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  • 1
    Publication Date: 2018-04-26
    Description: Materials, Vol. 11, Pages 666: Effect of Inoculant Alloy Selection and Particle Size on Efficiency of Isomorphic Inoculation of Ti-Al Materials doi: 10.3390/ma11050666 Authors: J. R. Kennedy B. Rouat D. Daloz E. Bouzy J. Zollinger The process of isomorphic inoculation relies on precise selection of inoculant alloys for a given system. Three alloys, Ti-10Al-25Nb, Ti-25Al-10Ta, and Ti-47Ta (at %) were selected as potential isomorphic inoculants for a Ti-46Al alloy. The binary Ti-Ta alloy selected was found to be ineffective as an inoculant due to its large density difference with the melt, causing the particles to settle. Both ternary alloys were successfully implemented as isomorphic inoculants that decreased the equiaxed grain size and increased the equiaxed fraction in their ingots. The degree of grain refinement obtained was found to be dependent on the number of particles introduced to the melt. Also, more new grains were formed than particles added to the melt. The grains/particle efficiency varied from greater than one to nearly twenty as the size of the particle increased. This is attributed to the breaking up of particles into smaller particles by dissolution in the melt. For a given particle size, Ti-Al-Ta and Ti-Al-Nb particles were found to have a roughly similar grain/particle efficiency.
    Electronic ISSN: 1996-1944
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Published by MDPI Publishing
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  • 2
    Publication Date: 2014-08-03
    Description: The central Taupo Volcanic Zone (TVZ) is an actively rifting continental arc and is well known for its exceptionally high rate of rhyolitic magma generation and frequent caldera-forming eruptions. Two end-member types of rhyolites (R1 and R2) have been previously identified based on differences in their bulk-rock chemistry and mineral assemblage with hydrous phases crystallizing in the R1 type, which are not present or only rare in R2 rhyolites. Here we present new trace element and volatile data from rhyolitic melt inclusions measured in several representative eruptive deposits (R1 and R2 rhyolites) from the central TVZ to examine their volatile concentrations and origin. R1 and R2 show very distinct Cl concentrations, with R2 rhyolites being enriched in Cl by c . 1000 ppm. H 2 O is slightly higher in the R1 rhyolites, whereas CO 2 concentrations are similar between the two end-member types. The origin of these volatile disparities between R1 and R2 melts is assigned to differences in the initial bulk volatile content of the parental magma, possibly associated with distinct input of fluids from the subduction zone. These disparities in bulk volatile concentrations can lead to variations in relative timing of exsolution of volatile phase(s) prior to melt inclusion entrapment. Supplementary material: Major, trace and volatile composition for the analysed central TVZ rhyolites, and comparison of H 2 O data between the transmission and reflectance FTIR are available at http://www.geolsoc.org.uk/SUP18767 .
    Print ISSN: 0305-8719
    Electronic ISSN: 2041-4927
    Topics: Geosciences
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