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  • 1
    Publication Date: 1985-06-01
    Print ISSN: 0722-3277
    Electronic ISSN: 1431-584X
    Topics: Physics
    Published by Springer
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    The European physical journal 28 (1977), S. 273-281 
    ISSN: 1434-6036
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract We develop a theory of low energy electron loss spectroscopy of vibrational modes of molecules adsorbed on metal surfaces. Differential and total cross sections are calculated in the Distorted Wave Born Approximation, assuming i) strong elastic scattering on the metal surface, ii) direct electron-molecule interaction via the electric dipole field associated with the molecular vibration. The angular distributions are calculated and discussed for molecules adsorbed at various distances above the metal surface and for several electron energies and impact angles. The influence of electronic screening of dipolar oscillations is discussed and the consequences of the classical induced “image” dipoles are explored. It is shown that the “metal surface selection rule” known in IR spectroscopy is only approximately valid in electron scattering. Finally, we give numerical estimates of the inelastic scattering cross sections for the stretching vibrations of CO molecule adsorbed on transition metal surfaces, in reasonable agreement with experiments.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Springer
    The European physical journal 59 (1985), S. 151-157 
    ISSN: 1434-6036
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract We calculate the density of states for the nondegenerate Anderson model for various values ofu=U/πΔ andn f using the perturbation theory withu as the expansion parameter. Summing all the ω-independent self-energy diagrams, we use the Friedel sum rule and Ward identities to express the physical quantities in terms of the remaining ω-dependent part of the self-energy, which we evaluate to the 2nd order. The results for the spin and charge susceptibilities obtained in such a way compare rather well with the Bethe-ansatz results. The density of states exhibits different features in different parts of the parameter space. In Kondo region (u〉1,n f ≅1, i.e., −ε f ~U/2≫Δ), we obtain a many-body resonance (half-width ∼T K ) around the Fermi level and two broad peaks (∼Δ) at about ε f +n f U and ε f +U. In the VF region (u〉1, and ε| f |≦Δ) we obtain only two peaks (∼Δ), one at about ε f and one between ε f +n f U and ε f +U. The consequences regarding the shape of the photoemission and inverse photoemission spectra of Ce intermetallics are discussed.
    Type of Medium: Electronic Resource
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