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  • 1
    Electronic Resource
    Electronic Resource
    Copenhagen : International Union of Crystallography (IUCr)
    Acta crystallographica 53 (1997), S. 181-187 
    ISSN: 1600-5740
    Source: Crystallography Journals Online : IUCR Backfile Archive 1948-2001
    Topics: Chemistry and Pharmacology , Geosciences , Physics
    Notes: The [PF6]− salt of E-tetraethyl-l,4-diaminobut-2-ene has been synthesized and the crystal structure determined. The experimental electronic charge distribution has been obtained by fitting a multipole model to low-temperature, high-resolution, single-crystal X-ray diffraction data. A high-level ab initio molecular orbital calculation has also been performed for the cation, which is used as an antifungal agent. Both experimental and theoretical Laplacian distributions display maxima only at the bond critical points. This correlates with a calculated electrostatic potential which is positive at all points.
    Type of Medium: Electronic Resource
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  • 2
    Publication Date: 2013-04-19
    Description: Alluvial riverbed elevation responds to the balance between sediment supply and transport capacity, which is largely dependent on climate and its translation into fluvial discharge. We examine these relations using U.S. Geological Survey streamflow and channel measurements in conjunction with basin characteristics for 915 reference ("least disturbed") measurement stations across the conterminous United States for the period A.D. 1950–2011. We find that (1) 68% of stations have bed elevation change ( BEC ) trends (p 〈 0.05) with median values of +0.5 cm/yr for aggradation and –0.6 cm/yr for degradation, with no obvious relation to drainage basin structure, physiography, or lithology; (2) BEC correlates with drainage basin area; (3) high-flow variability ( Q 90 / Q 50 , where Q is discharge and 90 and 50 are annual flow percentiles) translates directly into the magnitude, though not the direction, of BEC , after accounting for the scale dependence; (4) Q 90 / Q 50 declines systematically from dry to wet climates, producing disproportionately high rates of BEC in drier regions; and (5) marked increases in precipitation and streamflow occurred disproportionately at dry sites, while streamflow declined disproportionately at wet sites. Climatic shifts in streamflow have the potential to increase/decrease sediment flux and thus affect riverbed elevation by altering flood frequency. These unforeseen responses of bed elevation to climate and climate change have important implications for sediment budgets, longitudinal profiles, ecology, and river management.
    Print ISSN: 0091-7613
    Electronic ISSN: 1943-2682
    Topics: Geosciences
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