Publication Date:
2016-09-07
Description:
The title hydrated complex, [Cu2(C7H4O3)(C12H8N2)4](C7H5O3)2·7.5H2O, is composed of dinuclear CuII complex cations, noncoordinating 4-hydroxybenzoate anions and water molecules of crystallization. In the dinuclear complex cation, the CuII ions are bridged by a 4-oxidobenzoate ligand and thus each metal ion is five-coordinated by two chelating 1,10-phenanthroline (phen) molecules and one anionic O atom in a distorted trigonal-bipyramid geometry. In the crystal, aromatic π–π stacking occurs between phen rings of neighbouring dinuclear CuII complex cations, forming two-dimensional supramolecular systems parallel to (100).
Keywords:
crystal structure4-hydroxybenzoate4-oxidobenzoate1,10-phenanthrolinecopperdinuclear complex cation
Electronic ISSN:
1600-5368
Topics:
Chemistry and Pharmacology
,
Geosciences
Permalink