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Inclusion of HNEt3+ in an acyclic tetraphenolate (2000)

Leverd, Pascal C. ; Weber, Dirk ; Habicher, Wolf D. ; [et al.]

Oxford [u.a.] : International Union of Crystallography (IUCr)

Acta crystallographica 56 (2000), S. 997-998

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ISSN: 1600-5759

Source: Crystallography Journals Online : IUCR Backfile Archive 1948-2001

Topics: Chemistry and Pharmacology , Geosciences , Physics

Notes: The acyclic tetraphenolic derivative 2,2′-methylenebis[6-(3-tert-butyl-2-hydroxy-5-methylbenzyl)-4-methylphenol] reacts with excess triethylamine in acetonitrile to form a molecular complex, i.e. triethylammonium 2-(3-tert-butyl-2-hydroxy-5-methylbenzyl)-6-[3-(3-tert-butyl-2-hydroxy-5-methylbenzyl)-2-hydroxy-5-methylbenzyl]-4-methylphenolate acetonitrile solvate, C6H16N+·C39H47O4−·C2H3N, where the organic HNEt3+ cation is included in the partial cone defined by the aromatic faces of the acyclic polyphenolate.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1107/S0108270100006582

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