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  • 1
    Publication Date: 2019
    Description: 〈p〉The recent discovery of ferromagnetism in two-dimensional (2D) van der Waals (vdW) materials holds promises for spintronic devices with exceptional properties. However, to use 2D vdW magnets for building spintronic nanodevices such as magnetic memories, key challenges remain in terms of effectively switching the magnetization from one state to the other electrically. Here, we devise a bilayer structure of Fe〈sub〉3〈/sub〉GeTe〈sub〉2〈/sub〉/Pt, in which the magnetization of few-layered Fe〈sub〉3〈/sub〉GeTe〈sub〉2〈/sub〉 can be effectively switched by the spin-orbit torques (SOTs) originated from the current flowing in the Pt layer. The effective magnetic fields corresponding to the SOTs are further quantitatively characterized using harmonic measurements. Our demonstration of the SOT-driven magnetization switching in a 2D vdW magnet could pave the way for implementing low-dimensional materials in the next-generation spintronic applications.〈/p〉
    Electronic ISSN: 2375-2548
    Topics: Natural Sciences in General
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  • 2
    Publication Date: 2018-07-07
    Description: Ferroelectric materials for photovoltaics have sparked great interest because of their switchable photoelectric responses and above-bandgap photovoltages that violate conventional photovoltaic theory. However, their relatively low photocurrent and power conversion efficiency limit their potential application in solar cells. To improve performance, conventional strategies focus mainly on narrowing the bandgap to better match the solar spectrum, leaving the fundamental connection between polar order and photovoltaic effect largely overlooked. We report large photovoltaic enhancement by A -site substitutions in a model ferroelectric photovoltaic material, BiFeO 3 . As revealed by optical measurements and supported by theoretical calculations, the enhancement is accompanied by the chemically driven rotational instability of the polarization, which, in turn, affects the charge transfer at the band edges and drives a direct-to-indirect bandgap transition, highlighting the strong coupling between polarization, lattice, and orbital order parameters in ferroelectrics. Polar order engineering thus provides an additional degree of freedom to further boost photovoltaic efficiency in ferroelectrics and related materials.
    Electronic ISSN: 2375-2548
    Topics: Natural Sciences in General
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  • 3
    Publication Date: 2018-01-28
    Description: This paper presents a design methodology of multisine signals, so that they can be used as phase references or standards convenient for modulated measurements. To achieve an extendable measurement bandwidth, the spectrum of each multisine is designed with three successive segments, where the left (lower-frequency) and right (higher-frequency) ending ones have the same phase spectra. In this way several multisines, one by one overlapped at the ending segments, can jointly serve as an integrated phase reference/standard signal, which in theory has an arbitrarily extendable bandwidth. By the example of “Schroeder” phase relationship, the proposed method is experimentally verified for wideband modulated measurements, where the designed multisines are used as the phase references and standards, respectively, of a nonlinear vector network analyzer test bed. In this work, a phase measurement error less than ±1 deg. is experimentally confirmed for 1601-tone measurements with 160 MHz modulation bandwidth around 2 GHz.
    Print ISSN: 0048-6604
    Electronic ISSN: 1944-799X
    Topics: Geosciences , Physics
    Published by Wiley on behalf of American Geophysical Union (AGU).
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  • 4
    Publication Date: 2019
    Description: 〈p〉Atomic engineering is envisioned to involve selectively inducing the desired dynamics of single atoms and combining these steps for larger-scale assemblies. Here, we focus on the first part by surveying the single-step dynamics of graphene dopants, primarily phosphorus, caused by electron irradiation both in experiment and simulation, and develop a theory for describing the probabilities of competing configurational outcomes depending on the postcollision momentum vector of the primary knock-on atom. The predicted branching ratio of configurational transformations agrees well with our atomically resolved experiments. This suggests a way for biasing the dynamics toward desired outcomes, paving the road for designing and further upscaling atomic engineering using electron irradiation.〈/p〉
    Electronic ISSN: 2375-2548
    Topics: Natural Sciences in General
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  • 5
    Publication Date: 2012-01-13
    Description: Central Asia is currently a semiarid-arid region, dominated by the Westerlies. It is important to understand mechanisms of climate and precipitation changes here, as water availability in the region is crucial today and in the future. High-resolution, absolutely-dated oxygen isotope (δ18O) records of stalagmites from Kesang Cave characterize a dynamic precipitation history over most of the past 500,000 years. This record demonstrates, for the first time, that climate change in the region exhibits a processional rhythm with abrupt inceptions of low δ18O speleothem growth at times of high Northern Hemisphere summer insolation followed by gradual δ18O increases that track decreases of insolation. These observations and interpretations contrast with the interpretation of nearby, but higher elevation ice core records. The absolutely-dated cave δ18O shifts can be used to correlate the regional climate variability by providing chronological marks. Combined with other paleoclimate records, the Kesang observations suggest that possible incursions of Asian summer monsoon rainfall or related moisture into the Kesang site and/or adjacent areas during the high insolation times may play an important role in changing orbital-scale hydrology of the region. Based on our record, arid climate will prevail in this region for the next several millennia, providing that anthropogenic effects do not supersede natural processes.
