Publication Date:
2007-10-10
Description:
In the title dinuclear palladium complex, [Pd2Cl4(C29H46N2)], the terminal ligands adopt an anti configuration, with an intramolecular metal–metal distance of 3.3625 (5) Å. The dinuclear palladium complex adopts a V-shaped conformation, with a dihedral angle of 152.67 (3)° between the two chloride-bridged PdNCl3 square-planar systems. The benzene rings in the chelating amine ligand are at an angle of 74.9 (1)° with respect to each other. The complex is the first example of chloride-bridged dinuclear palladium complex with a bidentate secondary amine ligand.
Electronic ISSN:
1600-5368
Topics:
Chemistry and Pharmacology
,
Geosciences
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