite. However, empirical calibrations for single species from methodologically consistent data are still lacking. Here we present species-specific calibrations of Mg/Ca vs. calcification temperature for two commonly used species of planktic foraminifera: Globigerina bulloides and Neogloboquadrina pachyderma left, based on a series of Southern Ocean and North Atlantic core tops. Combining these new data with previously published data, we derive an integrated G. bulloides Mg/Ca-temperature calibration for mid and high latitudes of both hemispheres between 2 - 18°C, where Mg/Ca = 1.006 ± 0.032 * e 0.065 ± 0.003*Tiso (R 2 = 0.82). G. bulloides is found to calcify deeper in the Southern Ocean (∼ 200 m) than in the North Atlantic (top 50 m). We also propose a Mg/Ca temperature calibration to describe the temperature response in N. pachyderma left that calcified away from the influence of sea ice in the Southern Ocean, valid between ∼ -1 and 9°C, of the form Mg/Ca = 0.580 ± 0.016 * e 0.084 ± 0.006*Tiso (R 2 = 0.70). These calibrations account for uncertainties on Mg/Ca measurements and calcification temperature that were carefully estimated and propagated using Monte Carlo iterations. The 1σ propagated error in Mg/Ca-derived temperatures is 1.1°C for G. bulloides and 0.9°C for N. pachyderma left for the presented datasets. Geographical extension of genotypes must be assessed when choosing to develop regional or global calibrations. This article is protected by copyright. All rights reserved.
    Electronic ISSN: 1525-2027
    Topics: Chemistry and Pharmacology , Geosciences , Physics
    Published by Wiley on behalf of American Geophysical Union (AGU).
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  • 3
    Publication Date: 2016-03-10
    Description: We discuss water oxygen isotopes (δ 18 O w ) and carbon isotopes of dissolved inorganic carbon (δ 13 C DIC ) of brine-enriched shelf water (BSW) from Storfjorden (southern Svalbard) in comparison to Recent benthic foraminiferal δ 18 O c and δ 13 C c calcified in the same water. We determined relatively high δ 18 O w values of 0.15±0.03‰ VSMOW in BSW below sill depth at temperatures below −1.8 °C, and high δ 18 O c values of 3.90±0.18‰ VPDB. Such high BSW δ 18 O w cannot significantly deplete 18 O w contents of Arctic Ocean deep water; furthermore, such high δ 18 O c cannot be distinguished from δ 18 O c values of 3.82±0.12‰, calcified in warmer Arctic and Nordic seas intermediate and deeper waters. Today, in Storfjorden low benthic δ 13 C c and high δ 18 O c reflect the low δ 13 C DIC and relatively high δ 18 O w of BSW. High benthic δ 18 O c is in contrast to expected low δ 18 O c as brine rejection is widely thought to predominantly take place in surface water diluted by meteoric water with very low δ 18 O w . Low epibenthic δ 13 C c values of 0.50±0.12‰ partly reflect low δ 13 C DIC caused by enhanced uptake of atmospheric low δ 13 C CO 2 decreased by anthropogenic activities. An adjustment for preindustrial higher values would increase δ 13 C c by about 0.6‰. Therefore, in Storfjorden brine formed before the industrial era would be characterized by both high δ 13 C c as well as high δ 18 O c values of benthic foraminiferal calcite. Our data may cast doubt on scenarios that explain negative excursions in benthic foraminiferal stable isotope records from the Atlantic Ocean during cold stadials in the last glacial period by enhanced brine formation in Nordic seas analogously to modern processes in Storfjorden.
    Print ISSN: 0300-9483
    Electronic ISSN: 1502-3885
    Topics: Geography , Geosciences
    Published by Wiley
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  • 4
    Publication Date: 2011-02-23
    Description: Two SST records based on Mg/Ca of G. ruber (pink) from the continental slope off West Africa at 15°N and 12°N shed new light on the thermal bipolar seesaw pattern in the northeastern tropical Atlantic during periods of reduced Atlantic Meridional Overturning Circulation (AMOC) associated with Heinrich stadials H1 to H6. The two records indicate that the latitudinal position of the bipolar seesaw's zero-anomaly line, between cooling in the North and warming in the South, gradually shifted southward from H6 to H1. A conceptual model is presented that aims to provide a physically consistent mechanism for the southward migration of the seesaw's fulcrum. The conceptual model suggests latitudinal movements of the Intertropical Convergence Zone, driven by a combination of orbital-forced changes in the meridional temperature gradient within the realm of the Hadley cell and the expansion of the Northern Hemisphere cryosphere, as a major factor.
    Print ISSN: 0094-8276
    Electronic ISSN: 1944-8007
    Topics: Geosciences , Physics
    Published by Wiley on behalf of American Geophysical Union (AGU).
