ALBERT

Description: Reconstructions of global hydroclimate during the Common Era (CE; the past ∼2000 years) are important for providing context for current and future global environmental change. Stable isotope ratios in water are quantitative indicators of hydroclimate on regional to global scales, and these signals are encoded in a wide range of natural geologic archives. Here we present the Iso2k database, a global compilation of previously published datasets from a variety of natural archives that record the stable oxygen (δ18O) or hydrogen (δ2H) isotopic compositions of environmental waters, which reflect hydroclimate changes over the CE. The Iso2k database contains 759 isotope records from the terrestrial and marine realms, including glacier and ground ice (210); speleothems (68); corals, sclerosponges, and mollusks (143); wood (81); lake sediments and other terrestrial sediments (e.g., loess) (158); and marine sediments (99). Individual datasets have temporal resolutions ranging from sub-annual to centennial and include chronological data where available. A fundamental feature of the database is its comprehensive metadata, which will assist both experts and nonexperts in the interpretation of each record and in data synthesis. Key metadata fields have standardized vocabularies to facilitate comparisons across diverse archives and with climate-model-simulated fields. This is the first global-scale collection of water isotope proxy records from multiple types of geological and biological archives. It is suitable for evaluating hydroclimate processes through time and space using large-scale synthesis, model–data intercomparison and (paleo)data assimilation. The Iso2k database is available for download at https://doi.org/10.25921/57j8-vs18 (Konecky and McKay, 2020) and is also accessible via the NOAA/WDS Paleo Data landing page: https://www.ncdc.noaa.gov/paleo/study/29593 (last access: 30 July 2020).

Description: Quantifying the potential exposure of property to damages associated with storm surges, extreme weather and hurricanes is fundamental to developing frameworks that can be used to conceive and implement mitigation plans as well as support urban development that accounts for such events. In this study, we aim at quantifying the total value and area of properties exposed to the flooding associated with Hurricane Florence that occurred in September 2018. To this aim, we implement an approach for the identification of affected areas by generating a map of the maximum flood extent obtained from a combination of the flood extent produced by the Federal Emergency Management Agency's (FEMA's) water marks with those obtained from spaceborne radar remote-sensing data. The use of radar in the creation of the flood extent allows for those properties commonly missed by FEMA's interpolation methods, especially from pluvial or non-fluvial sources, and can be used in more accurately estimating the exposure and market value of properties to event-specific flooding. Lastly, we study and quantify how the urban development over the past decades in the regions flooded by Hurricane Florence might have impacted the exposure of properties to present-day storms and floods. This approach is conceptually similar to what experts are addressing as the “expanding bull's eye effect”, in which “targets” of geophysical hazards, such as people and their built environments, enlarge as populations grow and spread. Our results indicate that the total value of property exposed to flooding during Hurricane Florence was USD 52 billion (in 2018 USD), with this value increasing from USD ∼10 billion at the beginning of the past century to the final amount based on the expansion of the number of properties exposed. We also found that, despite the decrease in the number of properties built during the decade before Florence, much of the new construction was in proximity to permanent water bodies, hence increasing exposure to flooding. Ultimately, the results of this paper provide a new tool for shedding light on the relationships between urban development in coastal areas and the flooding of those areas, which is estimated to increase in view of projected increasing sea level rise, storm surges and the strength of storms.

Description: The North Atlantic Ocean and northwest European shelf experience intense low-pressure systems during the winter months. The effect of strong winds on shelf circulation and water properties is poorly understood as observations during these episodes are rare, and key flow pathways have been poorly resolved by models up to now. We compare the behaviour of a cross-shelf current in a quiescent period in late summer, with the same current sampled during a stormy period in midwinter, using drogued drifters. Concurrently, high-resolution time series of current speed and salinity from a coastal mooring are analysed. A Lagrangian analysis of modelled particle tracks is used to supplement the observations. Current speeds at 70 m during the summer transit are 10–20 cm s−1, whereas on-shelf flow reaches 60 cm s−1 during the winter storm. The onset of high across-shelf flow is identified in the coastal mooring time series, both as an increase in coastal current speed and as an abrupt increase in salinity from 34.50 to 34.85, which lags the current by 8 d. We interpret this as the wind-driven advection of outer-shelf (near-oceanic) water towards the coastline, which represents a significant change from the coastal water pathways which typically feed the inner shelf. The modelled particle analysis supports this interpretation: particles which terminate in coastal waters are recruited locally during the late summer, but recruitment switches to the outer shelf during the winter storm. We estimate that during intense storm periods, on-shelf transport may be up to 0.48 Sv, but this is near the upper limit of transport based on the multi-year time series of coastal current and salinity. The likelihood of storms capable of producing these effects is much higher during positive North Atlantic Oscillation (NAO) winters.

