ALBERT

Notes: Abstract The Aeolian volcanic arc displays a wide range of magmatic products. Mafic lavas range from hypersthene normative calc-alkaline basalts to silica-undersaturated potassic absarokites, although the former are spatially and temporally dominant, consistent with the subduction-zone tectonic setting. In addition, intermediate and acidic members of the various fractionation series may be recognised. Large variations in trace element and isotope ratios accompany the rapid calc-alkaline to potassic transition, and it is argued that these may be largely explained in terms of subduction-zone mantle enrichment involving components derived from both basaltic ocean crust and subducted sediments. In addition, it seems that the mantle wedge itself was substantially heterogeneous prior to the onset of subduction zone processes. Not only are these subduction components similar to those proposed in a number of island arcs, but they also resemble those recognised in the ultra-potassic lavas of the Roman province, supporting recent subduction-related petrogenetic models of the Roman magmatism. Although subducted sediment plays an important role in the generation of some potassic magmatism, it is not uniquely responsible for K2O-rich lavas, which are also produced without a large sediment contribution.

Notes: Abstract New Rb/Sr data on mineral and whole rock samples from in and around the south-east corner of the Tauern Window are presented. Pennine orthogeneisses yield an Rb/Sr whole rock age of 279±9 m.y., while orthogneiss samples from the Altkristallin Sheet near Innerkrems, Carinthia, yield an age of 381±30 m.y. by the same technique. The apparent mineral age break across the margins of the Tauern Window is investigated in an area of good structural and petrofabric control. The post-Palaeozoic history of the Eastern Alps is then discussed in the context of the available Rb/Sr data. It is argued that the bulk of the Katschberg Phyllites are of pre-Mesozoic age; that the major overthrusting movements of the Austroalpine Units were completed by 60–65 m.y.; and that the Peri-Adriatic intrusives can be little older than middle Tertiary.

Notes: Abstract Major and trace element and 143Nd/144Nd (0.51209–0.51216) and 87Sr/86Sr (0.70879–0.71105) isotope analyses are presented on a representative group of lavas from the Vulsini district of the Roman magmatic province. Three distinct series are identified; the high-K and low-K series are similar to those described from other Italian volcanoes, while the third is represented by a group of relative ly undifferentiated leucite basanites which are thought to be near-primary mantle melts. Major and trace element variations within the high-K series are consistent with fractional crystallisation from a parental magma similar to the most magnesian leucitites. Crustal contamination resulted in an increase in 87Sr/86Sr with increasing fractionation, but it was superimposed on magmas which had already inherited a range of incompatible element and isotope ratios from enrichment processes in the sub-continental mantle. These are reviewed using the available results from Vulsini, Roccamonfina and Ernici. Transition element abundances and Ta/Yb ratios indicate that the pre-enrichment mantle was similar to that of E-type MORB, and that these elements were not mobilised by the enrichment process. Mixing calculations suggest that three components were involved in the enrichment process; mantle comparable with the source of MORB, and two other components rich in trace elements. One, the low-K component, had high Sr/Nd, Th/Ta and Ba/Nb and no europium anomaly while the second had lower Sr/Nd, a negative europium anomaly and very high Th/Ta. It was also characterised by low Nb/Ba and high Rb/Ba ratios, similar to those reported from phlogopite-rich peridotite xenoliths. The trace element enrichment processes are therefore thought to have occurred in the mantle wedge above a subduction zone with the trace element characteristics of the high-K end-member reflecting the subduction of sediments and the stabilisation of mantle phlogopite.