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  • 5
    Publication Date: 2013-01-03
    Description: [1]  The composition of the Fram Strait freshwater outflow is investigated by comparing 10 sections of concurrent salinity, δ 18 O, nitrate and phosphate measurements collected between 1997 and 2011. The largest inventories of net sea ice meltwater are found in 2009, 2010 and 2011. The 2009–2011 sections are also the first to show positive fractions of sea ice meltwater at the surface near the core of the EGC. Sections from September 2009–2011 show an increased input of sea ice meltwater at the surface relative to older September sections. This suggests that more sea ice now melts back into the surface in late summer than previously. Comparison of April, July and September sections reveals seasonal variations in the inventory of positive sea ice meltwater, with maximum inventories in September sections. The time series of sections reveals a strong anti-correlation between meteoric water and net sea ice meltwater inventories, suggesting that meteoric water and brine may be delivered to Fram Strait together from a common source. We find that the freshwater outflow at Fram Strait exhibits a similar meteoric water to net sea ice meltwater ratio as the central Arctic Ocean and Siberian shelves, suggesting that much of the sea ice meltwater and meteoric water at Fram Strait may originate from these regions. However, we also find that the ratio of meteoric water to sea ice meltwater inventories at Fram Strait is decreasing with time, due to an increased surface input of sea ice meltwater in recent sections.
    Print ISSN: 0148-0227
    Topics: Geosciences , Physics
    Published by Wiley on behalf of American Geophysical Union (AGU).
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  • 6
    Publication Date: 2011-04-06
    Description: Studies of temporal changes of ocean circulation and deepwater ventilation often rely on δ13C records of epibenthic foraminifer Cibicidoides wuellerstorfi. However, primary productivity-related overprints may distort the signal and simulate a chemical age of ambient water mass that is too old and simulates poorly ventilated ambient bottom waters. To further constrain the use of C. wuellerstorfi δ13C records from high-productivity areas, we analyzed a 14CAMS-dated gravity core from the upwelling regime off northwest Africa at 12°N. We compare this new record with 37 radiocarbon dated δ13C records from the eastern Atlantic Ocean between 45°N and 25°S that are bathed by the same water mass. Only during Heinrich events 1 and 2, when the investigated core site off northwest Africa experienced year-round, sustained deposition of organic matter, the δ13C values at this site faithfully record deepwater ventilation states. During times of predominantly seasonal deposition of fresh phytodetritus, however, δ13C values were significantly lower than at the reference sites. This underscores that reconstruction of paleocirculation and deep ocean ventilation using C. wuellerstorfi δ13C from regions that experienced seasonal phytodetritus deposition needs to be validated by additional proxies that are not affected by local productivity.
    Print ISSN: 0883-8305
    Electronic ISSN: 1944-9186
    Topics: Geosciences
    Published by Wiley on behalf of American Geophysical Union (AGU).
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  • 7
    Publication Date: 2019
    Description: Abstract Foraminifera are commonly used in paleoclimate reconstructions as they occur throughout the world's oceans and are often abundantly preserved in the sediments. Traditionally, foraminifera‐based proxies like δ18O and Mg/Ca are analyzed on pooled specimens of a single species. Analysis of single specimens of foraminifera allows reconstructing climate variability on timescales related to El Niño–Southern Oscillation or seasonality. However, quantitative calibrations between the statistics of individual foraminifera analyses (IFA) and climate variability are still missing. We performed Mg/Ca and δ18O measurements on single specimens from core top sediments from different settings to better understand the signal recorded by individual foraminifera. We used three species of planktic foraminifera (Globigerinoides ruber (s.s.), T. sacculifer, and N. dutertrei) from the Indo‐Pacific Warm Pool and one species (G. ruber (pink)) from the Gulf of Mexico. Mean values for the different species of Mg/Ca versus calculated δ18O temperatures agree with published calibration equations. IFA statistics (both mean and standard deviation) of Mg/Ca and δ18O between the different sites show a strong relationship indicating that both proxies are influenced by a common factor, most likely temperature variations during calcification. This strongly supports the use of IFA to reconstruct climate variability. However, our combined IFA data for the different species only show a weak relationship to seasonal and interannual temperature changes, especially when seasonal variability increases at a location. This suggests that the season and depth habitat of the foraminifera strongly affect IFA variability, such that ecology needs to be considered when reconstructing past climate variability.
    Print ISSN: 0883-8305
    Electronic ISSN: 2572-4525
    Topics: Geosciences
    Published by Wiley on behalf of American Geophysical Union (AGU).
