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  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Journal of chemical crystallography 29 (1999), S. 949-953 
    ISSN: 1572-8854
    Keywords: 1,2,3,4,5,6,7,8-octahydroanthracene-9,10-dicarbonitrile ; disorder ; enthalpy and entropy of disorder ; packing effects
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract Octahydroanthracenedicarbonitrile is monoclinic, space group P21/c, at 172 K, a = 4.723(7), b = 8.254(3), c = 16.190(7) Å, β = 91.76(8)°, Z = 2, V = 630.8(12) Å3. The molecule, located on a center of symmetry, is disordered between the two senses of puckering in the aliphatic ring. The structure was also determined at 216, 256, and 297 K. The disorder increases with increasing temperature and can be described by a van't Hoff relationship with ΔH = 5.2(3) kJ mol−1 and ΔS = 13.8(12) J K−1 mol−1.
    Type of Medium: Electronic Resource
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