Notes: Abstract The Late Permian to Early Triassic Siberian Traps have been sampled by drill core (core SG-9) and from surface exposure (section 1F) in the Noril'sk region of the Siberian Platform, Russia. Combined major, trace element, and Nd-, Sr-, and Pb-isotope data on selected samples through the Siberia Trap, offer new chemostratigraphic criteria for the identification and characterisation of two fundamentally different magma types and 9 of the 11 formations of lava developed near Noril'sk. A Lower Sequence of sub-alkalic basalts, tholeiites, and picritic basalts (upwards these are the Ivakinsky, Syverminsky, and Gudchichinsky formations) are overlain by an Upper Sequence of picritic basalts and tholeiites interbedded with tuffs (upwards, these are the Khakanchansky, Tuklonsky, Nadezhdinsky, Morongovsky, Mokulaevsky and Kharayelakhsky formations).The Gudchichinsky and Tuklonsky formations contain both picritic and tholeiitic lavas. The Tuklonsky formation tholeiites and picrites have moderate Gd/Yb (1.6–1.8), low TiO2 (0.45–0.95 wt%), a significant negative Ta and Nb anomaly (Nb/La =0.42–0.57) and unradiogenic Nd (ɛ Nd CHUR = to -4.6). In contrast, both the Gudchichinsky formation tholeiites and picrites have high Gd/Yb (2.3–3.1), and TiO2 (1.2–2.3 wt%), no significant Nb or Ta anomaly (Nb/La =0.8–1.1), and radiogenic Nd (ɛ Nd CHUR = to 7.3). The low-Ti and Nb/La, high La/Sm, and unradiogenic Nd-isotope signatures of the picritic Tuklonsky formation lavas and the tholeiitic lavas of the Upper Sequence are characteristic of magmas strongly influenced by material from the continental lithosphere, whereas the high-Ti and Nb/La, low La/Sm and radiogenic Nd-isotope signatures of the Lower Sequence are more comparable to deeper asthenospheric mantle-plume generated lavas similar to oceanic island basalts. The lavas overlying the Tuklonsky formation have mg-numbers of 0.63 to 0.68, and are more evolved than the Tuklonsky (Mg-number 〈 0.62) and have more radiogenic ɛ Nd CHUR (Tuklonsky:-0.03 to-4.66; Mokulaevsky: + 0.60 to + 1.61), but have many of the incompatible trace element features of the Tuklonsky sky type magma. These lavas show a progressive upwards decline in SiO2 (55–49 wt%), La/Sm (4.6–2.0), and ɛ UR Sr ( + 67 to + 13) which has previously been attributed to a decrease in the proportion of crustal material contributed to the magma. This paper explores and alternative model where a component of the crustal contribution might be derived from within an ancient region of the mantle lithosphere as recycled sediment rather than from the overlying continental crust.

Notes: Abstract Strontium isotope data are reported for primitive lavas (leucitites, tephritic leucitites, K-rich basalts, and related types) from the Roccamonfina volcano. A strong positive correlation is found between 87Sr/86Sr and the abundances of K, Rb, Sr, Ba and Zr. It is argued that the present contents of these elements in the lavas are not far removed from their concentrations in their parental primary magmas. Models involving disequilibrium and equilibrium melting of respectively homogeneous and heterogeneous source rocks are discussed. It is concluded that a heterogeneous source highly enriched in incompatible elements at some stage in the past (? 300 m.y.) is indicated.

Notes: Abstract 143Nd/144Nd, 87Sr/86Sr, and REE analyses are presented on a wide variety of Pliocene-Recent volcanic rocks from central Italy. 143Nd/144Nd varies from 0.51214–0.51289 and 87Sr/86Sr from 0.7255-0.7036; while the rare earth elements are characterised by light RE enrichment and a significant negative Eu anomaly. These Italian volcanics are tentatively subdivided into three zones: (1) N. Tuscany where the magmas are believed to reflect crustal anatexis. (2) A central zone in which hybrid (crust/ mantle) rocks have been recognised. (3) A southern zone, south of Rome, where mantle-derived magmas are identified which have been largely unaffected by interaction with continental crust. At Roccamonfina, in zone 3, Rb/Sr and Sm/Nd pseudo isochrons are observed but since the calculated ages are 0.5 and 2.0 b.y. respectively it is argued that a simple isochron model is not applicable and that the data are most easily explained by a recent mixing event within the upper mantle. It is envisaged that this occurred during metasomatism of the upper mantle source region by a fluid that had high 87Sr/86Sr and low 143Nd/144Nd and was enriched in K, Rb, and LREE's but relatively depleted in Sr2+ and Eu2+.

Notes: Abstract Trachytes and rhyolites from Salsette Island, north of Bombay, have distinctive trace element and isotope features which mark them out from typical crustal melts. Their highly incompatible trace element and Sr-, Nd and Pb isotope ratios are similar to those of the associated Deccan flood basalts. Thus the rhyolites and trachytes are closely related to the basalts, and a striking compositional gap between 50 and 65% SiO2 suggests that the high SiO2 rocks evolved by 10–15% partial melting followed by variable amounts of fractional crystallisation. The source material could have been basalt within the Deccan Trap, or related gabbroic rocks in deep crustal sill complexes. The rhyolites yield an Rb-Sr whole rock age of 61.5±1.9 Ma, with a slightly high initial 87Sr/86Sr=0.7085±18. It is argued that crustal extension provides a suitable regime for the generation of acid magmas by partial melting of associated basic rocks.

