ALBERT

Description: Bronization and carburization of fine-grain superplastic stainless steel is reviewed, and new experimental results for fine grain Ti88.5Al4.5V3Fe2Mo2 are reported. In superplastic duplex stainless steel, the diffusion of carbon and boron is faster than in non-superplastic duplex stainless steel. Further, diffusion is activated by uniaxial compressive stress. Moreover, non-superplastic duplex stainless steel shows typical grain boundary diffusion; however, inner grain diffusion is confirmed in superplastic stainless steel. The presence of Fe and Cr carbides or borides is confirmed by X-ray diffraction, which indicates that the diffused carbon and boron react with the Fe and Cr in superplastic stainless steel. The Vickers hardness of the carburized and boronized layers is similar to that achieved with other surface treatments such as electro-deposition. Diffusion of boron into the superplastic Ti88.5Al4.5V3Fe2Mo2 alloy was investigated. The hardness of the surface exposed to boron powder can be increased by annealing above the superplastic temperature. However, the Vickers hardness is lower than that of Ti boride.

Description: Satellite remote sensing is a highly useful tool for monitoring chlorophyll-a concentration (Chl-a) in water bodies. Remote sensing algorithms based on near-infrared-red (NIR-red) wavelengths have demonstrated great potential for retrieving Chl-a in inland waters. This study tested the performance of a recently developed NIR-red based algorithm, SAMO-LUT (Semi-Analytical Model Optimizing and Look-Up Tables), using an extensive dataset collected from five Asian lakes. Results demonstrated that Chl-a retrieved by the SAMO-LUT algorithm was strongly correlated with measured Chl-a (R2 = 0.94), and the root-mean-square error (RMSE) and normalized root-mean-square error (NRMS) were 8.9 mg∙m−3 and 72.6%, respectively. However, the SAMO-LUT algorithm yielded large errors for sites where Chl-a was less than 10 mg∙m−3 (RMSE = 1.8 mg∙m−3 and NRMS = 217.9%). This was because differences in water-leaving radiances at the NIR-red wavelengths (i.e., 665 nm, 705 nm and 754 nm) used in the SAMO-LUT were too small due to low concentrations of water constituents. Using a blue-green algorithm (OC4E) instead of the SAMO-LUT for the waters with low constituent concentrations would have reduced the RMSE and NRMS to 1.0 mg∙m−3 and 16.0%, respectively. This indicates (1) the NIR-red algorithm does not work well when water constituent concentrations are relatively low; (2) different algorithms should be used in light of water constituent concentration; and thus (3) it is necessary to develop a classification method for selecting the appropriate algorithm.

Description: Rapid, simple, and low-cost screening procedures are necessary for the detection of harmful compounds in the effluent that flows out of point sources such as industrial outfall. The present study investigated the effects on a novel sensor of harmful compounds such as KCN, phenol, and herbicides such as 3-(3,4-dichlorophenyl)-1,1-dimethylurea (DCMU), 2-chloro-4-ethylamino-6-isopropylamino-1,3,5-triazine (atrazine), and 2-N-tert-butyl-4-N-ethyl-6-methylsulfanyl-1,3,5-triazine-2,4-diamine (terbutryn). The sensor employed an electrode system that incorporated the photocurrent of intra-cytoplasmic membranes (so-called chromatophores) prepared from photosynthetic bacteria and linked using carbon paste electrodes. The amperometric curve (photocurrent-time curve) of photo-induced electron transfer from chromatophores of the purple photosynthetic bacterium Rhodobacter sphaeroides to the electrode via an exogenous electron acceptor was composed of two characteristic phases: an abrupt increase in current immediately after illumination (I0), and constant current over time (Ic). Compared with other redox compounds, 2,5-dichloro-1,4-benzoquinone (DCBQ) was the most useful exogenous electron acceptor in this system. Photo-reduction of DCBQ exhibited Michaelis-Menten-like kinetics, and reduction rates were dependent on the amount of DCBQ and the photon flux intensity. The Ic decreased in the presence of KCN at concentrations over 0.05 μM (=μmol·dm−3). The I0 decreased following the addition of phenol at concentrations over 20 μM. The Ic was affected by terbutryn at concentrations over 10 μM. In contrast, DCMU and atrazine had no effect on either I0 or Ic. The utility of this electrode system for the detection of harmful compounds is discussed.

Description: Terminally hydroxylated polypropylene (PP) synthesized by a chain transfer method was grafted to graphene oxide (GO) at the chain end. Thus obtained PP-modified GO (PP-GO) was melt mixed with PP without the use of a compatibilizer to prepare PP/GO nanocomposites. Mechanical and electrical properties of the resultant nanocomposites and reference samples that contained graphite nanoplatelets, partially reduced GO, or fully reduced GO were examined. The best improvement in the tensile strength was obtained using PP-GO at 1.0 wt %. The inclusion of PP-GO also led to the highest electrical conductivity, in spite of the incomplete reduction. These observations pointed out that terminally hydroxylated PP covalently grafted to GO prevented GO layers from re-stacking and agglomeration during melt mixing, affording improved dispersion as well as stronger interfacial bonding between the matrix and GO.

Description: Sustainability, Vol. 10, Pages 59: Research and Development Strategy for Fishery Technology Innovation for Sustainable Fishery Resource Management in North-East Asia Sustainability doi: 10.3390/su10010059 Authors: Hidemichi Fujii Yoshitaka Sakakura Atsushi Hagiwara John Bostock Kiyoshi Soyano Yoshiki Matsushita The development of fishery technologies supports food sustainability to achieve a steady supply of fish and fishery products. However, the priorities for research and development (R&D) in fishery technologies vary by region due to differences in fish resource availability, environmental concerns, and consumer preferences for fishery products. This study examines trends in fishery technology innovations using data on patents granted as an indicator of changing R&D priorities. To clarify changes in R&D priorities, we apply a decomposition analysis framework that classifies fishery technologies into three types: harvesting, aquaculture, and new products. This study mainly focuses on China, Japan, and Korea as the major fishing countries in the north-east Asia region. The results show that the number of fishery technology patents granted increased between 1993 and 2015; in particular, the number of aquaculture patents granted has grown rapidly since 2012. However, the trend in Japan was the opposite, as the apparent priority given to aquaculture technology innovation decreased between 1993 and 2015. The trends and priority changes for fishery technology inventions vary by country and technology group. This implies that an international policy framework for fishery technology development should recognize that R&D priorities need to reflect diverse characteristics across countries and the technologies employed.