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  • 1
    Publication Date: 2004-11-01
    Print ISSN: 1434-6060
    Electronic ISSN: 1434-6079
    Topics: Physics
    Published by Springer
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    Journal of molecular evolution 43 (1996), S. 326-333 
    ISSN: 1432-1432
    Keywords: Clay catalysis ; Glycine oligomerization ; Molecular evolution ; Prebiotic peptide formation ; Smectite
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract Clay-catalyzed glycine and diglycine oligomerizations were performed as drying/wetting cycles at 80°C. Two trioctahedral smectites (hectorite and saponite), three pure montmorillonites, a ferruginous smectite, an Fe(II)-rich smectite, and three smectites containing goethite admixture were used as catalysts. Highest peptide bond formation was found with trioctahedral smectites. About 7% of glycine was converted to diglycine and diketopiperazine on hectorite after 7 days. In the case of dioctahedral smectites, highest yields were achieved using clays with a negative-layer charge localized in the octahedral sheets (up to 2% of converted glycine after 7 days). The presence of Fe(II) in clay is reflected in a higher efficiency in catalyzing amino acid dimerization (about 3.5% of converted glycine after 7 days). The possible significance of the results for prebiotic chemistry is discussed.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Springer
    Journal of molecular evolution 45 (1997), S. 457-466 
    ISSN: 1432-1432
    Keywords: Key words: Alanine — Glycine — Prebiotic peptide formation — Silica — Alumina — Clays — Catalysis
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract. The peptide bond formation of alanine (ala), ala + glycine (gly), ala + diglycine (gly2), and ala + gly cyclic anhydride (cyc-gly2) in drying/wetting cycles at 80°C was studied. Silica, alumina, and representative smectites—montmorillonite and hectorite—were used as catalysts, and the dependence of reaction yields on the available amount of water in the reaction systems was evaluated. Silica and alumina catalyze the formation of oligopeptide mainly in temperature fluctuation experiments, whereas higher amounts of water in the reaction system support clay-catalyzed reactions. Silica and alumina are much more efficient for amino acid dimerization than clays. Whereas only 0.1% of ala oligomerized on hectorite and no reaction proceeded on montmorillonite, about 0.9 and 3.8% alanine converted into its dimer and cyclic anhydride on silica and alumina, respectively. Clay minerals, on the other hand, seem to more efficiently catalyze peptide chain elongation than amino acid dimerization. The reaction yields of ala-gly-gly and gly-gly-ala from ala + gly2 and ala + cyc-gly2 reached about 0.3% on montmorillonite and 1.0% on hectorite. The possible mechanisms of these reactions and the relevance of the results for prebiotic chemistry are discussed.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Springer
    Journal of molecular evolution 43 (1996), S. 326-333 
    ISSN: 1432-1432
    Keywords: Key words: Clay catalysis — Glycine oligomerization — Molecular evolution — Prebiotic peptide formation — Smectite
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract. Clay-catalyzed glycine and diglycine oligomerizations were performed as drying/wetting cycles at 80°C. Two trioctahedral smectites (hectorite and saponite), three pure montmorillonites, a ferruginous smectite, an Fe(II)-rich smectite, and three smectites containing goethite admixture were used as catalysts. Highest peptide bond formation was found with trioctahedral smectites. About 7% of glycine was converted to diglycine and diketopiperazine on hectorite after 7 days. In the case of dioctahedral smectites, highest yields were achieved using clays with a negative-layer charge localized in the octahedral sheets (up to 2% of converted glycine after 7 days). The presence of Fe(II) in clay is reflected in a higher efficiency in catalyzing amino acid dimerization (about 3.5% of converted glycine after 7 days). The possible significance of the results for prebiotic chemistry is discussed.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Springer
    Archives of microbiology 36 (1960), S. 67-94 
    ISSN: 1432-072X
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    Springer
    Archives of microbiology 43 (1962), S. 183-200 
    ISSN: 1432-072X
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Summary Germination requirements of suspensions of spores of Bac. megaterium QM B1551, a “glucose type”, have been examined employing a decrease in optical density as the criterion of germination. Low concentrations of deionized glucose showed no germinative powers. Glucose was effective in augmenting germination by a variety of inorganic salts. Salts alone were sufficient germinators, but not all salts were active. Cl-, Br-, I- and NO3 - were efficient germinators. The nature of the cation portion of the germinative salts played a determinant role. A primary role for ions in germination is proposed and a secondary, augmentative action is attributed to glucose.