Description: Ice-nucleating particles (INPs) affect cloud development, lifetime, and radiative properties, hence it is important to know the abundance of INPs throughout the atmosphere. A critical factor in determining the lifetime and transport of INPs is their size; however very little size-resolved atmospheric INP concentration information exists. Here we present the development and application of a radio-controlled payload capable of collecting size-resolved aerosol from a tethered balloon for the primary purpose of offline INP analysis. This payload, known as the SHARK (Selective Height Aerosol Research Kit), consists of two complementary cascade impactors for aerosol size-segregation from 0.25 to 10 µm, with an after-filter and top stage to collect particles below and above this range at flow rates of up to 100 L min−1. The SHARK also contains an optical particle counter to quantify aerosol size distribution between 0.38 and 10 µm, and a radiosonde for the measurement of temperature, pressure, GPS altitude, and relative humidity. This is all housed within a weatherproof box, can be run from batteries for up to 11 h, and has a total weight of 9 kg. The radio control and live data link with the radiosonde allow the user to start and stop sampling depending on meteorological conditions and height, which can, for example, allow the user to avoid sampling in very humid or cloudy air, even when the SHARK is out of sight. While the collected aerosol could, in principle, be studied with an array of analytical techniques, this study demonstrates that the collected aerosol can be analysed with an offline droplet freezing instrument to determine size-resolved INP concentrations, activated fractions, and active site densities, producing similar results to those obtained using a standard PM10 aerosol sampler when summed over the appropriate size range. Test data, where the SHARK was sampling near ground level or suspended from a tethered balloon at 20 m altitude, are presented from four contrasting locations having very different size-resolved INP spectra: Hyytiälä (southern Finland), Leeds (northern England), Longyearbyen (Svalbard), and Cardington (southern England).

Description: Reconstructions of global hydroclimate during the Common Era (CE; the past ∼2000 years) are important for providing context for current and future global environmental change. Stable isotope ratios in water are quantitative indicators of hydroclimate on regional to global scales, and these signals are encoded in a wide range of natural geologic archives. Here we present the Iso2k database, a global compilation of previously published datasets from a variety of natural archives that record the stable oxygen (δ18O) or hydrogen (δ2H) isotopic compositions of environmental waters, which reflect hydroclimate changes over the CE. The Iso2k database contains 759 isotope records from the terrestrial and marine realms, including glacier and ground ice (210); speleothems (68); corals, sclerosponges, and mollusks (143); wood (81); lake sediments and other terrestrial sediments (e.g., loess) (158); and marine sediments (99). Individual datasets have temporal resolutions ranging from sub-annual to centennial and include chronological data where available. A fundamental feature of the database is its comprehensive metadata, which will assist both experts and nonexperts in the interpretation of each record and in data synthesis. Key metadata fields have standardized vocabularies to facilitate comparisons across diverse archives and with climate-model-simulated fields. This is the first global-scale collection of water isotope proxy records from multiple types of geological and biological archives. It is suitable for evaluating hydroclimate processes through time and space using large-scale synthesis, model–data intercomparison and (paleo)data assimilation. The Iso2k database is available for download at https://doi.org/10.25921/57j8-vs18 (Konecky and McKay, 2020) and is also accessible via the NOAA/WDS Paleo Data landing page: https://www.ncdc.noaa.gov/paleo/study/29593 (last access: 30 July 2020).

