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  • 1
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    AGU (American Geophysical Union) | Wiley
    In:  Global Biogeochemical Cycles, 31 (5). pp. 836-849.
    Publication Date: 2020-02-06
    Description: Primary productivity is limited by the availability of nitrogen (N) in most of the coastal Arctic, as a large portion of N is released by the spring freshet and completely consumed during the following summer. Thus, understanding the fate of riverine nitrogen is critical to identify the link between dissolved nitrogen dynamic and coastal primary productivity to foresee upcoming changes in the Arctic seas, such as increase riverine discharge and permafrost thaw. Here, we provide a field-based study of nitrogen dynamic over the Laptev Sea shelf based on isotope geochemistry. We demonstrate that while most of the nitrate found under the surface fresh water layer is of remineralized origin, some of the nitrate originates from atmospheric input and was probably transported at depth by the mixing of brine-enriched denser water during sea-ice formation. Moreover, our results suggest that riverine dissolved organic nitrogen (DON) represents up to 6 times the total riverine release of nitrate and that about 62 to 76% of the DON is removed within the shelf waters. This is a crucial information regarding the near-future impact of climate change on primary productivity in the Eurasian coastal Arctic.
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  • 2
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    AGU (American Geophysical Union) | Wiley
    In:  Geochemistry, Geophysics, Geosystems, 17 (1). pp. 56-64.
    Publication Date: 2019-02-01
    Description: Export of brine-enriched water from Siberian shelves is thought to be a key parameter in maintaining the Arctic Halocline, which isolates the fresh and cold surface water from the warm Atlantic water and thus prevent dramatic change in the Arctic sea-ice thermodynamic. In this study, we used five years of oxygen isotope and hydrological summer surveys to better understand the factors controlling the brine inventory and distribution over the Laptev Sea shelf. The inventory was maximal in 2011 and 2007 and minimal in 2010. The brine inventory interannual variations are coherent with the winter Arctic Oscillation index that was maximal in 2011 and 2007 and minimal in 2010, which is known to modulate Arctic winds and sea-ice export pattern. While we should remain cautious since our record is limited to 5-years, our results suggest that the combined effect of the Arctic Oscillation and of the Arctic Dipole is the main factor controlling the annual variations in the inventory of brine-enriched waters from the Laptev Sea shelf between 2007 and 2011, especially during extreme negative Arctic Oscillation and Arctic Dipole conditions as in 2010.
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  • 3
    Publication Date: 2019-09-23
    Description: A multiyear mooring record (2007–2014) and satellite imagery highlight the strong temperature variability and unique hydrographic nature of the Laptev Sea. This Arctic shelf is a key region for river discharge and sea ice formation and export and includes submarine permafrost and methane deposits, which emphasizes the need to understand the thermal variability near the seafloor. Recent years were characterized by early ice retreat and a warming near-shore environment. However, warming was not observed on the deeper shelf until year-round under-ice measurements recorded unprecedented warm near-bottom waters of +0.6°C in winter 2012/2013, just after the Arctic sea ice extent featured a record minimum. In the Laptev Sea, early ice retreat in 2012 combined with Lena River heat and solar radiation produced anomalously warm summer surface waters, which were vertically mixed, trapped in the pycnocline, and subsequently transferred toward the bottom until the water column cooled when brine rejection eroded stratification.
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  • 4
    Publication Date: 2019-09-23
    Description: A sediment core from the West Spitsbergen continental margin was studied to reconstruct climate and paleoceanographic variability during the last ~9 ka in the eastern Fram Strait. Our multiproxy evidence suggests that the establishment of the modern oceanographic configuration in the eastern Fram Strait occurred stepwise, in response to the postglacial sea-level rise and the related onset of modern sea-ice production on the shallow Siberian shelves. The late Early and Mid Holocene interval (9 to 5 ka) was generally characterized by relatively unstable conditions. High abundance of the subpolar planktic foraminifer species Turborotalita quinqueloba implies strong intensity of Atlantic Water (AW) inflow with high productivity and/or high AW temperatures, resulting in a strong heat flux to the Arctic. A series of short-lived cooling events (8.2, 6.9. and 6.1 ka) occurred superimposed on the warm late Early and Mid Holocene conditions. Our proxy data imply that simultaneous to the complete postglacial flooding of Arctic shallow shelves and the initiation of modern sea-ice production, strong advance of polar waters initiated modern oceanographic conditions in the eastern Fram Strait at ~5.2 ka. The Late Holocene was marked by the dominance of the polar planktic foraminifer species Neogloboquadrina pachyderma, a significant expansion of sea ice/icebergs, and strong stratification of the water column. Although planktic foraminiferal assemblages as well as sea surface and subsurface temperatures suggest a return of slightly strengthened advection of subsurface Atlantic Water after 3 ka, a relatively stable cold-water layer prevailed at the sea surface and the study site was probably located within the seasonally fluctuating marginal ice zone during the Neoglacial period.
