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  • 1
    Publikationsdatum: 2011-01-13
    Beschreibung: Hysteresis in the capillary pressure-saturation relationship (Pc–Sw) for a porous medium has contributions from the complex geometry of the pore network as well as the physical chemistry of the grain surfaces. To isolate the role of wettability on hysteresis, we fabricated microfluidic cells that contain a single wedge-shaped channel that simulates a single pore throat. Using confocal microscopy of the three-dimensional interfaces under imbibition and drainage, we demonstrate an accurate balance between mechanical work and surface free energy that was evaluated using measured advancing and receding contact angles. The closed-loop mechanical work per surface water molecule is 95 kJ/mol, which is consistent with physisorption. Therefore, the hysteresis in the Pc–Sw relationship for a single pore throat is defined by advancing and receding contact angles that are controlled by dissipative surface adsorption chemistry.
    Print ISSN: 0043-1397
    Digitale ISSN: 1944-7973
    Thema: Architektur, Bauingenieurwesen, Vermessung , Geographie
    Publiziert von Wiley im Namen von American Geophysical Union (AGU).
    Standort Signatur Erwartet Verfügbarkeit
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  • 2
    Publikationsdatum: 2013-04-18
    Beschreibung: [1]  Seismic characterization of fluid flow through fractures requires a fundamental understanding of the relationship between the hydraulic and mechanical properties of fractures. A finite-size scaling analysis was performed on fractures with weakly correlated random aperture distributions to determine the fundamental scaling relationship between fracture stiffness and fracture fluid flow. From computer simulations, the dynamic transport exponent, which provides the power law dependence, was extracted and used to collapse the flow-stiffness relationships from multiple scales into a single scaling function. Fracture specific stiffness was determined to be a surrogate for void area that is traditionally used in percolation studies. The flow-stiffness scaling function displays two exponentially decaying regions above and below the transition into the critical regime where the hydromechanical properties become scale dependent. The transition is governed by the stressed flow paths when the flow path geometry deforms from a sheet-like topology to a string-like topology. The resulting hydro-mechanical scaling function provides a link between fluid flow and the seismic response of a fracture.
    Print ISSN: 0094-8276
    Digitale ISSN: 1944-8007
    Thema: Geologie und Paläontologie , Physik
    Publiziert von Wiley im Namen von American Geophysical Union (AGU).
    Standort Signatur Erwartet Verfügbarkeit
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  • 3
    Publikationsdatum: 2009-03-01
    Print ISSN: 0016-8025
    Digitale ISSN: 1365-2478
    Thema: Geologie und Paläontologie , Physik
    Publiziert von Wiley
    Standort Signatur Erwartet Verfügbarkeit
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  • 4
    Publikationsdatum: 2012-04-15
    Beschreibung: Nanostructuring of phthalocyanine-based materials is a powerful tool towards the preparation of new materials with outstanding properties. It has been previously shown that porphyrin-functionalized and phthalocyanine-functionalized polymers give rise to nanosized aggregates. With the goal in mind of searching new phthalocyanine-containing polymeric materials that are able to self-organize into stable supramolecular nanostructures, we have prepared unsymmetrically functionalized Zn(II) phthalocyanines that are able to behave as initiators in the atom transfer radical polymerization of styrene. Hybrid phthalocyanine–polystyrene materials of different tail lengths have been prepared, and their self-organization behavior was studied by means of UV–Vis spectroscopy and transmission electron microscopy. Copyright © 2012 John Wiley & Sons, Ltd. Polymerization of styrene by ATRP using a series of Zn(II) phthalocyanine initiators proceeds in a controlled fashion and yields well-defined Zn(II)Pc-polystyrene hybrids with low polydispersities which form well-organized nanoarchitectures.
