ALBERT

Description: This study was focused on the generation of sulfate radicals and their applicability as powerful oxidants for degrading complex organic compounds with the final objective of operating in flow systems. To this end, the removal of two compounds from the pharmaceutical industry was assessed, lissamine green and prednisolone. Initially, sulfate radicals were generated by the activation of persulfate with iron as homogenous catalyst, and the key parameters involved in the process, as catalyst concentration and oxidant dosage, were evaluated. Furthermore, with the aim of preventing the secondary contamination due to metal leaching and to be operate in a continuous mode, a heterogeneous catalyst was developed. For it, the iron was fixed on a cationic resin as Amberlite IR120 Na+ form. It was demonstrated that the removal of both pollutants increases with greater catalyst dosages, achieving a decay of 85% within 25 min with 30 g·L−1 of catalyst. Moreover, the reuse capability of the catalyst was tested, illustrating that it is rough enough for its reuse. Conversely, in order to develop a continuous treatment in flow system, a fixed bed reactor was constructed and its feasibility was proven. Different experiments with residence times from 10 min to 60 min were performed, obtaining a removal level of ≈95% and 90% for prednisolone and lissamine green, respectively, at residence time of 60 min. In conclusion, the potential of sulfate radicals-based technology for degrading organic contaminants has been demonstrated.

Description: Namibia is a dry and low populated country highly dependent on agriculture, with many areas experiencing land degradation accelerated by climate change. One of the most obvious and damaging manifestations of these degradation processes are gullies, which lead to great economic losses while accelerating desertification. The development of standardized methods to detect and monitor the evolution of gully-affected areas is crucial to plan prevention and remediation strategies. With the aim of developing solutions applicable at a regional or even national scale, fully automated satellite-based remote sensing methods are explored in this research. For this purpose, three different algorithms are applied to a Digital Elevation Model (DEM) generated from the TanDEM-X satellite mission to extract gullies from their geomorphological characteristics: (i) Inverted Morphological Reconstruction (IMR), (ii) Smoothing Moving Polynomial Fitting (SMPF) and (iii) Multi Profile Curvature Analysis (MPCA). These algorithms are adapted or newly developed to identify gullies at the pixel level (12 m) in our study site in the Krumhuk Farm. The results of the three methods are benchmarked with ground truth; specific scenarios are observed to better understand the performance of each method. Results show that MPCA is the most reliable method to identify gullies, achieving an overall accuracy of approximately 0.80 with values of Cohen Kappa close to 0.35. The performance of these parameters improves when detecting large gullies (〉30 m width and 〉3 m depth) achieving Total Accuracies (TA) near to 0.90, Cohen Kappa above 0.5, and User Accuracy (UA) and Producer Accuracy (PA) over 0.50 for the gully class. Small gullies (〈12 m wide and 〈2 m deep) are usually neglected in the classification results due to spatial resolution constraints within the input DEM. In addition, IMR generates accurate results for UA in the gully class (0.94). The MPCA method developed here is a promising tool for the identification of large gullies considering extensive study areas. Nevertheless, further development is needed to improve the accuracy of the algorithms, as well as to derive geomorphological gully parameters (e.g., perimeter and volume) instead of pixel-level classification.

Description: The advent of the autonomous car is paving the road to the realization of ideas that will help optimize traffic flows, increase safety and reduce fuel consumption, among other advantages. We present one proposal to bring together Virtual Traffics Lights (VTLs) and platooning in urban scenarios, leaning on vehicle-to-vehicle (V2V) communication protocols that turn intersections into virtual containers of data. Newly-introduced protocols for the combined management of VTLs and platoons are validated by simulation, comparing a range of routing protocols for the vehicular networks with the baseline given by common deployments of traditional traffic lights ruled by state-of-the-art policies. The simulation results show that the combination of VTLs and platoons can achieve significant reductions in travel times and fuel consumption, provided that proper algorithms are used to handle the V2V communications.

Description: Many deaf women face the lack of numerous resources related to their personal development. The unavailability of proper information on Sexual and Reproductive Health (SRH), in particular, causes problems of sexually transmitted infections, unwanted pregnancy in adolescence, sexual violence, complications during pregnancy, etc. In response to this, we have created a social network that delivers SRH content (verified and validated by experts) to women with different degrees of hearing loss. The site features a recommender system that selects the most relevant pieces of content to deliver to each woman, driven by her individual preferences, needs and levels of knowledge on the different subjects. We report experiments conducted in Cuenca, Ecuador, between 2017 and 2018 with 98 volunteers from low- and middle-income settings, aiming to evaluate the quality and appeal of the contents, the coherence of the methodology followed to create them, and the effectiveness of the content recommendations. The positive results encourage the frequent creation of new content and the refinement of the recommendation logic as the cohort of users expands over time.