    Print ISSN: 0094-8276
    Electronic ISSN: 1944-8007
    Topics: Geosciences , Physics
    Published by Wiley on behalf of American Geophysical Union (AGU).
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  • 6
    Publication Date: 2016-06-19
    Description: The rapid growth of deformable and stretchable electronics calls for a deformable and stretchable power source. We report a scalable approach for energy harvesters and self-powered sensors that can be highly deformable and stretchable. With conductive liquid contained in a polymer cover, a shape-adaptive triboelectric nanogenerator (saTENG) unit can effectively harvest energy in various working modes. The saTENG can maintain its performance under a strain of as large as 300%. The saTENG is so flexible that it can be conformed to any three-dimensional and curvilinear surface. We demonstrate applications of the saTENG as a wearable power source and self-powered sensor to monitor biomechanical motion. A bracelet-like saTENG worn on the wrist can light up more than 80 light-emitting diodes. Owing to the highly scalable manufacturing process, the saTENG can be easily applied for large-area energy harvesting. In addition, the saTENG can be extended to extract energy from mechanical motion using flowing water as the electrode. This approach provides a new prospect for deformable and stretchable power sources, as well as self-powered sensors, and has potential applications in various areas such as robotics, biomechanics, physiology, kinesiology, and entertainment.
    Electronic ISSN: 2375-2548
    Topics: Natural Sciences in General
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  • 7
    Publication Date: 2016-05-27
    Description: The bi-spectral method retrieves cloud optical thickness ( τ ) and cloud droplet effective radius ( r e ) simultaneously from a pair of cloud reflectance observations, one in a visible or near infrared (VIS/NIR) band and the other in a shortwave-infrared (SWIR) band. A cloudy pixel is usually assumed to be horizontally homogeneous in the retrieval. Ignoring sub-pixel variations of cloud reflectances can lead to a significant bias in the retrieved τ and r e . In the literature, the retrievals of τ and r e are often assumed to be independent and considered separately when investigating the impact of sub-pixel cloud reflectance variations on the bi-spectral method. As a result, the impact on τ is contributed only by the sub-pixel variation of VIS/NIR band reflectance and the impact on r e only by the sub-pixel variation of SWIR band reflectance. In our new framework, we use the Taylor expansion of a two-variable function to understand and quantify the impacts of sub-pixel variances of VIS/NIR and SWIR cloud reflectances and their covariance on the τ and r e retrievals. This framework takes into account the fact that the retrievals are determined by both VIS/NIR and SWIR band observations in a mutually dependent way. In comparison with previous studies, it provides a more comprehensive understanding of how sub-pixel cloud reflectance variations impact the τ and r e retrievals based on the bi-spectral method. In particular, our framework provides a mathematical explanation of how the sub-pixel variation in VIS/NIR band influences the r e retrieval and why it can sometimes outweigh the influence of variations in the SWIR band and dominate the error in r e retrievals, leading to a potential contribution of positive bias to the r e retrieval. We test our framework using synthetic cloud fields from a large-eddy simulation and real observations from MODIS. The predicted results based on our framework agree very well with the numerical simulations. Our framework can be used to estimate the retrieval uncertainty from sub-pixel reflectance variations in operational satellite cloud products and to help understand the differences in τ and r e retrievals between two instruments.