    Print ISSN: 0894-3230
    Digitale ISSN: 1099-1395
    Thema: Chemie und Pharmazie , Physik
    Publiziert von Wiley
    Standort Signatur Erwartet Verfügbarkeit
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  • 5
    Publikationsdatum: 2012-03-01
    Beschreibung: Nanostructuring of phthalocyanine-based materials is a powerful tool towards the preparation of new materials with outstanding properties. It has been previously shown that porphyrin-functionalized and phthalocyanine-functionalized polymers give rise to nanosized aggregates. With the goal in mind of searching new phthalocyanine-containing polymeric materials that are able to self-organize into stable supramolecular nanostructures, we have prepared unsymmetrically functionalized Zn(II) phthalocyanines that are able to behave as initiators in the atom transfer radical polymerization of styrene. Hybrid phthalocyanine–polystyrene materials of different tail lengths have been prepared, and their self-organization behavior was studied by means of UV–Vis spectroscopy and transmission electron microscopy. Copyright © 2012 John Wiley & Sons, Ltd. Polymerization of styrene by ATRP using a series of Zn(II) phthalocyanine initiators proceeds in a controlled fashion and yields well-defined Zn(II)Pc-polystyrene hybrids with low polydispersities which form well-organized nanoarchitectures.
    Print ISSN: 0894-3230
    Digitale ISSN: 1099-1395
    Thema: Chemie und Pharmazie , Physik
    Publiziert von Wiley
    Standort Signatur Erwartet Verfügbarkeit
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  • 6
    Publikationsdatum: 2011-06-29
    Beschreibung: Slow crystallisation at lowered temperature yielded crystals of the “third-generation” tris (pyrazolyl)borate transfer agent p -BrC 6 H 4 TpCs (Tp′Cs) 1 (triclinic; P ; a = 8.540(4), b = 15.045(6), c = 15.879(7) Å; α = 65.853(8), β = 88.457(8), γ = 75.056(8)°; V = 1791.4(13) Å 3 ; Z = 4). The central caesium ion in 1 interacts with three individual p -BrC 6 H 4 Tp ligands in two different chelating fashions.In particular, κ 1 - N -coordination and η 5 -π-coordination of pyrazole moieties as well as η 6 -π-coordination of the p -BrC 6 H 4 substituent are observed. Further, comparable coordination of neighbouring caesium ions leads to the formation of polymeric structures connected by two bridging modes.
    Print ISSN: 0044-2313
    Digitale ISSN: 1521-3749
    Thema: Chemie und Pharmazie
    Publiziert von Wiley
    Standort Signatur Erwartet Verfügbarkeit
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  • 7
    Publikationsdatum: 2014-04-25
    Beschreibung: The radiation schemes in the Weather Research and Forecasting (WRF) model have previously not accounted for the presence of subgrid-scale cumulus clouds, thereby resulting in unattenuated shortwave radiation which can lead to overly energetic convection and overpredicted surface precipitation. This deficiency can become problematic when applying WRF as a regional climate model (RCM). Therefore, modifications were made to the WRF model to allow the Kain-Fritsch (KF) convective parameterization to provide subgrid-scale cloud fraction and condensate feedbacks to the Rapid Radiative Transfer Model – Global (RRTMG) shortwave and longwave radiation schemes. The effects of these changes are analyzed via three-year simulations using the standard and modified versions of WRF, comparing the modeled results with the North American Regional Reanalysis (NARR) and Climate Forecast System Reanalysis data, as well as with available data from the Surface Radiation Network and Clouds and Earth's Radiant Energy System. During the summer period, including subgrid cloudiness estimated by KF in the RRTMG reduces the surface shortwave radiation, leading to less buoyant energy, which is reflected in a smaller diabatic convective available potential energy, thereby alleviating the overly-energetic convection. Overall, these changes have reduced the overprediction of monthly regionally-averaged precipitation during summer for this RCM application; e.g., by as much as 49 mm for the southeastern U.S., to within 0.7% of the NARR value of 221 mm. These code modifications have been incorporated as an option available in the latest version of WRF (v3.6).
    Print ISSN: 0148-0227
    Thema: Geologie und Paläontologie , Physik
    Publiziert von Wiley im Namen von American Geophysical Union (AGU).
