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  • PANGAEA  (3)
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  • 1
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    PANGAEA
    In:  Supplement to: Croot, Peter L; Baars, Oliver; Streu, Peter (2011): The distribution of dissolved zinc in the Atlantic sector of the Southern Ocean. Deep Sea Research Part II: Topical Studies in Oceanography, 58(25-26), 2707-2719, https://doi.org/10.1016/j.dsr2.2010.10.041
    Publication Date: 2023-10-28
    Description: The distribution of dissolved zinc (Zn) was investigated in the Atlantic sector of the Southern Ocean in the austral autumn of 2008 as part of the IPY GEOTRACES expedition ZERO & DRAKE. Research focused on transects across the major frontal systems along the Zero Meridian and across the Drake Passage. There was a strong gradient in surface zinc concentrations observed across the Antarctic Polar Front along both transects and high zinc levels were found in surface waters throughout the Southern Ocean. Vertical profiles for dissolved Zinc showed the presence of local minima and maxima in the upper 200 m consistent with significant uptake by phytoplankton and release by zooplankton grazing, respectively. Highest deep water zinc concentrations were found in the centre of the Weddell Gyre associated with Central Intermediate Water (CIW), a water mass which is depleted in O2, elevated in CO2 and is regionally a CFC minimum. Our data suggests that the remineralization of sinking particles is a key control on the distribution of Zn in the Southern Ocean. Disappearance ratios of zinc to phosphate (Zn:P) in the upper water column increased southwards along both transects and based on laboratory studies they suggest slower growth rates of phytoplankton due to iron or light limitation. Zinc and silicate were strongly correlated throughout the study region but the disappearance ratio (Zn:Si) was relatively uniform overall except for the region close to the ice edge on the Zero Meridian.
    Keywords: ANT-XXIV/3; Bottle number; CTD/Rosette, ultra clean; CTD-UC; Date/Time of event; DEPTH, water; Drake Passage; Element analyser AAS, graphite furnace, Perkin-Elmer 4100 ZL; Elevation of event; Event label; GEOTRACES; Global marine biogeochemical cycles of trace elements and their isotopes; Latitude of event; Longitude of event; Nitrate and Nitrite; Nitrite; Phosphate; Polarstern; Pressure, water; Priority Programme 1158 Antarctic Research with Comparable Investigations in Arctic Sea Ice Areas; PS71; PS71/103-1; PS71/104-2; PS71/107-3; PS71/113-3; PS71/119-1; PS71/128-1; PS71/131-5; PS71/141-1; PS71/150-2; PS71/167-1; PS71/230-6; PS71/236-3; PS71/241-6; PS71/249-3; Salinity; Scotia Sea, southwest Atlantic; Silicate; South Atlantic Ocean; SPP1158; Temperature, water; Weddell Sea; Zinc, dissolved
    Type: Dataset
    Format: text/tab-separated-values, 1184 data points
    Location Call Number Expected Availability
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  • 2
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    Unknown
    PANGAEA
    In:  Supplement to: Baars, Oliver; Croot, Peter L (2011): The speciation of dissolved zinc in the Atlantic sector of the Southern Ocean. Deep Sea Research Part II: Topical Studies in Oceanography, 58(25-26), 2720-2732, https://doi.org/10.1016/j.dsr2.2011.02.003
    Publication Date: 2023-10-28
    Description: The speciation of dissolved zinc (Zn) was investigated by voltammetry in the Atlantic sector of the Southern Ocean along two transects across the major frontal systems: along the Zero Meridian and across the Drake Passage. In the Southern Ocean south of the APF we found detectable labile inorganic Zn throughout the surface waters in contrast to studies from lower latitudes. Using a combination of ASV titrations and pseudopolarography revealed the presence of significant concentration of electrochemically inert Zn ligands throughout the Southern Ocean. These ligands however were nearly always saturated due to the presence of excess concentrations of dissolved Zn that were associated with the high nutrient waters south of the Antarctic Polar Front (APF). Only in surface waters did the concentration of Zn complexing ligands exceed the dissolved Zn concentrations suggesting a biological source for these ligands. Our findings have clear implications for the biogeochemical cycling of Zn and for the interpretation of paleo records utilizing Zn in opal as a tracer of Zn speciation in the water column.
    Keywords: ANT-XXIV/3; Constant; CTD/Rosette, ultra clean; CTD-UC; Date/Time of event; DEPTH, water; Elevation of event; Event label; Latitude of event; Ligand concentration; Longitude of event; Polarstern; Priority Programme 1158 Antarctic Research with Comparable Investigations in Arctic Sea Ice Areas; PS71; PS71/107-3; PS71/131-5; PS71/161-1; PS71/167-1; PS71/241-6; Scotia Sea, southwest Atlantic; South Atlantic Ocean; SPP1158; Standard deviation; Titration; Weddell Sea; Zinc; Zinc, standard deviation
    Type: Dataset
    Format: text/tab-separated-values, 49 data points
    Location Call Number Expected Availability
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  • 3
    Publication Date: 2024-02-02
    Keywords: Climate - Biogeochemistry Interactions in the Tropical Ocean; Cobalt; CTD; Date/Time of event; DEPTH, water; Elevation of event; Event label; GOFLO; Go-Flo bottles; GoFlo bottles 11; GoFlo bottles 3; GoFlo bottles 6; GoFlo bottles 7; GoFlo bottles 9; Latitude of event; Longitude of event; M80/2; M80/2_1246; M80/2_1272; M80/2_1305; M80/2_1328; M80/2_1360; Meteor (1986); Nitrate; Nitrite; Oxygen; Phosphate; Sample code/label; SFB754; Silicate
    Type: Dataset
    Format: text/tab-separated-values, 424 data points
    Location Call Number Expected Availability
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