Publication Date:
2019-10-17
Description:
A unique chemical analytical approach is proposed based on the integration of chemical radiophysics with electrochemistry at the catalytically-active surface. This approach includes integration of: radiofrequency modulation polarography with platinum electrodes, applied as film enthrakometers for microwave measurements; microwave thermal analysis performed on enthrakometers as bolometric sensors; catalytic measurements, including registration of chemical self-oscillations on the surface of a platinum enthrakometer as the chemosensor; measurements on the Pt chemosensor implemented as an electrochemical chip with the enthrakometer walls acting as the chip walls; chemotron measurements and data processing in real time on the surface of the enthrakometric chip; microwave electron paramagnetic resonance (EPR) measurements using an enthrakometer both as a substrate and a microwave power meter; microwave acceleration of chemical reactions and microwave catalysis оn the Pt surface; chemical generation of radio- and microwaves, and microwave spin catalysis; and magnetic isotope measurements on the enthrakometric chip. The above approach allows one to perform multiparametric physical and electrochemical sensing on a single active enthrakometric surface, combining the properties of the selective electrochemical sensor and an additive physical detector.
Electronic ISSN:
2227-9040
Topics:
Chemistry and Pharmacology
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