ISSN:
1573-9171
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Conclusions 1. Lamellar compounds of graphite with Cu, Co, Mn, Fe, Ni, Mo, and Znchlorides are catalytically active in the liquid-phase oxidation of cyclohexene by molecular oxygen and in the breakdown of cyclohexyl hydroper-oxides. Appreciable quantities of cyclohexene oxide are formed in these reactions on LCG-MoCl5. 2. On the basis of the determined product compositions, and our knowledge of the kinetics of heterogeneously catalyzed liquid-phase oxidation reactions, oxidation in the presence of the LCG must proceed through a radical-chain heterogeneous-homogeneous mechanism.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF01167752
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