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  • 1
    ISSN: 1432-0967
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Notes: Abstract Pb, Sr and Nd isotope variations are correlated in diverse lavas erupted at small seamounts near the East Pacific Rise. Tholeiites are isotopically indistinguishable from MORB (206Pb/204Pb=18.1–18.5; 87Sr/86Sr=0.7023–0.7028; 143Nd/144Nd=0.51326-0.51308); associated alkali basalts always show more radiogenic Pb and Sr signatures (206Pb/204Pb=18.8–19.2; 87Sr/86Sr=0.7029–0.7031) and less radiogenic Nd (143Nd/144Nd=0.51289–0.51301). The isotopic variability covers ∼80% of the variability for Pacific MORB, due to the presence of small-scale heterogeneity in the underlying mantle. Isotope compositions also correlate with trace element ratios such as La/Sm. Tholeiites at these seamounts have 3He/4He between 7.8–8.7 R A(R A= atmospheric ratio), also indistinguishable from MORB. He trapped in vesicles of alkali basalts, released by crushing in vacuo, has low 3He/4He (1.2–2.6 R)Ain conjunction with low helium concentrations ([He]〈5×10−8 ccSTP/g). In many cases post-eruptive radiogenic ingrowth has produced He isotope disequilibrium between vesicles and glass in the alkali basalts; subatmospheric 3He/4He ratios characterize the He dissolved in the glass which is released by melting the crushed powders. The narrow range of 3He/4He in the vesicles of the alkali basalts suggests that low 3He/4He is a source characteristic, but given their low [He] and high (U + Th), pre-eruptive radiogenic ingrowth cannot be excluded as a cause for low inherited 3He/4He ratios. Pb, Sr and Nd isotope compositions in lavas erupted at Shimada Seamount, an isolated volcano on 20 m.y. old seafloor at 17°N, are distinctly different from other seamounts in the East Pacific (206Pb/204Pb=18.8–19.0, 87Sr/ 86Sr≅0.7048 and 143Nd/144Nd≅0.51266). Relatively high 207Pb/204Pb (15.6–15.7) indicates ancient (〉2 Ga) isolation of the source from the depleted upper mantle, similar to Dupal components which are more prevalent in the southern hemisphere mantle. 3He/4He at Shimada Seamount is between 3.9–4.8 R A. Because the helium concentrations range up to 1.5×10−6, the low 3He/4He can not be due to radiogenic accumulation of 4He in the magma for reasonable volcanic evolution times. The low 3He/4He may be due to the presence of “enriched” domains within the lithosphere with high (U + Th)/He ratios, possibly formed during its accretion near the ridge. Alternatively, the low 3He/4He may be an inherent characteristic of an enriched component in the mantle beneath the East Pacific. Collectively, the He-Pb-Sr-Nd isotope systematics at East Pacific seamounts suggest that the range of isotope compositions present in the mantle is more readily sampled by seamount and island volcanism than by axial volcanism. Beneath thicker lithosphere away from the ridge axis, smaller degrees of melting in the source regions are less efficient in averaging the chemical characteristics of small-scale heterogeneities.
    Type of Medium: Electronic Resource
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  • 2
    Publication Date: 2022-10-26
    Description: © The Author(s), 2019. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Roberts, Mark L., Elder, Kathryn L., Jenkins, William J., Gagnon, Alan R., Xu, Li, Hlavenka, Joshua D., & Longworth, Brett E. C-14 Blank Corrections for 25-100 mu G samples at the National Ocean Sciences AMS Laboratory. Radiocarbon, 61(5), (2019): 1403-1411, Doi: 10.1017/RDC.2019.74.
    Description: Replicate radiocarbon (14C) measurements of organic and inorganic control samples, with known Fraction Modern values in the range Fm = 0–1.5 and mass range 6 μg–2 mg carbon, are used to determine both the mass and radiocarbon content of the blank carbon introduced during sample processing and measurement in our laboratory. These data are used to model, separately for organic and inorganic samples, the blank contribution and subsequently “blank correct” measured unknowns in the mass range 25–100 μg. Data, formulas, and an assessment of the precision and accuracy of the blank correction are presented.
    Description: This work is supported by a Cooperative Agreement (OCE-1755125) with the U.S. National Science Foundation.
    Keywords: AMS ; AMS dating ; Blank corrections
    Repository Name: Woods Hole Open Access Server
    Type: Article
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  • 3
    Publication Date: 2022-05-26
    Description: © The Author(s), 2017. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Annals of Glaciology 58 (2017): 107-117, doi:10.1017/aog.2017.19.