    Print ISSN: 0148-0227
    Topics: Geosciences , Physics
    Published by Wiley on behalf of American Geophysical Union (AGU).
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  • 8
    Publication Date: 2016-05-28
    Description: High-pressure (HP) metagreywacke from the Namche Barwa complex, Eastern Himalayan Syntaxis (EHS), consists of garnet, biotite, plagioclase, quartz, rutile and ilmenite with or without K-feldspar, sillimanite, cordierite, spinel and orthopyroxene. Two types of metagreywacke are recognized: medium-temperature (MT) and high-temperature (HT) types. Garnet in the MT metagreywacke shows significant growth zoning and contains lower MgO than the weakly zoned garnet in the HT metagreywacke. Petrographic observations and phase equilibria modelling for four representative samples indicate that both types of metagreywacke experienced clockwise P–T paths subdivided into three stages: stage I is the pre-peak prograde to pressure peak ( P max ) stage characterized by progressive increase in P–T conditions. The P max conditions are estimated using the garnet composition with maximum CaO, being 12.5–13.5 kbar and 685–725 °C for the MT metagreywacke, and 15–16 kbar and 825–835 °C for the HT one. Stage II is the post- P max decompression with heating or near-isothermal to T max stage and the T max conditions, constrained using the garnet compositions with maximum MgO, are 11 kbar and 760 °C for the MT metagreywacke, and ~12 kbar and 830–845 °C for the HT one. The modelled mineral assemblages at T max are garnet + biotite + K-feldspar + rutile + plagioclase ± ilmenite in the presence of melt for both types of metagreywacke, consistent with the petrographic observations. Stage III is the post- T max retrograde metamorphism, characterized by decompression and cooling. The modelling suggests that the melts with high Na/K ratios (1.7–5.2) have been produced during stages I and II, which could be responsible for the formation of sodium-rich leucogranites. This study and previous results indicate that the Higher Himalayan Crystallines (HHC) in the Eastern Himalayan Syntaxis consist of MT–HP and HT–HP metamorphic units separated by a speculated tectonic contact. Petrological and structural discontinuities within the EHS cannot be easily interpreted with ‘tectonic aneurysm’ model. This article is protected by copyright. All rights reserved.
    Print ISSN: 0263-4929
    Electronic ISSN: 1525-1314
    Topics: Geosciences
    Published by Wiley
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  • 9
    Publication Date: 2018
    Description: 〈p〉Theory has established the importance of geometric phase (GP) effects in the adiabatic dynamics of molecular systems with a conical intersection connecting the ground- and excited-state potential energy surfaces, but direct observation of their manifestation in chemical reactions remains a major challenge. Here, we report a high-resolution crossed molecular beams study of the H + HD -〉 H〈sub〉2〈/sub〉 + D reaction at a collision energy slightly above the conical intersection. Velocity map ion imaging revealed fast angular oscillations in product quantum state–resolved differential cross sections in the forward scattering direction for H〈sub〉2〈/sub〉 products at specific rovibrational levels. The experimental results agree with adiabatic quantum dynamical calculations only when the GP effect is included.〈/p〉
    Print ISSN: 0036-8075
    Electronic ISSN: 1095-9203
    Topics: Biology , Chemistry and Pharmacology , Computer Science , Medicine , Natural Sciences in General , Physics
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  • 10
    Publication Date: 2011-05-06
    Description: A continuous countercurrent supercritical CO 2 extraction-distillation dual-column process was developed to extract and concentrate natural vitamin E (VE) from soybean oil deodorizer distillate (SODD). The experimental results demonstrated that process parameters such as extraction pressure, temperature, and solvent-to-feed ratio significantly impacted on the extraction efficiency of natural VE. A new five-parameter mass transfer model for the continuous countercurrent supercritical CO 2 extraction-distillation dual-column process was presented based on the Penetration and Double-Film theories. The calculated values of the mathematical model agreed well with the experimental data, with absolute average relative deviation values of less than 25 %. A continuous countercurrent supercritical CO 2 extraction-distillation dual-column process was developed to extract and concentrate natural vitamin E from soybean oil deodorizer distillate. A new five-parameter mass transfer model for this process was presented based on the Penetration and Double-Film theories.
    Print ISSN: 0930-7516
    Electronic ISSN: 1521-4125
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Published by Wiley
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