ALBERT

Description: Authigenic low-magnesium calcite (LMC)—a mineral phase that should precipitate in calcite seas rather than today’s aragonite sea—was recently discovered at the seafloor of the Gulf of Mexico (GoM) at water depths of 65 m (site SS296) and 189 m (site GC53). This study investigates the mineralogical, petrographic, and geochemical characteristics of LMC from both sites to reveal its formation process. The δ18O values of LMC from site SS296 cluster in two groups (−0.6‰ to 1.7‰; 6.3‰ to 7.5‰) and the presence of cone-in-cone texture in the samples with lower δ18O values suggest precipitation at higher temperatures and greater depth. Low δ18O values of LMC from site GC53 ranging from −9.4‰ to −2.5‰ indicate an influence of meteoric waters during formation. LMC at both sites reveals a wide range of δ13C values (−17.4‰ to 2.6‰), indicating various carbon sources including seawater and/or organic matter. This interpretation is further supported by the δ13C values of organic carbon extracted from the LMC lithologies (δ13Corg: from −26.8‰ to −18.9‰). Relatively low Sr concentrations of LMC samples regardless of variable 87Sr/86Sr ratios, ranging from 0.707900 to 0.708498 for site GC53 and from 0.709537 to 0.710537 for site SS396, suggest the exchange of Sr between pore fluids and ambient sediments/rocks. The observed wide range of 87Sr/86Sr ratios and the enrichment of Fe and Mn in LMC is in accordance with pore fluids deriving from the dissolution of Louann salt. Overall, this study reveals that the formation of LMC at sites SS296 and GC53 was favored by the presence of low Mg/Ca ratio pore fluids resulting from salt dissolution in subsurface environments when sufficient dissolved inorganic carbon was available. These results are essential for understanding the formation of marine LMC at times of an aragonite sea, highlighting the role of formation environments—open environments close to or at the seafloor vs. confined subseafloor environments typified by pore waters with a composition largely different from that of seawater.

Description: The inkjet printing of nanoparticle inks to produce metal coatings is low in manufacturing cost and high in efficiency compared to conventional methods such as electroplating and etching. However, inkjet-printed metal coatings require sintering to provide better metal conductivity and adhesion. Traditional sintering methods require high processing temperatures that can easily damage the coating substrate. In this study, an enhanced overall conductivity is achieved by sintering a nanoparticle metal coating with intense pulsed light. Metal coatings sintered using different parameters were characterized by a profilometer and a four-probe tester, which showed that the surface topographies differed with different sintering degrees. The adhesion of the metal coating was proportional to the pre-sintering temperature within the allowable range of the substrate. Finally, the optimization of the sintering process according to the experimental results improved both the electrical conductivity and adhesion of the metal coating. The optimized parameters were used to fabricate a microstrip antenna and perform the return loss test and microwave darkroom test. The results matched the simulation results well.

Description: In the tropical region, convective rain is a dominant rain event. However, very little information is known about the convective rain melting layer. In this paper, S-band dual-polarized radar data is studied in order to identify both the stratiform and convective rain melting layers in the tropical region, with a focus on the convective events. By studying and analyzing the above-mentioned two types of rain events, amongst three radar measurements of reflectivity ( Z ), differential reflectivity ( Z DR ), and cross correlation coefficient ( ρ HV ), the latter one is the best indicator for convective rain melting layer detection. From two years (2014 and 2015) of radar and radiosonde observations, 13 convective rain melting layers are identified with available 0 °C isothermal heights which are derived from radiosonde vertical profiles. By comparing the melting layer top heights with the corresponding 0 °C isothermal heights, it is found that for convective rain events, the threshold to detect melting layer should be modified to ρ HV = 0.95 for the tropical region. The melting layer top and bottom heights are then estimated using the proposed threshold, and it is observed from this study that the thickness of convective rain melting layer is around 2 times that of stratiform rain melting layer which is detected by using the conventional ρ HV = 0.97 .

Description: Cold-water corals (CWCs) are frequently found at cold seep areas. However, the relationship between fluid seepage and CWC development is not clear. Here, for the first time, we report the occurrences, species identification, mineralogy, carbon and oxygen isotopes, as well as elemental compositions of fossil CWC skeletons from gas-hydrate-bearing sediment in drilling cores from the South China Sea (SCS). Three sites (GMGS-08, GMGS-09B, and GMGS-16) were investigated but CWCs were only found at one site (GMGS-09B). Interestingly, the CWCs were found in three horizons and they were all embedded with authigenic carbonates. Three genera of fossil CWCs (Crispatotrochus sp., Solenosmilia sp. and Enallopsammia sp.) were identified. The CWC fragments are predominantly aragonite. The CWCs exhibit δ13C values between −8.4‰ and −0.6‰ that are significantly higher than δ13C values of the associated seep carbonates (δ13C values with an average of −55.6‰, n = 19), which indicates a carbon source other than methane for the CWCs. It appears that authigenic carbonates provide a substratum for coral colonization. Bathymetric high points, appropriate water temperature and stronger bottom-water currents at site GMGS-09B might be crucial to keep conditions favorable for the growth of CWCs in the studied area. In addition, high trace-element concentrations of Cr, Ni, Pb, U, Ba, Th, and Sr suggest that the CWCs are influenced by strong fluid seepage that can reach the water-sediment interface, and associated microbial activity. Hence, it also becomes evident that CWCs in hydrocarbon-rich seepage areas not only provide a critical constraint on the impact of fluid emission on the bottom water chemistry, but also are likely to be very precise recorders of the end time of cold seep activity.