Publication Date:
2012-03-14
Description:
The asymmetric unit of the title compound, [MnCl2(C16H20N2O)4]·2C16H20N2O, is composed of two coordinatingN-(adamantan-1-yl)pyridine-4-carboxamide molecules, one Cl−anion, an MnIIion, lying on an inversion centre, and one freeN-(adamantan-1-yl)pyridine-4-carboxamide molecule. The distorted octahedral Mn environment comprises two terminal Cl atoms and four monodentate N atoms from four organic ligands. All the carbamoyl N atoms are involved in intermolecular N—H...O hydrogen-bonding interactions which link the molecules into a chain along theaaxis.
Electronic ISSN:
1600-5368
Topics:
Chemistry and Pharmacology
,
Geosciences
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