    Standort Signatur Erwartet Verfügbarkeit
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  • 8
    Publikationsdatum: 2014-10-05
    Beschreibung: Spectral nudging – a scale-selective interior constraint technique – is commonly used in regional climate models to maintain consistency with large-scale forcing while permitting mesoscale features to develop in the downscaled simulations. Several studies have demonstrated that spectral nudging improves the representation of regional climate in reanalysis-forced simulations compared with not using nudging in the interior of the domain. However, in the Weather Research and Forecasting (WRF) model, spectral nudging tends to produce degraded precipitation simulations when compared to analysis nudging – an interior constraint technique that is scale indiscriminate but also operates on moisture fields which until now could not be altered directly by spectral nudging. Since analysis nudging is less desirable for regional climate modeling because it dampens fine-scale variability, changes are proposed to the spectral nudging methodology to capitalize on differences between the nudging techniques and aim to improve the representation of clouds, radiation, and precipitation without compromising other fields. These changes include adding spectral nudging toward moisture, limiting nudging to below the tropopause, and increasing the nudging timescale for potential temperature, all of which collectively improve the representation of mean and extreme precipitation, 2-m temperature, clouds, and radiation, as demonstrated using a model-simulated 20-year historical period. Such improvements to WRF may increase the fidelity of regional climate data used to assess the potential impacts of climate change on human health and the environment and aid in climate change mitigation and adaptation studies.
    Print ISSN: 0148-0227
    Thema: Geologie und Paläontologie , Physik
    Publiziert von Wiley im Namen von American Geophysical Union (AGU).
    Standort Signatur Erwartet Verfügbarkeit
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  • 9
    Publikationsdatum: 2014-06-01
    Beschreibung: The Weather Research and Forecasting (WRF) model is used to downscale a coarse reanalysis (National Centers for Environmental Prediction–Department of Energy Atmospheric Model Intercomparison Project reanalysis, hereafter R2) as a proxy for a global climate model (GCM) to examine the consequences of using different methods for setting lake temperatures and ice on predicted 2-m temperature and precipitation in the Great Lakes region. A control simulation is performed where lake surface temperatures and ice coverage are interpolated from the GCM-proxy. Because the R2 represents the five Great Lakes with only three grid points, ice formation is poorly represented, with large, deep lakes freezing abruptly. Unrealistic temperature gradients appear in areas where the coarse scale fields have no inland water points nearby and lake temperatures on the finer grid are set using oceanic points from the GCM-proxy. Using WRF coupled with the Freshwater Lake (FLake) model reduces errors in lake temperatures and significantly improves the timing and extent of ice coverage. Overall, WRF-FLake increases the accuracy of 2-m temperature compared to the control simulation where lake variables are interpolated from R2. However, the decreased error in FLake-simulated lake temperatures exacerbates an existing wet bias in monthly precipitation relative to the control run because the erroneously cool lake temperatures interpolated from R2 in the control run tend to suppress over-active precipitation.
    Print ISSN: 0148-0227
    Thema: Geologie und Paläontologie , Physik
    Publiziert von Wiley im Namen von American Geophysical Union (AGU).
    Standort Signatur Erwartet Verfügbarkeit
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  • 10
    Publikationsdatum: 2014-07-31
    Beschreibung: Active geophysical monitoring of potential failure along mechanical discontinuities in rock requires identification of precursory signatures to failure in geophysical signals. Active ultrasonic monitoring of shear failure along frictional discontinuities was performed to determine the signatures of potential failure. An instrumented direct shear apparatus was used to apply a constant shearing rate to a discontinuity that was held under a constant normal stress. Transmitted and reflected compressional and shear waves were recorded during the shearing process. Ultrasonic precursors were identified as distinct maxima in the amplitude of transmitted shear waves as well as minima in the amplitude of reflected shear waves that occurred well before the peak shear strength of a frictional discontinuity. The precursors are linked to changes in the local shear specific stiffness along the discontinuity while the discontinuity's macroscopic shear strength continues to increase prior to failure.
    Print ISSN: 0094-8276
    Digitale ISSN: 1944-8007
    Thema: Geologie und Paläontologie , Physik
    Publiziert von Wiley im Namen von American Geophysical Union (AGU).
    Standort Signatur Erwartet Verfügbarkeit
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