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  • 1
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 114 (2001), S. 3809-3816 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: The behavior of tethered polymers on gel/gel adhesion is studied with the single-chain mean-field (SCMF) theory. It is shown that the gel surface structure, the gel/gel adhesion strength, the equilibrium gel/gel distance, and the detailed interface structures can be tailored by specifically designed tethered layers on gel surfaces. The SCMF theory allows to study the effect of various variables of tethered layers, such as the surface coverage, the attraction between polymers and gels, and the composition of block copolymers. These theoretical results provide guidelines for experimental designs of novel gel materials with tethered layers. © 2001 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 2
    ISSN: 1089-7623
    Source: AIP Digital Archive
    Topics: Physics , Electrical Engineering, Measurement and Control Technology
    Notes: We describe a laser heated diamond anvil cell system at the GeoSoilEnviroCARS sector at the Advanced Photon Source. The system can be used for in situ x-ray measurements at simultaneously ultrahigh pressures (to 〉150 GPa) and ultrahigh temperatures (to 〉4000 K). Design goals of the laser heating system include generation of a large heating volume compared to the x-ray beam size, minimization of the sample temperature gradients both radially and axially in the diamond anvil cell, and maximization of heating stability. The system is based on double-sided laser heating technique and consists of two Nd:YLF lasers with one operating in TEM00 mode and the other in TEM01* mode, optics to heat the sample from both sides, and two spectroradiometric systems for temperature measurements on both sides. When combined with an x-ray microbeam (3–10 μm) technique, a temperature variation of less than 50 K can be achieved within an x-ray sampled region for longer than 10 min. The system has been used to obtain in situ structural data and high temperature equations of state on metals, oxides, and silicates to 3500 K and 160 GPa. © 2001 American Institute of Physics.
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  • 3
    Publication Date: 2021-06-09
    Description: In this study we present dissolved and particulate 230Th and 232Th results, as well as particulate 234Th data, obtained as part of the GEOTRACES central Arctic Ocean sections GN04 (2015) and IPY11 (2007). Samples were analyzed following GEOTRACES methods, and compared to previous results from 1991. We observe significant decreases in 230Th concentrations in the deep waters of the Nansen Basin. We ascribe this non-steady state removal process to a variable release and scavenging of trace metals near an ultra-slow spreading ridge. This finding demonstrates that hydrothermal scavenging in the deep-sea may vary on annual time scales and highlights the importance of repeated GEOTRACES sections
    Repository Name: EPIC Alfred Wegener Institut
    Type: Article , isiRev
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  • 4
    Publication Date: 2015-08-11
    Description: In this study, we developed a new method for in-situ pressure determination in multi-anvil, high-pressure apparatus using an acoustic travel time approach within the framework of acoustoelasticity. The ultrasonic travel times of polycrystalline Al 2 O 3 were calibrated against NaCl pressure scale up to 15 GPa and 900 °C in a Kawai-type double-stage multi-anvil apparatus in conjunction with synchrotron X-radiation, thereby providing a convenient and reliable gauge for pressure determination at ambient and high temperatures. The pressures derived from this new travel time method are in excellent agreement with those from the fixed-point methods. Application of this new pressure gauge in an offline experiment revealed a remarkable agreement of the densities of coesite with those from the previous single crystal compression studies under hydrostatic conditions, thus providing strong validation for the current travel time pressure scale. The travel time approach not only can be used for continuous in-situ pressure determination at room temperature, high temperatures, during compression and decompression, but also bears a unique capability that none of the previous scales can deliver, i.e., simultaneous pressure and temperature determination with a high accuracy (±0.16 GPa in pressure and ±17 °C in temperature). Therefore, the new in-situ Al 2 O 3 pressure gauge is expected to enable new and expanded opportunities for offline laboratory studies of solid and liquid materials under high pressure and high temperature in multi-anvil apparatus.
    Print ISSN: 0021-8979
    Electronic ISSN: 1089-7550
    Topics: Physics
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  • 5
    Publication Date: 2016-06-22
    Description: Most lakes in the interior Tibetan Plateau have expanded rapidly since the late 1990s. Because of a lack of observations, lake water balances and their changes are far from well understood. Evaporation is a component of the lake water balance, and this study quantifies its magnitude, decadal change, and its contribution to the water balance changes in Lake Nam Co, one of the largest lakes on the Tibetan Plateau (with an area of approximately 2000 km 2 and a mean depth of approximately 40 m). The lake temperature and the evaporation are simulated by the Flake model. The simulation results are validated against observed lake temperature profile from 2013 and MODIS lake surface temperature data from 2000-2014. The simulated latent heat flux and sensible heat flux are validated against Bowen ratio-derived estimates for 2013. Based on the validated simulation results, the long-term mean annual evaporation is approximately 832 ± 69 mm, and this value is much less than the potential evaporation estimated using the Penman-Monteith equation. The annual evaporation from 1980-2014 displays a complex decadal oscillation, mainly due to the changes in energy-related terms (air temperature and radiation). The mean lake evaporation since the late 1990s is greater than previous periods; thus, this change in evaporation has suppressed the recent expansion of Nam Co.
    Print ISSN: 0148-0227
    Topics: Geosciences , Physics
    Published by Wiley on behalf of American Geophysical Union (AGU).
