Publication Date:
2011-07-24
Description:
We conducted 1 atm experiments on a synthetic Hawaiian picrite at f O 2 values ranging from the quartz–fayalite–magnetite (QFM) buffer to air and temperatures ranging from 1302 to 1600°C. Along the QFM buffer, olivine is the liquidus phase at ~1540°C and small amounts of spinel (〈 0·2 wt %) are present in experiments conducted at and below 1350°C. The olivine becomes progressively more ferrous with decreasing temperature [Fo 92 · 3 to Fo 87 · 3 , where Fo = 100 x Mg/(Mg + Fe), atomic]; compositions of coexisting liquids reflect the mode and composition of the olivine with concentrations of SiO 2 , TiO 2 , Al 2 O 3 , and CaO increasing monotonically with decreasing temperature, those of NiO and MgO decreasing, and FeO* (all Fe as FeO) remaining roughly constant. An empirical relationship based on our data, T (°C) = 19·2 x (MgO in liquid, wt %) + 1048, provides a semi-quantitative geothermometer applicable to a range of Hawaiian magma compositions. The olivine–liquid exchange coefficient, = (FeO/MgO) ol /(FeO/MgO) liq , is 0·345 ± 0·009 (1 ) for our 11 experiments. A literature database of 446 1 atm experiments conducted within 0·25 log units of the QFM buffer (QFM ± 0·25) yields a median of 0·34; values from single experiments range from 0·41 to 0·13 and are correlated with SiO 2 and alkalis in the liquid, as well as the forsterite (Fo) content of the olivine. For 78 experiments with broadly tholeiitic liquid compositions (46–52 wt % SiO 2 and ≤ 3 wt % Na 2 O + K 2 O) coexisting with Fo 92 – 80 olivines, and run near QFM (QFM ± 0·25), is approximately independent of composition with a median value of 0·340 ± 0·012 (error is the mean absolute deviation of the 78 olivine–glass pairs from the database that meet these compositional criteria), a value close to the mean value of 0·343 ± 0·008 from our QFM experiments. Thus, over the composition range encompassed by Hawaiian tholeiitic lavas and their parental melts, ~ 0·34 and, given the redox conditions and a Fo content for the most magnesian olivine phenocrysts, a parental melt composition can be reconstructed. The calculated compositions of the parental melts are sensitive to the input parameters, decreasing by ~1 wt % MgO for every log unit increase in the selected f O 2 , every 0·5 decrease in the Fo-number of the target olivine, and every 0·015 decrease in . For plausible ranges in redox conditions and Fo-number of the most MgO-rich olivine phenocrysts, the parental liquids for Hawaiian tholeiites are highly magnesian, in the range of 19–21 wt % MgO for Kilauea, Mauna Loa and Mauna Kea.
Print ISSN:
0022-3530
Electronic ISSN:
1460-2415
Topics:
Geosciences
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