    Description: Jakobshavn Isbræ, which terminates in Ilulissat Icefjord, has undergone rapid retreat and is currently the largest contributor to ice-sheet mass loss among Greenland’s marine terminating glaciers. Accelerating mass loss is increasing fresh water discharge to the ocean, which can feed back on ice melt, impact marine ecosystems and potentially modify regional and larger scale ocean circulation. Here we present hydrographic observations, including inert geochemical tracers, that allow the first quantitative description of the glacially-modified waters exported from the Jakobshavn/Icefjord system. Observations within the fjord suggest a deep-reaching overturning cell driven by glacial buoyancy forcing. Modified waters containing submarine meltwater (up to 2.5 ± 0.12%), subglacial discharge (up to 6 ± 0.37%) and large portions of entrained ocean waters are seen to exit the fjord and flow north. The exported meltwaters form a buoyant coastal gravity current reaching to 100 m depth and extending 10 km offshore.
    Description: We gratefully acknowledge support from WHOI’s Ocean and Climate Change Institute, the WHOI Doherty Postdoctoral Scholarship, the US National Science Foundation grant NSF OCE-1536856, and the leaders and participants of the Advanced Climate Dynamics Summer School (SiU grant NNA-2012/10151). Ship-based CTD data are freely available from the NOAA National Centers for Environmental Information, discoverable with Accession Number 0162649. Expendable CTD data are included in the Supplementary Material.
    Keywords: Glacier discharge ; Icebergs ; Ice/ocean interactions ; Meltwater chemistry ; Polar and subpolar oceans
    Repository Name: Woods Hole Open Access Server
    Type: Article
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  • 4
    Publication Date: 2013-01-01
    Description: Compound specific radiocarbon measurements can be made instantaneously using a gas chromatograph (GC) combustion system coupled to a 14C AMS system fitted with a gas ion source. Samples below 10 μg C can be analyzed but the precision is reduced to 5–10% because of lower source efficiency. We modified our GC for CH4 and CO2 analysis and injected samples multiple times to sum data and increase precision. We attained a maximum precision of 0.6% for modern CO2 from 25 injections of 27 μg C and a background of ≃0.5% (40 kyr) for ancient methane. The 14C content of dissolved CO2 and CH4 in water samples collected at a deep-sea hydrothermal vent and a serpentine mud volcano was measured and the results for the vent sample are consistent with previously published data. Further experiments are required to determine a calibration and correction procedure to maximize accuracy.
    Print ISSN: 0033-8222
    Electronic ISSN: 1945-5755
    Topics: Archaeology , Energy, Environment Protection, Nuclear Power Engineering , Geosciences
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  • 5
    Publication Date: 2010-01-01
    Description: We report and compare radiocarbon observations made on 2 meridional oceanographic sections along 150°W in the South Pacific in 1991 and 2005. The distributions reflect the progressive penetration of nuclear weapons-produced 14C into the oceanic thermocline. The changes over the 14 yr between occupations are demonstrably large relative to any possible drift in our analytical standardization. The computed difference field based on the gridded data in the upper 1600 m of the section exhibits a significant decrease over time (approaching 40 to 50‰ in Δ14C) in the upper 200–300 m, consistent with the decadal post-bomb decline in atmospheric 14C levels. A strong positive anomaly (increase with time), centered on the low salinity core of the Antarctic Intermediate Water (AAIW), approaches 50–60‰ in Δ14C, a clear signature of the downstream evolution of the 14C transient in this water mass. We use this observation to estimate the transit time of AAIW from its “source region” in the southeast South Pacific and to compute the effective reservoir age of this water mass. The 2 sections show small but significant changes in the abyssal 14C distributions. Between 1991 and 2005, Δ14C has increased by 9‰ below 2000 m north of 55°S. This change is accompanied overall by a modest increase in salinity and dissolved oxygen, as well as a slight decrease in dissolved silica. Such changes are indicative of greater ventilation. Calculation of “phosphate star” also indicates that this may be due to a shift from the Southern Ocean toward North Atlantic Deep Water as the ventilation source of the abyssal South Pacific.
    Print ISSN: 0033-8222
    Electronic ISSN: 1945-5755
    Topics: Archaeology , Energy, Environment Protection, Nuclear Power Engineering , Geosciences
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  • 6
    Publication Date: 2010-01-01
    Description: Gas-accepting ion sources for radiocarbon accelerator mass spectrometry (AMS) have permitted the direct analysis of CO2 gas, eliminating the need to graphitize samples. As a result, a variety of analytical instruments can be interfaced to an AMS system, processing time is decreased, and smaller samples can be analyzed (albeit with lower precision). We have coupled a gas chromatograph to a compact 14C AMS system fitted with a microwave ion source for real-time compound-specific 14C analysis. As an initial test of the system, we have analyzed a sample of fatty acid methyl esters and biodiesel. Peak shape and memory was better then existing systems fitted with a hybrid ion source while precision was comparable. 14C/12C ratios of individual components at natural abundance levels were consistent with those determined by conventional methods. Continuing refinements to the ion source are expected to improve the performance and scope of the instrument.
    Print ISSN: 0033-8222
    Electronic ISSN: 1945-5755
    Topics: Archaeology , Energy, Environment Protection, Nuclear Power Engineering , Geosciences
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  • 7
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