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  • 6
    Publication Date: 2016-04-01
    Description: Generally, the phase structure change of Pb(B′ B″)O 3 –PZT solid solutions near a morphotropic phase boundary (MPB) can be originated from composition variations. Here our results show that the excess PbO and the sintering temperature can also result in the ferroelectric phase structure change in the Pb(Ni 1/3 Nb 2/3 )O 3 –Pb(Zr,Ti)O 3 (PNN–PZT)-based ceramics near the MPB. The dielectric, piezoelectric, and ferroelectric properties are dependent on the tetragonal phase content ( TP ) which is closely associated with the excess PbO and the sintering temperature. The temperature dependence of the polarization ( P )–electric field ( E ) hysteresis loops reveals that the tetragonal phase in the PNN–PZT-based ceramics has a lower activation energy ( E a ) for domain wall movement than that of the rhombohedral phase, thus resulting in easier polarization rotation. This is responsible for the phase structure–electrical property relationships in the PNN–PZT-based ceramics, exhibiting the dependence of the tetragonal phase content ( TP ) on the electrical properties.
    Print ISSN: 0021-8979
    Electronic ISSN: 1089-7550
    Topics: Physics
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  • 7
    Publication Date: 2015-12-29
    Description: In this paper, we study the long time behavior of solutions to a weakly dissipative fractional Korteweg de Vries (KdV) equation on the real line R . The main difficulty lies in that the dissipative term is a nonlocal operator. We overcome this difficulty by the commutator estimates and product estimates associated with fractional Laplacian. The asymptotical compactness of solution semigroup is proved by the tail estimates. Finally, we conclude the existence of ( H 2 ( R ), H 5 ( R )) global attractor of the weakly dissipative fractional KdV equation.
    Print ISSN: 0022-2488
    Electronic ISSN: 1089-7658
    Topics: Mathematics , Physics
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  • 8
    Publication Date: 2019
    Description: Abstract Dynamic changes in soil organic carbon (SOC) have become a popular topic in global research on organic carbon as part of the increasing attention being paid to food security and reducing greenhouse gas emissions. In this paper, the semiarid regions of China were selected as a research focus, and SOC data from 1980–2015 were analyzed using IBM SPSS Statistics 20.0 software. SOC in farmland varied according to cultivated land type, mulching material type, and planting method in the studied regions. The SOC content is 10.3–10.8 g/kg in supplementally irrigated land and flat dry land, 7.1–8.7 g/kg in terraced dry land and river beach land, and 6.2–6.4 g/kg in sloping dry land. The SOC content increased to 16.1–17.4 g/kg when crop stalks were used as mulch. The increase was only 11.5‐13.5 g/kg in soils mulched with film or sandstone. The SOC value in wheat, maize, and potatoes sown on single or double ridges was 2.4–3.2%, 35.7–36.4% and 4.4–4.8%, respectively, which are higher than the values for wheat, maize, and potatoes sown using the flat planting method. The SOC sequestering potential also varied according to the previously noted factors and was improved from 224.1–383.8% depending on cultivated land type, from 96.5–182.3% depending on mulching material type, and from 96.1–191.3% depending on planting method. The SOC sequestering potential can be improved by 453.2–757.4% with the integration of the optimal cultivated land type, mulching material type, and planting method. Thus, there is substantial soil carbon sequestration potential in China's semiarid regions. This article is protected by copyright. All rights reserved.
    Print ISSN: 0266-0032
    Electronic ISSN: 1475-2743
    Topics: Geosciences , Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Published by Wiley
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  • 9
    Publication Date: 2018
    Description: Abstract In this work, we report a lead‐free piezoelectric ceramic of (0.9‐x)NaNbO3‐0.1BaTiO3‐xBaZrO3, and the effects of BaZrO3 on the phase structure, microstructure, electrical properties and temperature stability are investigated. A morphotropic phase boundary‐like region consisting of rhombohedral (R) and tetragonal (T) phases is constructed in the compositions with x = 0.035‐0.04. More importantly, in situ temperature independence of the piezoelectric effect {piezoelectric constant (d33) and strain} can be achieved below the Curie temperature (Tc). Intriguingly, the electric field‐induced strain is still observed at T ≥ Tc due to the combined actions of the electrostrictive effect and the electric field‐induced phase transition. We believe that NaNbO3‐based ceramics of this type have potential for applications in actuators and sensors.
    Print ISSN: 0002-7820
    Electronic ISSN: 1551-2916
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Published by Wiley
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  • 10
    Publication Date: 2016-06-04
    Description: Independent measurements of the volumetric and elastic properties of Columbia River basalt glass were made up to 5.5 GPa by high-pressure X-ray microtomography and GHz-ultrasonic interferometry, respectively. The Columbia River basalt displays P- and S-wave velocity minima at 4.5 and 5 GPa, respectively, violating Birch's Law. These data constrain the pressure dependence of the density and elastic moduli at high pressure, which cannot be modeled through usual equations of state nor determined by step-wise integrating the bulk sound velocity as is common practice. We propose a systematic variation in compression behavior of silicate glasses that is dependent on the degree of polymerization and arises from the flexibility of the aluminosilicate network. This behavior likely persists into the liquid state for basaltic melts resulting in weak pressure dependence for P-wave velocities perhaps to depths of the transition zone. Modeling the effect of partial melt on P-wave velocity reductions suggest that melt fraction determined by seismic velocity variations may be significantly overestimated in the crust and upper mantle.
    Print ISSN: 0148-0227
    Topics: Geosciences , Physics
    Published by Wiley on behalf of American Geophysical Union (AGU).
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