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  • Springer  (34)
  • 1990-1994  (26)
  • 1960-1964  (4)
  • 1930-1934  (2)
  • 1925-1929  (2)
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  • 1
    Electronic Resource
    Electronic Resource
    The hydration shell of myoglobin (1992)
    Springer
    European biophysics journal 21 (1992), S. 313-320 
    Details
    ISSN: 1432-1017
    Keywords: Monte Carlo ; Crystal water ; Structure refinement
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Physics
    Notes: Abstract The space in the unit cell of a metmyoglobin crystal not occupied by myoglobin atoms was filled with water using Monte Carlo calculations. Independent calculations with different amounts of water have been performed. Structure factors were calculated using the water coordinates thus obtained and the known coordinates of the myoglobin atoms. A comparison with experimental structure factors showed that both the low and the high resolution regime could be well reproduced with 814 Monte Carlo water molecules per unit cell with a B-value of 50 Å2. The Monte Carlo water molecules yield a smaller standard R-value (0.166) than using a homogeneous electron density for the simulation of the crystal water (R = 0.212). A reciprocal space refinement of the water and the protein coordinates has been performed. Monte Carlo calculations can be used to obtain information for crystallographically invisible parts of the unit cell and yield better coordinates for the visible part in the refinement.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF00188343
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  • 2
    Electronic Resource
    Electronic Resource
    Evidence of a 50-year increase in tropospheric ozone in Upper Bavaria (1994)
    Springer
    Annales geophysicae 12 (1994), S. 1197-1206 
    Details
    ISSN: 0992-7689
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract In a series of ozone-sonde soundings at the Hohenpeißenberg observatory, starting in 1967, the most striking features are increases of \sim2.2% per year in all tropospheric heights up to 8 km during the past 24 years. These facts have recently been published and discussed by several authors. In this paper, we present some evidence for the increase of tropospheric ozone concentrations during the past 50 years 1940–1990 in the territory of the northern edge of the Bavarian Alps, including the Hohenpeißenberg data. In December 1940 and August 1942, probably the first exact wet-chemical vertical soundings of ozone up to 9 km height were made by an aircraft in the region mentioned. These results were published in the earlier literature. We have converted the results of the flights on 4 days in December 1940 and on 6 days in August 1942 to modern units and have compared them with the Hohenpeißenberg ozone-sonde data of the December and August months. We also compared the data at the ground with the August results of Paris-Montsouris 1886-1898. Our results show an increase of ozone concentration at all tropospheric heights in Upper Bavaria during the past 50 years, compared with the Montsouris data in August during the past 105 years. In the recently published papers, the increases since 1967 were approximated linearly.Our results, extended to the past, show non-linear trends, with steeper increases since 1975-1979. Possible reasons for these findings are discussed. Quite recently (in case of the December months since 1986/87, the August months since 1990), the ozone mixing ratios at and above Hohenpeißenberg seem to have decreased.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/s00585-994-1197-7
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  • 3
    Electronic Resource
    Electronic Resource
    Experimental investigations on two-phase flow past a sphere using digital Particle-Image-Velocimetry (1993)
    Springer
    Experiments in fluids 14 (1993), S. 296-304 
    Details
    ISSN: 1432-1114
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract Digital Particle-Image-Velocimetry was applied to investigate particle trajectories in a gas flow past a sphere. The particle displacement was determined by autocorrelation analysis of image sections. To enhance the signal/noise ratio a synthetic image with idealized particle pictures was generated from the real image. The autocorrelation function (ACF) was calculated using the Fast Hartley Transformation (FHT). The desired secondary maximum of this function was detected by an algorithm with subpixel resolution. A data validation step testing the plausibility of the velocity vectors completes the image analysis. Particle trajectories are traced with help of the particles' velocity vectors. The particle deposition on a sphere can be deduced from the course of these trajectories.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF00189487
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  • 4
    Electronic Resource
    Electronic Resource
    Hydrogen bonding in basic copper salts: a spectroscopic study of malachite, Cu2(OH)2CO3, and brochantite, Cu4(OH)6SO4 (1993)
    Springer
