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  • 1
    ISSN: 1432-0630
    Keywords: 73.60.Fw ; 81.15Ef ; 68.55+b
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Abstract Phosphorus-doped Si epilayers with bulk-like mobilities were grown by molecular beam epitaxy (Si-MBE) by coevaporation of phosphorus from a tin phosphide source. The behaviour of P doping as a function of growth parameters and of “potential enhanced doping” indicates a non-unity, almost growth-temperature independent incorporation efficiency with negligible surface segregation -a unique combination among coevaporated dopants in Si-MBE.
    Type of Medium: Electronic Resource
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  • 2
    ISSN: 1432-0630
    Keywords: 72.20 ; 73.60
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Abstract Measurements of the Hall coefficients and of the resistivity of MBE-grown Si, doped with P, As, Sb, B, and Ga in the concentration range 1014 to 1020 cm−3, were carried out at 77 K and at 300 K. With the exception of Ga-doped Si, the measured mobilities were close to or higher than those of bulk materials at both temperatures. The Mott metal/non-metal transition has been observed in the present epitaxial materials and the measured values for the critical impurity concentration at which the transition occurs, agree with values reported by other workers for bulk silicon.
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  • 3
    Electronic Resource
    Electronic Resource
    Springer
    Journal of applied electrochemistry 4 (1974), S. 69-73 
    ISSN: 1572-8838
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Electrical Engineering, Measurement and Control Technology
    Notes: Abstract The electrochemical removal of Antimony from 1m sulphuric acid in a restrained bed reactor was studied in terms of current, flow velocity, bed depth, bead size and pressure drop. Current efficiencies are quoted as a function of current density and information is given so that they may be calculated in terms of the above variables. Experimentally-obtained limiting current densities are compared with calculated values, using empirical formulae from the literature.
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  • 4
    Electronic Resource
    Electronic Resource
    Springer
    Journal of applied electrochemistry 4 (1974), S. 173-190 
    ISSN: 1572-8838
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Electrical Engineering, Measurement and Control Technology
    Notes: Abstract Electrochemical cells, designed to operate with reactants at low concentrations, require special provisions to be made for enhancement of mass transport of the reactants to the electrode surface. The different concepts for doing this in industrial or large-scale cells are reviewed. Examples are given of cells and processes in which these ideas have been used. A comprehensive literature survey of the quantitative relationships pertaining to the different configurations is given. The various cell designs are compared on a quantitative basis, usingi lim, and some advantages and disadvantages are discussed.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Springer
    Climatic change 40 (1998), S. 495-518 
    ISSN: 1573-1480
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract A positive correlation exists between temperature and atmospheric concentrations of carbon dioxide and methane over the last 220,000 years of glacial history, including two glacial and three interglacial periods. A similar correlation exists for the Little Ice Age and for contemporary data. Although the dominant processes responsible may be different over the three time periods, a warming trend, once established, appears to be consistently reinforced through the further accumulation of heat-trapping gases in the atmosphere; a cooling trend is reinforced by a reduction in the release of heat-trapping gases. Over relatively short periods of years to decades, the correspondence between temperature and greenhouse gas concentrations may be due largely to changes in the metabolism of terrestrial ecosystems, whose respiration, including microbial respiration in soils, responds more sensitively, and with a greater total effect, to changes in temperature than does gross photosynthesis. Despite the importance of positive feedbacks and the recent rise in surface temperatures, terrestrial ecosystems seem to have been accumulating carbon over the last decades. The mechanisms responsible are thought to include increased nitrogen mobilization as a result of human activities, and two negative feedbacks: CO2 fertilization and the warming of the earth, itself, which is thought to lead to an accumulation of carbon on land through increased mineralization of nutrients and, as a result, increased plant growth. The relative importance of these mechanisms is unknown, but collectively they appear to have been more important over the last century than a positive feedback through warming-enhanced respiration. The recent rate of increase in temperature, however, leads to concern that we are entering a new phase in climate, one in which the enhanced greenhouse effect is emerging as the dominant influence on the temperature of the earth. Two observations support this concern. One is the negative correlation between temperature and global uptake of carbon by terrestrial ecosystems. The second is the positive correlation between temperature and the heat-trapping gas content of the atmosphere. While CO2 fertilization or nitrogen mobilization (either directly or through a warming-enhanced mineralization) may partially counter the effects of a warming-enhanced respiration, the effect of temperature on the metabolism of terrestrial ecosystems suggests that these processes will not entirely compensate for emissions of carbon resulting directly from industrial and land-use practices and indirectly from the warming itself. The magnitude of the positive feedback, releasing additional CO2, CH4, and N2O, is potentially large enough to affect the rate of warming significantly.
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  • 6
    Electronic Resource
    Electronic Resource
    Springer
    Climatic change 19 (1991), S. 99-118 
    ISSN: 1573-1480
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract Recent estimates of the net release of carbon to the atmosphere from deforestation in the tropics have ranged between 0.4 and 2.5 × 1015 g yr−1. Two things have happened to require a revision of these estimates. First, refinements of the methods used to estimate the stocks of carbon in the vegetation of tropical forests have produced new estimates that are intermediate between the previous high and low estimates of carbon stocks. When these revised estimates were used here to calculate the emissions of carbon from deforestation, the new range was 1.0–2.0 × 1015 g C. Second, the previous range of estimates of flux was based on rates of deforestation in 1980. Myers' recent estimate of the rates of tropical deforestation in 1989 is about 90% higher than the rates just 10 years ago. When these recent rates were used to calculate the current net flux of carbon to the atmosphere, the range was between 1.6 and 2.7 × 1015 g C. Other uncertainties expanded this range, however, to 1.1–3.6 × 1015 g C yr−1. Three factors contributed about equally to the expanded range: rates of deforestation, the fate of deforested lands (permanent or temporary clearing), and carbon stocks of forests, including anthropogenic reductions of carbon stocks within forests (thinning or degradation).
    Type of Medium: Electronic Resource
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  • 7
    ISSN: 1572-901X
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Summary The rates of nitration in sulphuric acid of 1,10-phenanthroline coordinated to rhodium(III) and cobalt(Ill) in a number of complexes have been measured and found to be much greater in these complexes than in free phenanthroline under the same conditions. Relative rates are generally higher in those complexes which bear the smaller overall positive charges, but these charges may be modified by protonation of the other ligands in the complexes. Contrary to earlier reports, some other electrophilic substitutions do not occur in a variety of phenanthroline complexes.
    Type of Medium: Electronic Resource
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  • 8
    Publication Date: 2002-01-01
    Print ISSN: 0009-5893
    Electronic ISSN: 1612-1112
    Topics: Chemistry and Pharmacology
    Published by Springer
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  • 9
    Publication Date: 2002-01-01
    Print ISSN: 0009-5893
    Electronic ISSN: 1612-1112
    Topics: Chemistry and Pharmacology
    Published by Springer
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  • 10
    Publication Date: 2004-05-01
    Print ISSN: 0009-5893
    Electronic ISSN: 1612-1112
    Topics: Chemistry and Pharmacology
    Published by Springer
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