ISSN:
1573-4986
Keywords:
Methyl α-isomalto-oligosaccharides
;
tert-butyl(dimethyl)silyl donor
;
2-deoxy-α-d-arabino-hexopyranosyl
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Abstract Methyl α-isomaltoside and methyl α-isomaltotrioside specifically deoxygenated at position C-2 of the terminal glucopyranosyl unit were synthesized by trimethylsilyltriflate-mediated condensation of 3,4,6-tri-O-benzoyl-1-O-tert-butyl(dimethyl)silyl-2-deoxy-β-d-arabino-hexopyranose with suitably blocked derivatives of methyl α-d-glucopyranoside and methyl α-isomaltoside, respectively.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF00732428
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