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  • 5
    Publication Date: 2019-09-23
    Description: Hydrographic and stable isotope (δ18O) data from 4 summer surveys in the Laptev Sea are used to derive fractions of sea-ice meltwater and river water. Sea-ice meltwater fractions are found to be correlated to river water fractions. While initial heat of river discharge is too small to melt the observed 0-158 km3 of sea-ice meltwater, arctic rivers contain suspended particles (SPM) and colored dissolved organic material (CDOM) that preferentially absorb solar radiation. Accordingly heat content in surface waters is correlated to river water fractions. But in years when river water is largely absent within the surface layer absolute heat content values increase to considerably higher values with extended exposure time to solar radiation and sensible heat. Nevertheless no net sea-ice melting is observed on the shelf in years when river water is largely absent within the surface layer. The total freshwater volume of the central-eastern Laptev Sea (72-76°N, 122-140°E) varies between ~1000-1500 km3 (34.92 reference salinity). It is dominated by varying river water volumes (~1300-1800 km3) reduced by an about constant freshwater deficit (~350-400 km3) related to sea-ice formation. Net sea-ice melt (~109-158 km3) is only present in years with high river water budgets. Intermediate to bottom layer (〉25 salinities) contain ~60% and 30% of the river budget in years with low and high river budgets, respectively. The average mean residence time of shelf waters was ~2-3 years during 2007-2009.
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  • 6
    Publication Date: 2017-04-10
    Description: Five years of oxygen isotope and hydrological surveys reveal interannual variations in the inventory and distribution of river water over the Laptev Sea. In 2007, 2009, and 2010 relatively low amounts of river water (≤1500 km3) were found and were mostly located in the southeastern Laptev Sea. In 2008 and 2011, high amounts of river water (~1600 km3 and ~2000 km3) were found, especially in the central and northern part of the shelf, suggesting a northward export of this water. This temporal pattern is coherent with the summer Arctic Dipole index that was higher in 2008 and 2011. Our results suggest that the Arctic Dipole might influence the export of river water from the Laptev Sea. Moreover, the river water inventory in the Laptev Sea seems related to the freshwater content of the Arctic Ocean with a 2 years lag.
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  • 7
    Publication Date: 2022-03-09
    Description: Large gradients and inter annual variations on the Laptev Sea shelf prevent the use of uniform property ranges for a classification of major water masses. The central Laptev Sea is dominated by predominantly marine waters, locally formed polynya waters and riverine summer surface waters. Marine waters enter the central Laptev Sea from the northwestern Laptev Sea shelf and originate from the Kara Sea or the Arctic Ocean halocline. Local polynya waters are formed in the Laptev Sea coastal polynyas. Riverine summer surface waters are formed from Lena river discharge and local melt. We use a principal component analysis (PCA) in order to assess the distribution and importance of water masses within the Laptev Sea. This mathematical method is applied to hydro-chemical summer datasets from the Laptev Sea from five years and allows to define water types based on objective and statistically significant criteria. We argue that the PCA derived water types are consistent with the Laptev Sea hydrography and indeed represent the major water masses on the central Laptev Sea shelf. Budgets estimated for the thus defined major Laptev Sea water masses indicate that freshwater inflow from the western Laptev Sea is about half or in the same order of magnitude as freshwater stored in locally formed polynya waters. Imported water dominates the nutrient budget in the central Laptev Sea; and only in years with enhanced local polynya activity is the nutrient budget of the locally formed water in the same order as imported nutrients.