    Physics and chemistry of minerals 20 (1993), S. 27-32 
    Details
    ISSN: 1432-2021
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Geosciences , Physics
    Notes: Abstract Infrared and Raman spectra of the basic copper salts malachite, Cu2(OH)2CO3, and brochantite, Cu4(OH)6SO4, as well as of deuterated and 13C substituted samples are presented and discussed in terms of group theory and the hydrogen bonds present. The main results are that (i) the hydrogen donor strengths of the OH− ions are strongly increased due to the very great synergetic effect of the copper ions, (ii) the acceptor strengths of the H-bond acceptor groups (SO4 2-, CO3 2-, and OH− ions) are significantly modified by the linkage and coordination of the acceptor atoms — this complicates true assignment of the OH bands observed to the two and six different OH− ions present in malachite and brochantite, respectively -, and (iii) the Cu — O stretching modes at 430–590 cm−1 and 420–520 cm−1 for malachite and brochantite, respectively, exhibit strong, partially covalent Cu — O bonding.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF00202247
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  • 5
    Electronic Resource
    Electronic Resource
    Immunitätszüchtung bei Tabak (1934)
    Springer
    Naturwissenschaften 22 (1934), S. 557-559 
    Details
    ISSN: 1432-1904
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Chemistry and Pharmacology , Natural Sciences in General
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF01495111
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  • 6
    Electronic Resource
    Electronic Resource
    Buchbesprechungen (1960)
    Springer
    Theoretical and applied genetics 30 (1960), S. 258-264 
    Details
    ISSN: 1432-2242
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF00713411
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  • 7
    Electronic Resource
    Electronic Resource
    Neutron-proton pairing in symmetric nuclear matter (1990)
    Springer
    The European physical journal 337 (1990), S. 355-356 
    Details
    ISSN: 1434-601X
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF01289707
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  • 8
    Electronic Resource
    Electronic Resource
    Adsorption of fish oil and poly(vinylbutyral) onto aluminum oxide particles studied by light scattering (1991)
    Springer
    Colloid & polymer science 269 (1991), S. 1077-1085 
    Details
    ISSN: 1435-1536
    Keywords: Aluminum oxide ; adsorption ; light scattering ; fish oil ; poly(vinylbutyral)
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract The effects of added poly(vinylbutyral) (PVB) and oxidized Menhaden fish oil (O-FO) on dilute suspensions of Al2O3 in the azeotropic solvent mixture 73/27 Wt.-% trichloroethylene/ethanol were studied by static (SLS) and dynamic light-scattering (DLS). The DLS correlation function consisted of four terms from: 1) interdiffusion of the two solvents, 2) diffusion of Al2O3, 3) diffusion of added O-FO and/or PVB, and 4) an induced velocity of particles through the scattering volume due to “laser pressure.” The amplitude and relaxation time of all terms could be determined. Addition of PVB to the Al2O3 suspension resulted in an increase in particle size corresponding to the adsorption of a monolayer of coils. Addition of O-FO to the Al2O3 suspension did not produce a significant increase in particle size, indicating either no adsorption or a compact conformation of O-FO molecules on the Al2O3 surface.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF00654114
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  • 9
    Electronic Resource
    Electronic Resource
    Buchbesprechungen (1964)
    Springer
    Colloid & polymer science 198 (1964), S. 101-111 
    Details
    ISSN: 1435-1536
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF01499465
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  • 10
    Electronic Resource
    Electronic Resource
    Heisenberg's uncertainty relation of position and momentum in experiments without mutual disturbance (1990)
    Springer
    Foundations of physics 3 (1990), S. 249-254 
    Details
    ISSN: 1572-9524
    Keywords: quantum theory ; fundamentals ; uncertainty relation violations
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract Arranging target atoms in a plane monolayer, one may produce by atomic or nuclear reaction an ensemble of particles with small initial position spread without disturbing their momentum spread. This would either allow a violation of Heisenberg's uncertainty relation, by creating a situation not described by quantum mechanics hence rendering quantum mechanics incomplete, or, if the uncertainty relation should hold also in this non-disturbative situation, it would mean a permanent violation of energy conservation. Thus an uncertainty relation for position and momentum and energy conservation appear to be mutually exclusive.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF00666015
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