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  • Springer  (27)
  • 2020-2021
  • 1980-1984  (27)
  • 1
    ISSN: 1434-4475
    Keywords: Cyanoethylation ; Heterocyclic compounds
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Zusammenfassung Diazotiertes 5-Amino-3-methyl-4-phenylpyrazol (1) reagiert mit einer aktiven Methylenkomponente und β-Naphthol zu den Pyrazolo[1,5-c]-1,2,4-triazin-Derivaten2a-e und5. 1 ergibt mit Benzoylisothiocyanat und Phenylisothiocyanat die entsprechenden Pyrazol-5-yl-thioharnstoffe6a, b. 5a wurde mittels Säure oder Base in das Thioharnstoffderivat8 umgewandelt. Es wird über eine Synthese von 2-Methyl-3-phenyl-4,5,6,7-tetrahydropyrazolo[1,5-a]-pyrimidin-5-on aus α-Phenylacetoacetonitril (3-Oxo-2-phenyl-butyronitril) und β-Cyanoethylhydrazin berichtet.
    Notes: Abstract Diazotised 5-amino-3-methyl-4-phenyloyrazole (1) reacted with active methylene reagents and with β-naphthol to yield the pyrazolo[1,5-c)-1,2,4-triazine derivatives2a-e and5. Compound1 reacted with benzoyl isothiocyanate and with phenyl isothiocyanate to yield the corresponding pyrazol-5-ylthiourea derivatives6a, b. 5a was converted into the thiourea derivative8 by the action of acids or alkalies. A synthesis of 2-methyl-3-phenyl-4,5,6,7-tetrahydropyrazolo[1,5-a]-pyrimidin-5-one from the reaction of α-phenylacetoactonitrile (3-oxo-2-phenyl-butyric nitrile) and β-cyanoethylhydrazine is reported.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    Archiv der Mathematik 42 (1984), S. 97-101 
    ISSN: 1420-8938
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mathematics
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Springer
    Mathematische Zeitschrift 182 (1983), S. 385-388 
    ISSN: 1432-1823
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mathematics
    Type of Medium: Electronic Resource
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  • 4
    ISSN: 1432-1203
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Medicine
    Notes: Summary A report by Bullock and coworkers has emphasized the need for standardization of the CK assay in carrier detection for DMD. A collaborative study, according to a well-specified design and involving two laboratories in Paris and Lyon, indicates that the reliability of this assay can be improved provided that special attention is paid to information about participating subjects, laboratory protocol, and repeated sampling. On a random sample of young women, mean and variance of 1n(CK) are 1.66 and 0.015 respectively. Within and between variance components are in a 3:4 ratio, homogeneous between populations. Additional use of a common test serum should insure good reliability of this assay among laboratories.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Springer
    Polymer bulletin 9 (1983), S. 313-320 
    ISSN: 1436-2449
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Summary Closed loop diagrams were obtained with ternary systems containing two interacting copolymers (styrene-4-vinylpyridine / styrene-methacrylic acid or methyl methacrylate-4-vinylpyridine / methyl methacrylate-methacrylic acid) and a solvent (dioxane or chloroform). Viscosimetric interaction parameters were determined in both solvents. Higher interactions in chloroform than in dioxane were evidenced from greater positive Δ b23. A single glass transition temperature obtained with the pair of copolymers of styrene-methacrylic acid / butyl methacrylate-4-vinylpyridine confirmed the compatibility of these copolymers in the solid state.
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    Springer
    Polymer bulletin 7 (1982), S. 607-614 
    ISSN: 1436-2449
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Summary Measurements of both apparent molecular weight and second virial coefficient of solutions of styrene-4-vinylpyridine copolymer in ethyl benzoate containing varying concentrations of methyl methacrylate-methacrylic acid copolymer isorefractive with ethyl benzoate were carried out by low angle laser light scattering. The apparent molecular weight depended very little on the acidic copolymer concentration. The second virial coefficient first decreased rapidly, then increased and finally tends to level off as the acidic copolymer concentration was raised. Great association is observed when the visible polymer is in excess.
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  • 7
    Electronic Resource
    Electronic Resource
    Springer
    Mycopathologia 86 (1984), S. 99-101 
    ISSN: 1573-0832
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Medicine
    Notes: Abstract The proteolytic activity of five (ATCC) strains of lactic acid bacteria were investigated in the presence of different concentrations of aflatoxin B-1. The presented data revealed that aflatoxin in milk can affect the lactic acid bacteria which are used in the manufacture of dairy products. Such effect depends on toxin concentration and the species of lactic acid bacteria. This investigation is of practical value because it may explain the effect which occurs during cheese manufacture. This defect can be characterized by off flavour which can be very undesirable for a ripened cheese.
    Type of Medium: Electronic Resource
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  • 8
    ISSN: 1434-4475
    Keywords: Enaminonitriles ; Fused Pyrazoles
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Zusammenfassung Die Reaktion von 5-Amino-4-cyano-3-phenylpyrazol (1) mit Acrylnitril oder Ethylacrylate ergibt 4-Cyano-3-phenyl-4,5,6,7-tetrahydro-5-oxopyrazolo-[1,5-a]-pyrimidin (2). Die Reaktion von1 mit Harnstoff, Thioharnstoff und7. Ethyl acetoacetat ergibt die Pyrazolopyrimidinderivate6a,6b und7. Andererseits entsteht das Thioharnstoffderivat4 durch die Reaktion von1 mit Benzoylisothiocyanat. Diazotiertes1 koppelt mit Malononitril und Ethylcyanoacetat zu den Pyrazolopyrimidinen10 und11, die Kopplung mit α-chloroacetoacetic ester und Acetylaceton ergibt jedoch die Hydrazone12 und13.
    Notes: Abstract 5-Amino-4-cyano-3-phenylpyrazole (1) reacts with acrylonitrile or ethyl acrylate to yield 4-cyano-3-phenyl-4,5,6,7-tetrahydro-5-oxopyrazolo-[1,5-a]-pyrimidine (2). With urea, thiourea and ethyl acetoacetate1 gives the pyrazolopyrimidine derivatives6a,6b, and7 respectively. On the other hand, compound1 reacted with benzoylisothiocyanate to give the corresponding thiourea derivative4. Diazotized1 was coupled with malononitrile and ethyl cyanoacetate to yield the pyrazolopyrimidine derivatives10 and11, respectively, whereas on coupling with α-chloro acetoacetic ester and with acetylacetone the hydrazones12 and13 were obtained.
    Type of Medium: Electronic Resource
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  • 9
    Electronic Resource
    Electronic Resource
    Springer
    Transition metal chemistry 9 (1984), S. 199-202 
    ISSN: 1572-901X
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Summary The extraction of iron(III) and cobalt(II) from hydrochloric acid solutions by Hyamine 1622, a quaternary ammonium halide, in dichloroethane is described. The effect of acidity, salting-out agent, metal and extradant concentrations and temperature, has been investigated. The extraction mechanism is discussed in the light of results obtained. Separation of iron(III) and cobalt(II) is also outlined.
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  • 10
    ISSN: 1573-8310
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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