Notes: Abstract A numerical inversion program has been developed to investigate isotope and trace element variations in suites of related rocks in terms of assimilation and fractional crystallisation processes. Major element compositions constrain the degree of fractionation, and the program may be used to calculate the isotope and trace element composition of either the crustal contaminant, or of the parental magmas once the contaminant is known. The ratio of the rate of assimilation to the rate of fractional crystallisation, and the bulk partition coefficients, can be varied with changes in magma composition. The approach is illustrated with a suite of calc-alkaline rocks from the Cerro Galan centre in NW Argentina, and a suite of continental flood basalts from the southern Paraná in Brazil. Both exhibit striking increases in 87Sr/86Sr with increasing SiO2 consistent with progressive contamination during differentiation within the continental crust. In detail, both suites contain a subset of samples which have undergone relatively little contamination, and a subset characterised by relatively high SiO2 and 87Sr/86Sr reflecting larger crustal contributions. Individual samples within the more contaminated subset can be modelled in terms of assimilation with fractional crystallisation (AFC) processes, although no clear progressively contaminated liquid lines of descent are preserved. At both Cerro Galan and the southern Paraná, the associated dacites and rhyodacites appear to have similar compositions to the crustal contaminants. Thus the inversion program has been used to investigate the amount of contamination, the relationship between the amount of contamination and the amount of crystals removed by fractional crystallisation, and the isotope and trace element contents of the parental magmas prior to AFC. The latter are estimated to have had 87Sr/86Sr=0.7055 and 143Nd/144Nd=0.51256 at Cerro Galan, and 0.7090 and 0.51226 respectively in the southern Paraná.

Notes: Abstract Post-3Ma volcanics from the N Luzon arc exhibit systematic variations in 87Sr/86Sr (0.70327–0.70610), 143Nd/144Nd (0.51302–0.51229) and 208Pb*/206Pb* (0.981–1.035) along the arc over a distance of about 500 km. Sediments from the South China Sea west of the Manila Trench also exhibit striking latitudinal variations in radiogenic isotope ratios, and much of the isotopic range in the volcanics is attributed to variations in the sediment added to the mantle wedge during subduction. However, Pb-Pb isotope plots reveal that prior to subduction, the mantle end-member had high Δ8/4, and to a lesser extent high Δ7/4, similar to that in MORB from the Indian Ocean and the Philippine Sea Plate. Th isotope data on selected Holocene lavas indicate a source with unusually high Th/U ratios (4.5–5.5). Combined trace element and isotope data require that three end-members were implicated in the genesis of the N Luzon lavas: (1) a mantle wedge end-member with a Dupal-type Pb isotope signature, (2) a high LIL/HFS ‘subduction component’ interpreted to be a slab-derived hydrous fluid, and (3) an isotopically enriched end-member which reflects bulk addition (〈5%) of subducted S China Sea terrigenous sediment. The 87Sr/86Sr ratios in the volcanics show a restricted range compared with that in the sediments, and this contrasts with 143Nd/144Nd and 208Pb*/206Pb*, both of which have similar ranges in the volcanics and sediments. Such differences imply that whereas the isotope ratios of Nd, Pb and Th are dominated by the component from subducted sediment, those of Sr reflect a larger relative contribution from the slab-derived fluid.

Notes: Abstract Subduction related basalts display wide ranges in large ion lithophile element ratios (e.g., Rb/Ba and Rb/ Sr) which are unlikely to result from mixing, but suggest a role for small degree partial melting of a relatively Rb-poor mantle wedge source. However, these variations do not correlate with other trace element criteria, such as the depletions of high field strength elements (HFSE) and light rare earth elements (LREE) relative to the LILE, which characterise subduction related magmatism. Integration of radiogenic isotope and trace element data demonstrates that the elemental enrichment cannot be simply related to two component mixtures inferred from isotopic variations. Thus a minimum of three components is required to describe the geochemistry of subduction zone basalts. Two are subduction related: high Sr/Nd material is derived from the dehydration of subducted basaltic ocean crust, and a low Sr/Nd component is thought to be from subducted terrigenous sediment. The third component is in the mantle wedge, it is usually similar to the source of MORB, particularly in its isotopic composition. However, in some cases, notably continental areas, more enriched mantle wedge material with relatively high 87Sr/86Sr, low 143Nd/144Nd and elevated incompatible trace element contents may be involved Mixing of these three components is capable of producing both the entire range of Sr, Nd and Pb isotope signatures observed in destructive margin basalts, and their distinctive trace element compositions. The isotope differences between Atlantic and Pacific island arc basalts are attributed to the isotope compositions of sediments in the two oceans.