ISSN:
1572-8854
Source:
Springer Online Journal Archives 1860-2000
Topics:
Geosciences
,
Physics
Notes:
Abstract The reaction of bis(hydroxymethyl)phenylphosphane withtert-butyldichlorophosphane leads to the formation ofcis-2-tert-butyl-5-phenyl-1,3,2,5-dioxadiphosphorinane (1). Thecis configuration was definitively proven by the X-ray diffraction study of the 2, 5-dithioxo derivative (2), which was obtained from (1) by a stereoselective reaction. The diselenoxo compound (3) was also prepared. These three new compounds were subjected to a complete NMR study (1H,13C,31P, and77Se).
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF01171046
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