Description: In recent years, sea spray as well as the biological material it contains has received increased attention as a source of ice-nucleating particles (INPs). Such INPs may play a role in remote marine regions, where other sources of INPs are scarce or absent. In the Arctic, these INPs can influence water–ice partitioning in low-level clouds and thereby the cloud lifetime, with consequences for the surface energy budget, sea ice formation and melt, and climate. Marine aerosol is of a diverse nature, so identifying sources of INPs is challenging. One fraction of marine bioaerosol (phytoplankton and their exudates) has been a particular focus of marine INP research. In our study we attempt to address three main questions. Firstly, we compare the ice-nucleating ability of two common phytoplankton species with Arctic seawater microlayer samples using the same instrumentation to see if these phytoplankton species produce ice-nucleating material with sufficient activity to account for the ice nucleation observed in Arctic microlayer samples. We present the first measurements of the ice-nucleating ability of two predominant phytoplankton species: Melosira arctica, a common Arctic diatom species, and Skeletonema marinoi, a ubiquitous diatom species across oceans worldwide. To determine the potential effect of nutrient conditions and characteristics of the algal culture, such as the amount of organic carbon associated with algal cells, on the ice nucleation activity, Skeletonema marinoi was grown under different nutrient regimes. From comparison of the ice nucleation data of the algal cultures to those obtained from a range of sea surface microlayer (SML) samples obtained during three different field expeditions to the Arctic (ACCACIA, NETCARE, and ASCOS), we found that they were not as ice active as the investigated microlayer samples, although these diatoms do produce ice-nucleating material. Secondly, to improve our understanding of local Arctic marine sources as atmospheric INPs we applied two aerosolization techniques to analyse the ice-nucleating ability of aerosolized microlayer and algal samples. The aerosols were generated either by direct nebulization of the undiluted bulk solutions or by the addition of the samples to a sea spray simulation chamber filled with artificial seawater. The latter method generates aerosol particles using a plunging jet to mimic the process of oceanic wave breaking. We observed that the aerosols produced using this approach can be ice active, indicating that the ice-nucleating material in seawater can indeed transfer to the aerosol phase. Thirdly, we attempted to measure ice nucleation activity across the entire temperature range relevant for mixed-phase clouds using a suite of ice nucleation measurement techniques – an expansion cloud chamber, a continuous-flow diffusion chamber, and a cold stage. In order to compare the measurements made using the different instruments, we have normalized the data in relation to the mass of salt present in the nascent sea spray aerosol. At temperatures above 248 K some of the SML samples were very effective at nucleating ice, but there was substantial variability between the different samples. In contrast, there was much less variability between samples below 248 K. We discuss our results in the context of aerosol–cloud interactions in the Arctic with a focus on furthering our understanding of which INP types may be important in the Arctic atmosphere.

Description: Ice shelves play a critical role in the long-term stability of ice sheets through their buttressing effect. The underlying bathymetry and cavity thickness are key inputs for modelling future ice sheet evolution. However, direct observation of sub-ice-shelf bathymetry is time-consuming, logistically risky, and in some areas simply not possible. Here we use new compilations of airborne and marine gravity, radar depth sounding, and swath bathymetry to provide new estimates of sub-ice-shelf bathymetry outboard of the rapidly changing West Antarctic Thwaites Glacier and beneath the adjacent Dotson and Crosson ice shelves. This region is of special interest, as the low-lying inland reverse slope of the Thwaites Glacier system makes it vulnerable to marine ice sheet instability, with rapid grounding line retreat observed since 1993 suggesting this process may be underway. Our results confirm a major marine channel 〉800 m deep extends tens of kilometres to the front of Thwaites Glacier, while the adjacent ice shelves are underlain by more complex bathymetry. Comparison of our new bathymetry with ice shelf draft reveals that ice shelves formed since 1993 comprise a distinct population where the draft conforms closely to the underlying bathymetry, unlike the older ice shelves, which show a more uniform depth of the ice base. This indicates that despite rapid basal melting in some areas, these recently floated parts of the ice shelf are not yet in dynamic equilibrium with their retreated grounding line positions and the underlying ocean system, a factor which must be included in future models of this region's evolution.

Description: Deposition to the sea surface is a major atmospheric loss pathway for many important trace gases, such as sulfur dioxide (SO2). The air–sea transfer of SO2 is controlled entirely on the atmospheric side of the air–sea interface due to high effective solubility and other physical–chemical properties. There have been few direct field measurements of such fluxes due to the challenges associated with making fast-response measurements of highly soluble trace gases at very low ambient levels. In this study, we report direct eddy covariance air–sea flux measurements of SO2, sensible heat, water vapor, and momentum. The measurements were made over shallow coastal waters from the Scripps Pier, La Jolla, CA, using negative ion chemical ionization mass spectrometry as the SO2 sensor. The observed transfer velocities for SO2, sensible heat, water vapor, and momentum and their wind speed dependences indicate that SO2 fluxes can be reliably measured using this approach. As expected, the transfer velocities for SO2, sensible heat, and water vapor are lower than that for momentum, demonstrating the contribution of molecular diffusion to the overall air-side resistance to gas transfer. Furthermore, transfer velocities of SO2 were lower than those of sensible heat and water vapor when observed simultaneously. This result is attributed to diffusive resistance in the interfacial layer of the air–sea interface.