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  • 8
    Publication Date: 2023-02-08
    Description: A major surface circulation feature of the Arctic Ocean is the Transpolar Drift (TPD), a current that transports river‐influenced shelf water from the Laptev and East Siberian Seas toward the center of the basin and Fram Strait. In 2015, the international GEOTRACES program included a high‐resolution pan‐Arctic survey of carbon, nutrients, and a suite of trace elements and isotopes (TEIs). The cruises bisected the TPD at two locations in the central basin, which were defined by maxima in meteoric water and dissolved organic carbon concentrations that spanned 600 km horizontally and ~25‐50 m vertically. Dissolved TEIs such as Fe, Co, Ni, Cu, Hg, Nd, and Th, which are generally particle‐reactive but can be complexed by organic matter, were observed at concentrations much higher than expected for the open ocean setting. Other trace element concentrations such as Al, V, Ga, and Pb were lower than expected due to scavenging over the productive East Siberian and Laptev shelf seas. Using a combination of radionuclide tracers and ice drift modeling, the transport rate for the core of the TPD was estimated at 0.9 ± 0.4 Sv (106 m3 s‐1). This rate was used to derive the mass flux for TEIs that were enriched in the TPD, revealing the importance of lateral transport in supplying materials beneath the ice to the central Arctic Ocean and potentially to the North Atlantic Ocean via Fram Strait. Continued intensification of the Arctic hydrologic cycle and permafrost degradation will likely lead to an increase in the flux of TEIs into the Arctic Ocean.
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  • 9
    Publication Date: 2023-02-08
    Description: Neogloboquadrina pachyderma is the dominant species of planktonic foraminifera found in polar waters and is therefore invaluable for paleoceanographic studies of the high latitudes. However, the geochemistry of this species is complicated due to the development of a thick calcite crust in its final growth stage and at greater depths within the water column. We analyzed the in situ Mg/Ca and δ18O in discrete calcite zones using LA‐ICP‐MS, EPMA and SIMS within modern N. pachyderma shells from the highly dynamic Fram Strait and the seasonally isothermal/isohaline Irminger Sea. Here we compare shell geochemistry to the measured temperature, salinity and δ18Osw in which the shells calcified to better understand the controls on N. pachyderma geochemical heterogeneity. We present a relationship between Mg/Ca and temperature in N. pachyderma lamellar calcite that is significantly different than published equations for shells that contained both crust and lamellar calcite. We also document highly variable SIMS δ18O results (up to a 3.3‰ range in single shells) on plankton tow samples which we hypothesize is due to the granular texture of shell walls. Finally, we document that the δ18O of the crust and lamellar calcite of N. pachyderma from an isothermal/isohaline environment are indistinguishable from each other, indicating that shifts in N. pachyderma δ18O are primarily controlled by changes in environmental temperature and/or salinity rather than differences in the sensitivities of the two calcite types to environmental conditions.
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  • 10
    Publication Date: 2023-05-04
    Description: The first full transarctic section of 228Ra in surface waters measured during GEOTRACES cruises PS94 and HLY1502 (2015) shows a consistent distribution with maximum activities in the Transpolar Drift. Activities in the central Arctic have increased from 2007 through 2011 to 2015. The increased 228Ra input is attributed to stronger wave action on shelves resulting from a longer ice‐free season. A concomitant decrease in the 228Th/228Ra ratio likely results from more rapid transit of surface waters depleted in 228Th by scavenging over the shelf. The 228Ra activities observed in intermediate waters (〈 1500m) in the Amundsen Basin are explained by ventilation with shelf water on a time scale of about 15‐18 years, in good agreement with estimates based on SF6 and 129I/236U. The 228Th excess below the mixed layer up to 1500m depth can complement 234Th and 210Po as tracers of export production, after correction for the inherent excess resulting from the similarity of 228Ra and 228Th decay times. We show with a Th/Ra profile model that the 228Th/228Ra ratio below 1500m is inappropriate for this purpose because it is a delicate balance between horizontal supply of 228Ra and vertical flux of particulate 228Th. The accumulation of 226Ra in the deep Makarov Basin is not associated with an accumulation of Ba and can therefore be attributed to supply from decay of 230Th in the bottom sediment. We estimate a ventilation time of 480 years for the deep Makarov‐Canada Basin, in good agreement with previous estimates using other tracers.
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