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  • 7
    Electronic Resource
    Electronic Resource
    Springer
    Archives of microbiology 43 (1962), S. 201-212 
    ISSN: 1432-072X
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Summary Germination requirements of suspensions of spores of Bacillus megaterium, Texas strain, an “l-alanine-inosine type”, have been examined employing a decrease in optical density as the criterion of germination. In deionized water, l-alanine and inosine were devoid of germinative powers. They were effective only in conjunction with any one of a large variety of salts. Data are given for germination by the monovalent and divalent alkali metal chlorides. The potassium halides were germinative; potassium fluoride was the best. Salts of organic acids, including fatty acids and polycarboxylic acids, were germinative. The need for inosine could be bypassed by various salts, e.g., ammonium propionate or salts of dipicolinic acid. Also, l-alanine was replaceable by a variety of amino acids, provided suitable ions were present. In the presence of magnesium chloride, sodium dipicolinate could substitute for either inosine or l-alanine, but not both. Salts of n-hexylamine and n-heptylamine bypassed the need for both l-alanine and inosine. A primary role for ions in germination is proposed and a secondary, augmentative action is attributed to l-alanine and inosine.
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  • 8
    Electronic Resource
    Electronic Resource
    Springer
    Applied physics 69 (1999), S. S121 
    ISSN: 1432-0630
    Keywords: PACS: 52.50.Jm; 79.20.Ds
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Abstract. The ionization of laser-ablated vapours with lasers producing ns duration pulses at various wavelengths has been studied in order to understand the mechanisms of the vapour–plasma transition. It has been established that there are several regimes characterizing the laser–target interaction which depend on laser intensity, wavelength, and pulse duration. The range of laser intensities for optimal laser evaporation is determined by the condition of transparent vapours. The intensity range is upper-limited by the opaque plasma formation due to vapour optical breakdown. Results are given for laser evaporation of graphite with Nd:YAG laser (1.064 μm), KrF laser (248 nm) and ArF laser (193 nm). For the UV laser wavelength the regime of skin-effect interaction was proposed as the mechanism of ion acceleration, and the range of validity of the skin-effect mode was established. With UV lasers the interaction has a bimodal nature: the interaction may proceed initially in the skin effect regime, resulting in a few high-energy ions, until hydrodynamic expansion begins at a later stage. The skin-effect interaction at the initial stage of the UV laser pulse gives the first, to our knowledge, explanation for the acceleration of ions up to ∼100 eV at low laser intensities of 108–109 W/cm2 and ns-range pulse duration.
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  • 9
    ISSN: 1432-0630
    Keywords: PACS: 81.05.Tp; 51.10.+y; 34.10.+x
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Abstract. It has been proved [1] that the use of a CO2-laser system operating in continuous wave mode (cw) can be efficiently used for the production of carbon single-walled nanotubes (SWNTs). In this article we first describe in detail the variable experimental conditions (different ambient gases, static gas pressure, and gas flow) for SWNT formation and summarize the results of the characterization studies of the synthesized materials. Second, we analyze the influence of the different experimental conditions on the SWNTs formation process. We show that the heat transport, kinetic, and diffusion processes allow us to explain seemingly different formation conditions in a qualitative and semi-quantitative agreement with the experimental results. The presented self-consistent scenario for nanotube formation in a gas phase allowed us to propose future experiments on testing the mechanism of nanotube formation.
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  • 10
    ISSN: 1432-0983
    Keywords: Mitochondrial DNA ; Plasmid-like DNA ; Date-palm ; Recombination
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract A molecular clone containing the complete sequence of a mitochondrial circular plasmid-like DNA (the R plasmid) isolated from the date-palm variety V3DP was used as a probe in Southern analyses of mitochondrial DNA prepared from other varieties. Another circular structure (the S plasmid) was detected in some of these varieties, and sequenced from variety V2DP. It appears that the R plasmid could have arisen from the S plasmid by an intermolecular recombination event at a set of 26-bp imperfect short direct repeats.
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