Description: Low concentrations of ice-nucleating particles (INPs) are thought to be important for the properties of mixed-phase clouds, but their detection is challenging. Hence, there is a need for instruments where INP concentrations of less than 0.01 L−1 can be routinely and efficiently determined. The use of larger volumes of suspension in drop assays increases the sensitivity of an experiment to rarer INPs or rarer active sites due to the increase in aerosol or surface area of particulates per droplet. Here we describe and characterise the InfraRed-Nucleation by Immersed Particles Instrument (IR-NIPI), a new immersion freezing assay that makes use of IR emissions to determine the freezing temperature of individual 50 µL droplets each contained in a well of a 96-well plate. Using an IR camera allows the temperature of individual aliquots to be monitored. Freezing temperatures are determined by detecting the sharp rise in well temperature associated with the release of heat caused by freezing. In this paper we first present the calibration of the IR temperature measurement, which makes use of the fact that following ice nucleation aliquots of water warm to the ice–liquid equilibrium temperature (i.e. 0 ∘C when water activity is ∼1), which provides a point of calibration for each individual well in each experiment. We then tested the temperature calibration using ∼100 µm chips of K-feldspar, by immersing these chips in 1 µL droplets on an established cold stage (µL-NIPI) as well as in 50 µL droplets on IR-NIPI; the results were consistent with one another, indicating no bias in the reported freezing temperature. In addition we present measurements of the efficiency of the mineral dust NX-illite and a sample of atmospheric aerosol collected on a filter in the city of Leeds. NX-illite results are consistent with literature data, and the atmospheric INP concentrations were in good agreement with the results from the µL-NIPI instrument. This demonstrates the utility of this approach, which offers a relatively high throughput of sample analysis and access to low INP concentrations.

Description: The European Slope Current provides a shelf-edge conduit for Atlantic Water, a substantial fraction of which is destined for the northern North Sea, with implications for regional hydrography and ecosystems. Drifters drogued at 50 m in the European Slope Current at the Hebridean shelf break follow a wide range of pathways, indicating highly variable Atlantic inflow to the North Sea. Slope Current pathways, timescales and transports over 1988–2007 are further quantified in an eddy-resolving ocean model hindcast. Particle trajectories calculated with model currents indicate that Slope Current water is largely recruited from the eastern subpolar North Atlantic. Observations of absolute dynamic topography and climatological density support theoretical expectations that Slope Current transport is to first order associated with meridional density gradients in the eastern subpolar gyre, which support a geostrophic inflow towards the slope. In the model hindcast, Slope Current transport variability is dominated by abrupt 25–50 % reductions of these density gradients over 1996–1998. Concurrent changes in wind forcing, expressed in terms of density gradients, act in the same sense to reduce Slope Current transport. This indicates that coordinated regional changes of buoyancy and wind forcing acted together to reduce Slope Current transport during the 1990s. Particle trajectories further show that 10–40 % of Slope Current water is destined for the northern North Sea within 6 months of passing to the west of Scotland, with a general decline in this percentage over 1988–2007. Salinities in the Slope Current correspondingly decreased, evidenced in ocean analysis data. Further to the north, in the Atlantic Water conveyed by the Slope Current through the Faroe–Shetland Channel (FSC), salinity is observed to increase over this period while declining in the hindcast. The observed trend may have broadly compensated for a decline in the Atlantic inflow, limiting salinity changes in the northern North Sea during this period. Proxies for both Slope Current transport and Atlantic inflow to the North Sea are sought in sea level height differences across the FSC and between Shetland and the Scottish mainland (Wick). Variability of Slope Current transport on a wide range of timescales, from seasonal to multi-decadal, is implicit in sea level differences between Lerwick (Shetland) and Tórshavn (Faroes), in both tide gauge records from 1957 and a longer model hindcast spanning 1958–2012. Wick–Lerwick sea level differences in tide gauge records from 1965 indicate considerable decadal variability in the Fair Isle Current transport that dominates Atlantic inflow to the northwest North Sea, while sea level differences in the hindcast are dominated by strong seasonal variability. Uncertainties in the Wick tide gauge record limit confidence in this proxy.