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  • 8
    Publication Date: 2017-08-29
    Description: Negative stable carbon isotopic excursions have been observed throughout most of the mid-depth (~1000–3000m) Atlantic Ocean during Heinrich Stadial 1 (HS1) and the Younger Dryas (YD). Although there is agreement that these mid-depth excursions were in some way associated with a slowdown of the Atlantic Meridional Overturning Circulation (AMOC), there is still no consensus on the precise mechanism(s). Here, we present benthic stable carbon and oxygen isotopic (δ 13 C and δ 18 O) records from five cores from the western equatorial Atlantic (WEA). Together with published benthic isotopic records from nearby cores, we produced a WEA depth transect (~800–2500m). We compare HS1 and YD data from this transect with data from previously published North- and South Atlantic cores and demonstrate that the largest negative δ 13 C excursions occurred in the WEA during these times. Moreover, our benthic δ 18 O records require the presence of two water masses flowing from the Southern Ocean, bisected by a Northern Component Water (NCW). Given that δ 18 O is a conservative water mass tracer, we suggest that δ 13 C was decoupled from water mass composition and does not correspond to simple alternations between northern and southern sourced waters. Instead, δ 13 C behaved non-conservatively during HS1 and the YD. Consistently with our new 231 Pa/ 230 Th record from the WEA transect, that allowed the reconstruction of AMOC strength, we hypothesize that the negative δ 13 C excursions reflect an increase in the residence time of NCW in response to a weakened AMOC, allowing for a marked accumulation of 13 C-depleted respired carbon at the mid-depth WEA.
    Print ISSN: 0883-8305
    Electronic ISSN: 1944-9186
    Topics: Geosciences
    Published by Wiley on behalf of American Geophysical Union (AGU).
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  • 9
    Publication Date: 2017-10-29
    Description: The Eastern Equatorial Pacific (EEP) is a key area to understand past oceanic processes that control atmospheric CO 2 concentrations. Many studies argue for higher nutrient concentrations by enhanced nutrient transfer via Southern Ocean Intermediate Water (SOIW) to the low-latitude Pacific during glacials. Recent studies, however, argue against SOIW as the primary nutrient source, at least during early Marine Isotope Stage 2 (MIS 2), as proxy-data indicate that nutrients are better utilized in the Southern Ocean under glacial conditions. New results from the subarctic Pacific suggest that enhanced convection of nutrient-rich Glacial North Pacific Intermediate Water (GNPIW) contributes to changes in nutrient concentrations in equatorial sub-thermocline water masses during MIS 2. However, the interplay between SOIW versus GNPIW and its influence on the nutrient distribution in the EEP spanning more than one glacial cycle are still not understood. We present a carbon isotope (δ 13 C) record of sub-thermocline waters derived from deep-dwelling planktonic foraminifera Globorotaloides hexagonus in the EEP, which is compared with published δ 13 C records around the Pacific. Results indicate enhanced influence of GNPIW during MIS 6 and MIS 2 compared to today with largest contributions of northern-sourced intermediate waters during glacial maxima. These observations suggest a mechanistic link between relative contributions of northern and southern intermediate waters and past EEP nutrient concentrations. A switch from increased GNPIW (decreased SOIW) to diminished GNPIW (enhanced SOIW) influence on equatorial sub-thermocline waters is recognized during glacial terminations and marks changes to modern-like conditions in nutrient concentrations and biological productivity in the EEP.
    Print ISSN: 0883-8305
    Electronic ISSN: 1944-9186
    Topics: Geosciences
    Published by Wiley on behalf of American Geophysical Union (AGU).
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  • 10
    Publication Date: 2017-05-13
    Description: The carbon isotope composition (δ 13 C) of seawater provides valuable insight on ocean circulation, air-sea exchange, the biological pump and the global carbon cycle, and is reflected by the δ 13 C of foraminifera tests. Here, more than 1,700 δ 13 C observations of the benthic foraminifera genus Cibicides from late Holocene sediments (δ 13 C Cibnat ) are compiled and compared with newly updated estimates of the natural (pre-industrial) water-column δ 13 C of dissolved inorganic carbon (δ 13 C DICnat ) as part of the international Ocean Circulation and Carbon Cycling (OC3) project. Using selection criteria based on the spatial distance between samples we find high correlation between δ 13 C Cibnat and δ 13 C DICnat , confirming earlier work. Regression analyses indicate significant carbonate ion (-2.6 ± 0.4)×10 -3 ‰/(μmol kg -1 ) [CO 3 2- ] and pressure (-4.9 ± 1.7)×10 -3 ‰ m -1 (depth) effects, which we use to propose a new global calibration for predicting δ 13 C DICnat from δ 13 C Cibnat . This calibration is shown to remove some systematic regional biases and decrease errors compared with the one-to-one relationship (δ 13 C DICnat = δ 13 C Cibnat ). However, these effects and the error reductions are relatively small, which suggests that most conclusions from previous studies using a one-to-one relationship remain robust. The remaining standard error of the regression is generally σ ≅ 0.25 ‰, with larger values found in the southeast Atlantic and Antarctic (σ ≅ 0.4 ‰) and for species other than Cibicides wuellerstorfi . Discussion of species effects and possible sources of the remaining errors may aid future attempts to improve the use of the benthic δ 13 C record.
    Print ISSN: 0883-8305
    Electronic ISSN: 1944-9186
    Topics: Geosciences
    Published by Wiley on behalf of American Geophysical Union (AGU).
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